Articles
1.
№5-6, 2018
УДК 678.6
Chursova L.V.1, Grebeneva T.A.1, Panina N.N.1
RENEWABLE SOURCES OF RAW MATERIALS FOR EPOXY OLIGOMERS CHEMISTRY (review)
In this paper the possibility of producing epoxy resins with epichlorohydrin prepared from renewable materials and vegetable oils instead of synthetic polymers from natural gas, coal and oil feedstock are discussed. The requirement to use renewable raw materials to obtain the final product, including epoxy oligomers, instead of the exhausted, is very relevant. As a raw material for producing epoxy oligomers may be used various petroleum resins and vegetable oils, and the process for producing such epoxy oligomers is epoxidation of these resins and oils.
Keywords: epichlorohydrin, epoxy oligomers, petroleum resins, vegetable oils, epoxidation.
Reference List
1. Kablov E.N. Strategicheskie napravleniya razvitiya materialov i tekhnologiy ikh pererabotki na period do 2030 goda [The strategic directions of development of materials and technologies of their processing for the period till 2030] // Aviatsionnye materialy i tekhnologii. 2012. №S. S. 7–17.
2. Grashhenkov D.V., Chursova L.V. Strategiya razvitiya kompozicionnyh i funkcionalnyh materialov [Strategy of development of composite and functional materials] // Aviacionnye materialy i tehnologii. 2012. №S. S. 231–242.
3. Azimov A. Kratkaya istoriya khimii [Short history of chemistry]. M.: Tsentrpoligraf, 2002. 284 s.
4. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] //Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
5. Anastas P.T., Bartlett L.B., Kirchhoff M.M., Williamson T.C. The role of catalysis in the design, development, and implementation of green chemistry // Catalysis Today. 2000. Vol. 55. No. 1–2. P. 11–22.
6. Resheniya XIX Mendeleevskogo sezda po obshchey i prikladnoy khimii [Solutions XIX of Mendeleevsky congress on the general and applied chemistry] (Volgograd, 25–30 sent. 2011 g.) [Elektronnyy resurs]. Available at: http://www.mendeleev2011.vstu.ru/ (accessed: October 12, 2016).
7. Gandini A. Polymers from renewable resources: a challenge for the future of macromolecular materials // Macromolecules. 2008. Vol. 41. No. 24. P. 9491–9504.
8. Kamm B., Gruber P.R., Kamm M. Biorefineries – industrial processes and products. Weinheim: Wiley–VCH, 2006. Vol. 1. 964 p.
9. Amidon T.E., Wood C.D., Shupe A.M. et al. Biorefinery: conversion of woody biomass to chemicals, energy and materials // Journal of Biobased Materials and Bioenergy. 2008. Vol. 2. No. 2. P. 100–120.
10. Slavgorodskaya O.I., Bondaletov V.G., Fiterer E.P., Ogorodnikov V.D. Poluchenie epoksidirovannykh neftepolimernykh smol po reaktsii Prilezhaeva [Receiving epoksidirovanny petropolymeric pitches on Prilezhayev's reaction] // Polzunovskiy vestnik. 2013. №1. S. 186–190.
11. Process for producing dichloropropanol from glycerol, the glycerol coming eventually from the conversion of animal fats in the manufacture of biodiesel: pat. WO2005054167; filed. 18.11.04; opubl. 16.06.05.
12. Energetics // Industrial bioproducts: today and tomorrow. Columbia, MD: Energetics, Incorporated, 2003. P. 49, 52–56.
13. Danov S.M., Sulimov A.V., Sulimova A.V. Sovremennye protsessy polucheniya epikhlorgidrina [Modern processes of receiving epihydrinchlorine] // Uspekhi v khimii i khimicheskoy tekhnologii. 2010. T. 24. №5 (110). S. 74–76.
14. Shah D.U. Towards sustainable polymers and plastics: NMR spectroscopic analysis and characterisation of vernonia seed (vernonia galamensis) oil and epoxidised soya bean seed (glycine max) oil // The Scitech Journal – Science. Technology. Innovation. 2004. Vol. 1. No. 12. P. 13–29.
15. Vasilev D.D. Rastitelnye masla kak poluprodukty dlya polucheniya aktivnykh razbaviteley epoksidnykh smol [Vegetable oils as semi-products for receiving active thinners of epoxies] // Sb. tez. 14-y Mezhdunar. Pushchinskoy shkoly-konferentsii molodykh uchenykh «Biologiya – nauka XXI veka». Pushchino: Institut belka RAN. 2010. T. 2. S. 15–16.
16. Gunstone D. The study of natural epoxy oils and epoxidized vegetable oils by13C nuclear magnetic resonance spectroscopy // JAOCS. 1993. Vol. 70. No. 11. P. 1139–1144.
17. Kablov E.N. Rossii nuzhny materialy novogo pokolenija [Materials of new generation are neces-sary to Russia] // Redkie zemli. 2014. №3. S. 8–13.
18. Muhametov R.R., Ahmadieva K.R., Chursova L.V., Kogan D.I. Novye polimernye svyazujushhie dlya perspektivnyh metodov izgotovleniya konstrukcionnyh voloknistyh PKM [New polymeric binding for perspective methods of manufacturing of constructional fibrous PCM] // Aviacionnye materialy i tehnologii. 2011. №2. S. 38–42.
19. Postnova M.V., Postnov V.I. Opyt razvitiya bezavtoklavnyh metodov formovaniya PKM [Development experience out-of-autoclave methods of formation PCM]// Trudy VIAM: ehlektron. nauch.-tekhnich. zhurn. 2014. №4. St. 06. Available at: http://www.viam-works.ru (accessed: October 13, 2016). DOI 10.18577/2307-6046-2014-0-4-6-6.
20. Akintayo E.T. Ziegler T., Onipede A. Shromatographic and spectroscopic analysis of epoxidised canola oil // Bulletin of the Chemical Society of Ethiopia. 2006. Vol. 20. P. 75–81.
21. Ledeneva I.V., Falaleev A.V., Kartavtsev P.A., Perelygina I.E., Lyapun D.V. GKh/MS analiz produktov okisleniya metilovykh efirov zhirnykh kislot podsolnechnogo masla [GH/MS analysis of products of oxidation of methyl ethers of greasy acids of sunflower oil] // Sorbtsionnye i khromatograficheskie protsessy. 2015. T. 15. Vyp. 2. S. 280–287.
22. Tundo P., Anastas P., Black D.StC. et al. Synthetic Pathways and Processes in Green Chemistry. Introductory Overview // Pure and Applied Chemistry. 2000. Vol. 72. No. 7. P. 1207–1228.
23. Kustov L.M., Beletskaya I.P. Green Chemistry – novoe myshlenie [Green Chemistry – new thinking] // Rossiyskiy Khimicheskiy Zhurnal. 2004. T. 48. №6. S. 3–12.
24. Mehta G. Polnyy sintez novykh struktur i biologicheski aktivnykh estestvennykh produktov [Complete synthesis of new structures and biologically active natural products] // XVIII Mendeleevskiy sezd po obshchey i prikladnoy khimii: tez. dokl. M.: 2007. T. 5. S. 2218–2648.
25. Anastas P.T., Warner J.C. Green Chemistry: Theory and Practice. Oxford: Oxford University Press, 1998. 135 p.
26. Zelenaya khimiya v Rossii: sb. statey [Green chemistry in Russia: collection of articles] / pod red. V.V. Lunina, P. Tundo, E.S. Loktevoy. M.: Izd. Mosk. un-ta, 2004. 230 s.
2. Grashhenkov D.V., Chursova L.V. Strategiya razvitiya kompozicionnyh i funkcionalnyh materialov [Strategy of development of composite and functional materials] // Aviacionnye materialy i tehnologii. 2012. №S. S. 231–242.
3. Azimov A. Kratkaya istoriya khimii [Short history of chemistry]. M.: Tsentrpoligraf, 2002. 284 s.
4. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] //Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
5. Anastas P.T., Bartlett L.B., Kirchhoff M.M., Williamson T.C. The role of catalysis in the design, development, and implementation of green chemistry // Catalysis Today. 2000. Vol. 55. No. 1–2. P. 11–22.
6. Resheniya XIX Mendeleevskogo sezda po obshchey i prikladnoy khimii [Solutions XIX of Mendeleevsky congress on the general and applied chemistry] (Volgograd, 25–30 sent. 2011 g.) [Elektronnyy resurs]. Available at: http://www.mendeleev2011.vstu.ru/ (accessed: October 12, 2016).
7. Gandini A. Polymers from renewable resources: a challenge for the future of macromolecular materials // Macromolecules. 2008. Vol. 41. No. 24. P. 9491–9504.
8. Kamm B., Gruber P.R., Kamm M. Biorefineries – industrial processes and products. Weinheim: Wiley–VCH, 2006. Vol. 1. 964 p.
9. Amidon T.E., Wood C.D., Shupe A.M. et al. Biorefinery: conversion of woody biomass to chemicals, energy and materials // Journal of Biobased Materials and Bioenergy. 2008. Vol. 2. No. 2. P. 100–120.
10. Slavgorodskaya O.I., Bondaletov V.G., Fiterer E.P., Ogorodnikov V.D. Poluchenie epoksidirovannykh neftepolimernykh smol po reaktsii Prilezhaeva [Receiving epoksidirovanny petropolymeric pitches on Prilezhayev's reaction] // Polzunovskiy vestnik. 2013. №1. S. 186–190.
11. Process for producing dichloropropanol from glycerol, the glycerol coming eventually from the conversion of animal fats in the manufacture of biodiesel: pat. WO2005054167; filed. 18.11.04; opubl. 16.06.05.
12. Energetics // Industrial bioproducts: today and tomorrow. Columbia, MD: Energetics, Incorporated, 2003. P. 49, 52–56.
13. Danov S.M., Sulimov A.V., Sulimova A.V. Sovremennye protsessy polucheniya epikhlorgidrina [Modern processes of receiving epihydrinchlorine] // Uspekhi v khimii i khimicheskoy tekhnologii. 2010. T. 24. №5 (110). S. 74–76.
14. Shah D.U. Towards sustainable polymers and plastics: NMR spectroscopic analysis and characterisation of vernonia seed (vernonia galamensis) oil and epoxidised soya bean seed (glycine max) oil // The Scitech Journal – Science. Technology. Innovation. 2004. Vol. 1. No. 12. P. 13–29.
15. Vasilev D.D. Rastitelnye masla kak poluprodukty dlya polucheniya aktivnykh razbaviteley epoksidnykh smol [Vegetable oils as semi-products for receiving active thinners of epoxies] // Sb. tez. 14-y Mezhdunar. Pushchinskoy shkoly-konferentsii molodykh uchenykh «Biologiya – nauka XXI veka». Pushchino: Institut belka RAN. 2010. T. 2. S. 15–16.
16. Gunstone D. The study of natural epoxy oils and epoxidized vegetable oils by13C nuclear magnetic resonance spectroscopy // JAOCS. 1993. Vol. 70. No. 11. P. 1139–1144.
17. Kablov E.N. Rossii nuzhny materialy novogo pokolenija [Materials of new generation are neces-sary to Russia] // Redkie zemli. 2014. №3. S. 8–13.
18. Muhametov R.R., Ahmadieva K.R., Chursova L.V., Kogan D.I. Novye polimernye svyazujushhie dlya perspektivnyh metodov izgotovleniya konstrukcionnyh voloknistyh PKM [New polymeric binding for perspective methods of manufacturing of constructional fibrous PCM] // Aviacionnye materialy i tehnologii. 2011. №2. S. 38–42.
19. Postnova M.V., Postnov V.I. Opyt razvitiya bezavtoklavnyh metodov formovaniya PKM [Development experience out-of-autoclave methods of formation PCM]// Trudy VIAM: ehlektron. nauch.-tekhnich. zhurn. 2014. №4. St. 06. Available at: http://www.viam-works.ru (accessed: October 13, 2016). DOI 10.18577/2307-6046-2014-0-4-6-6.
20. Akintayo E.T. Ziegler T., Onipede A. Shromatographic and spectroscopic analysis of epoxidised canola oil // Bulletin of the Chemical Society of Ethiopia. 2006. Vol. 20. P. 75–81.
21. Ledeneva I.V., Falaleev A.V., Kartavtsev P.A., Perelygina I.E., Lyapun D.V. GKh/MS analiz produktov okisleniya metilovykh efirov zhirnykh kislot podsolnechnogo masla [GH/MS analysis of products of oxidation of methyl ethers of greasy acids of sunflower oil] // Sorbtsionnye i khromatograficheskie protsessy. 2015. T. 15. Vyp. 2. S. 280–287.
22. Tundo P., Anastas P., Black D.StC. et al. Synthetic Pathways and Processes in Green Chemistry. Introductory Overview // Pure and Applied Chemistry. 2000. Vol. 72. No. 7. P. 1207–1228.
23. Kustov L.M., Beletskaya I.P. Green Chemistry – novoe myshlenie [Green Chemistry – new thinking] // Rossiyskiy Khimicheskiy Zhurnal. 2004. T. 48. №6. S. 3–12.
24. Mehta G. Polnyy sintez novykh struktur i biologicheski aktivnykh estestvennykh produktov [Complete synthesis of new structures and biologically active natural products] // XVIII Mendeleevskiy sezd po obshchey i prikladnoy khimii: tez. dokl. M.: 2007. T. 5. S. 2218–2648.
25. Anastas P.T., Warner J.C. Green Chemistry: Theory and Practice. Oxford: Oxford University Press, 1998. 135 p.
26. Zelenaya khimiya v Rossii: sb. statey [Green chemistry in Russia: collection of articles] / pod red. V.V. Lunina, P. Tundo, E.S. Loktevoy. M.: Izd. Mosk. un-ta, 2004. 230 s.
2.
№5-6, 2018
УДК 665.939.5
Dementyeva L.A.1, Lukina N.Ph.1, Petrova A.P.1, Isaev A.Yu.1
PROPERTIES AND ASSIGNMENT SELF-FADING GLUES VK-11S and VK-46B
Properties and assignment of polyurethane glue of the VK-11S and high-strength epoxy film adhesive of the VK-46B, which are characterized by the lowered combustibility are provided. VK-11S glue is characterized for gluing of decorative and facing materials to units and devices of the household equipment of passenger planes, helicopters, and also different devices. VK-46B glue is characterized for pasting of designs, including cellular, from polymeric composite materials and aluminum alloys. The materials can be maintained in all-weather conditions.
Keywords: polyurethane glue, the epoxy film glue, the lowered combustibility, smoke allocation, glued joint, mechanical characteristics.
Reference List
1. Chaykun A.M., Eliseev O.A., Naumov I.S., Venediktova M.A. Osobennosti postroeniya receptur dlya morozostojkih rezin [Compounding principles in the field of frost resistant rubbers] // Aviacionnye materialy i tehnologii. 2013. №3. S. 53–55.
2. Naumov I.S., Petrova A.P., Barbotko S.L., Guliaev A.I. Reziny s ponizhennoi goriuchestiu na osnove etilenpropilen-dienovogo kauchuka [Rubbers with the lowered combustibility on basis of ethylenepropylene-diene rubber] // Trudy VIAM: elektron. nauch.-tekhnich. zhurn. 2016. №2. St. 09. Available at: http://www.viam-works.ru (accessed: July 25, 2017). DOI: 10.18577/2307-6046-2016-0-2-9-9.
3. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] //Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
4. Kablov E.N. Strategicheskie napravleniya razvitiya materialov i tekhnologiy ikh pererabotki na period do 2030 goda [The strategic directions of development of materials and technologies of their processing for the period till 2030] // Aviatsionnye materialy i tekhnologii. 2012. №S. S. 7–17.
5. Petrova A.P., Malysheva G.V. Klei, kleevye svyazuyushchie i kleevye prepregi [Glues, glue binding and glue prepregs]. Pod obshchej redaktsiej E.N. Kablova. M.: VIAM, 2017. 472 s.
6. Dementeva L.A., Bocharova L.I., Lukina N.F., Petrova A.P. Mnogofunktsionalnye epoksidnye klei dlya aviatsionnoj tekhniki [Multifunction epoxy glues for aviation engineering] // Klei. Germetiki. Tekhnologii. 2006. №7. S. 18–20.
7. Lukina N.F., Dementeva L.A., Petrova A.P., Serezhenkov A.A. Konstrukcionnye i termostojkie klei [Constructional and heat-resistant glues] // Aviacionnye materialy i tehnologii. 2012. №S. S. 328–335.
8. Petrova A.P., Lukina N.F., Sharova I.A. Otsenka prochnosti kleevykh soedinenij, vypolnennykh epoksidnymi kleyami, pri vozdejstvii razlichnykh faktorov [Assessment of durability of the glued joints executed by epoxy glues, at influence of different factors] // Vse materialy. Entsiklopedicheskij spravochnik. 2013. №8. S. 28–34.
9. Dementeva L.A., Petrova A.P., Lukina N.F. Primenenie i naznachenie epoksidnogo plenochnogo kleya VK-31 [Application and assignment of epoxy film VK-31 glue] // Vse materialy. Entsiklopedicheskij spravochnik. 2015. №1. S. 25–29.
10. Dementeva L.A., Bocharova L.I., Lukina N.F., Petrova A.P. Vysokoprochnye plenochnye klei VK-51 i VK-51A [High-strength film adhesives VK-51 and VK-51A] // Klei. Germetiki. Tekhnologii. 2015. №4. S. 17–19.
11. Kablov E.N., Chursova L.V., Lukina N.F., Petrova A.P. Issledovanie jepoksidno-polisulfonovyh polimernyh sistem kak osnovy vysokoprochnyh kleev aviacionnogo naznachenija [Research of epoxy and polysulfonic polymeric systems as bases of high-strength adhesives of aviation assignment] // Klei. Germetiki. Tehnologii. 2017. №3. S. 7–12.
12. Petrovа A.P., Dementyevа L.A., Lukina N.F., Chursova L.V. Kleevye svjazujushhie dlja polimernyh kompozicionnyh materialov na ugle- i steklonapolniteljah [Adhesive binders for polymer composite materials based on carbon- and glass fillers] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №9. St. 11. Available at: http://www.viam-works.ru (accessed: July 25, 2018). DOI: 10.18577/2307-6046-2015-0-9-11-11.
13. Petrova A.P. Vspenivayushchiesya klei i ikh primenenie v aviastroenii [Foaming glues and their application in aircraft industry] // Klei. Germetiki. Tekhnologii. 2015. №1. S. 2–5.
14. Lukina N.F., Petrova A.P., Muhametov R.R., Kogtjonkov A.S. Novye razrabotki v oblasti kleyashhih materialov aviacionnogo naznacheniya [New developments in the field of adhesive aviation materials] // Aviacionnye materialy i tehnologii. 2017. №S. S. 452–459. DOI: 10.18577/2071-9140-2017-0-S-452-459.
15. Sharova I.A., Lukina N.F. Zazorozapolnyayushchij epoksidnyj klej VK-67M kholodnogo otverzhdeniya [Gap filling epoxy VK-67M glue of cold curing] // Klei. Germetiki. Tekhnologii. 2012. №3. S. 10–12.
16. Dementeva L.A., Tyumeneva T.Yu., Sharova I.A. Klei s ponizhennoj goryuchestyu dlya aviatsionnoj tekhniki [Glues with the lowered combustibility for aviation engineering] // Tr. VI Mezhdunar. konf. «Polimernye materialy ponizhennoj goryuchesti». Vologda, 2011. S. 102–104.
17. Avdonina I.A., Lukina N.F. Bystrootverzhdayushchijsya epoksidnyj klej VK-93 kholodnogo otverzhdeniya [Quick-hardening epoxy VK-93 glue of cold curing] // Klei. Germetiki. Tekhnologii. 2009. №3. S. 14–17.
18. Zhadova N.S., Tyumeneva T.Yu., Sharova I.A., Lukina N.F. Perspektivnye tehnologii dlya vremennogo operativnogo remonta aviacionnoj tehniki [Perspective technologies for field repair if aviation engineering] // Aviacionnye materialy i tehnologii. 2013. №2. S. 67–70.
19. Karimova S.A., Pavlovskaya T.G., Petrova A.P. Podgotovka poverkhnosti alyuminievykh splavov s primeneniem anodnogo oksidirovaniya [Surface preparation of aluminum alloys using anodic oxidation] // Klei. Germetiki. Tekhnologii. 2014. №1. S. 34–38.
2. Naumov I.S., Petrova A.P., Barbotko S.L., Guliaev A.I. Reziny s ponizhennoi goriuchestiu na osnove etilenpropilen-dienovogo kauchuka [Rubbers with the lowered combustibility on basis of ethylenepropylene-diene rubber] // Trudy VIAM: elektron. nauch.-tekhnich. zhurn. 2016. №2. St. 09. Available at: http://www.viam-works.ru (accessed: July 25, 2017). DOI: 10.18577/2307-6046-2016-0-2-9-9.
3. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] //Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
4. Kablov E.N. Strategicheskie napravleniya razvitiya materialov i tekhnologiy ikh pererabotki na period do 2030 goda [The strategic directions of development of materials and technologies of their processing for the period till 2030] // Aviatsionnye materialy i tekhnologii. 2012. №S. S. 7–17.
5. Petrova A.P., Malysheva G.V. Klei, kleevye svyazuyushchie i kleevye prepregi [Glues, glue binding and glue prepregs]. Pod obshchej redaktsiej E.N. Kablova. M.: VIAM, 2017. 472 s.
6. Dementeva L.A., Bocharova L.I., Lukina N.F., Petrova A.P. Mnogofunktsionalnye epoksidnye klei dlya aviatsionnoj tekhniki [Multifunction epoxy glues for aviation engineering] // Klei. Germetiki. Tekhnologii. 2006. №7. S. 18–20.
7. Lukina N.F., Dementeva L.A., Petrova A.P., Serezhenkov A.A. Konstrukcionnye i termostojkie klei [Constructional and heat-resistant glues] // Aviacionnye materialy i tehnologii. 2012. №S. S. 328–335.
8. Petrova A.P., Lukina N.F., Sharova I.A. Otsenka prochnosti kleevykh soedinenij, vypolnennykh epoksidnymi kleyami, pri vozdejstvii razlichnykh faktorov [Assessment of durability of the glued joints executed by epoxy glues, at influence of different factors] // Vse materialy. Entsiklopedicheskij spravochnik. 2013. №8. S. 28–34.
9. Dementeva L.A., Petrova A.P., Lukina N.F. Primenenie i naznachenie epoksidnogo plenochnogo kleya VK-31 [Application and assignment of epoxy film VK-31 glue] // Vse materialy. Entsiklopedicheskij spravochnik. 2015. №1. S. 25–29.
10. Dementeva L.A., Bocharova L.I., Lukina N.F., Petrova A.P. Vysokoprochnye plenochnye klei VK-51 i VK-51A [High-strength film adhesives VK-51 and VK-51A] // Klei. Germetiki. Tekhnologii. 2015. №4. S. 17–19.
11. Kablov E.N., Chursova L.V., Lukina N.F., Petrova A.P. Issledovanie jepoksidno-polisulfonovyh polimernyh sistem kak osnovy vysokoprochnyh kleev aviacionnogo naznachenija [Research of epoxy and polysulfonic polymeric systems as bases of high-strength adhesives of aviation assignment] // Klei. Germetiki. Tehnologii. 2017. №3. S. 7–12.
12. Petrovа A.P., Dementyevа L.A., Lukina N.F., Chursova L.V. Kleevye svjazujushhie dlja polimernyh kompozicionnyh materialov na ugle- i steklonapolniteljah [Adhesive binders for polymer composite materials based on carbon- and glass fillers] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №9. St. 11. Available at: http://www.viam-works.ru (accessed: July 25, 2018). DOI: 10.18577/2307-6046-2015-0-9-11-11.
13. Petrova A.P. Vspenivayushchiesya klei i ikh primenenie v aviastroenii [Foaming glues and their application in aircraft industry] // Klei. Germetiki. Tekhnologii. 2015. №1. S. 2–5.
14. Lukina N.F., Petrova A.P., Muhametov R.R., Kogtjonkov A.S. Novye razrabotki v oblasti kleyashhih materialov aviacionnogo naznacheniya [New developments in the field of adhesive aviation materials] // Aviacionnye materialy i tehnologii. 2017. №S. S. 452–459. DOI: 10.18577/2071-9140-2017-0-S-452-459.
15. Sharova I.A., Lukina N.F. Zazorozapolnyayushchij epoksidnyj klej VK-67M kholodnogo otverzhdeniya [Gap filling epoxy VK-67M glue of cold curing] // Klei. Germetiki. Tekhnologii. 2012. №3. S. 10–12.
16. Dementeva L.A., Tyumeneva T.Yu., Sharova I.A. Klei s ponizhennoj goryuchestyu dlya aviatsionnoj tekhniki [Glues with the lowered combustibility for aviation engineering] // Tr. VI Mezhdunar. konf. «Polimernye materialy ponizhennoj goryuchesti». Vologda, 2011. S. 102–104.
17. Avdonina I.A., Lukina N.F. Bystrootverzhdayushchijsya epoksidnyj klej VK-93 kholodnogo otverzhdeniya [Quick-hardening epoxy VK-93 glue of cold curing] // Klei. Germetiki. Tekhnologii. 2009. №3. S. 14–17.
18. Zhadova N.S., Tyumeneva T.Yu., Sharova I.A., Lukina N.F. Perspektivnye tehnologii dlya vremennogo operativnogo remonta aviacionnoj tehniki [Perspective technologies for field repair if aviation engineering] // Aviacionnye materialy i tehnologii. 2013. №2. S. 67–70.
19. Karimova S.A., Pavlovskaya T.G., Petrova A.P. Podgotovka poverkhnosti alyuminievykh splavov s primeneniem anodnogo oksidirovaniya [Surface preparation of aluminum alloys using anodic oxidation] // Klei. Germetiki. Tekhnologii. 2014. №1. S. 34–38.
3.
№5-6, 2018
УДК 665.939.5
Petrova A.P.1, Lukina N.Ph.1
HISTORY OF DEVELOPMENT AND ACHIEVEMENTS IN THE FIELD OF ADHESIVE MATERIALS
The article describe development history of scientific direction at creation adhesive materials: adhesives, adhesive binders and adhesive prepregs. The properties and nomenclature of phenol-formaldehyde, epoxy, phenol-rubber, polyurethane, organosilicone, inorganic and elastomeric adhesives and materials with a sticky layer are presented. The properties of adhesive binders and adhesive prepregs are presented. Information on the application anodizing of aluminum alloys as an preparation their surface for bonding is described.
Keywords: adhesive, adhesive film, adhesive binder, adhesive prepreg, adhesive bonded-joint, glued construction, honeycomb construction, glued multi-layer construction.
Reference List
1. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the develop-ment of materials and technologies of their processing for the period until 2030»] //Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
2. Kablov E.N. Strategicheskie napravleniya razvitiya materialov i tekhnologiy ikh pererabotki na period do 2030 goda [The strategic directions of development of materials and technologies of their processing for the period till 2030] // Aviatsionnye materialy i tekhnologii. 2012. №S. S. 7–17.
3. Petrova A.P., Lukina N.F., Starodubtseva O.A., Dementeva L.A. 50 let laboratorii «Klei i kleevye prepregi» [50 years of laboratory «Glues and glue prepregs»]. M.: VIAM, 2008. 26 s.
4. Lukina N.F., Dementeva L.A., Petrova A.P., Anihovskaya L.I. Kleyashhie materialy v konstrukcii lopastej vertoletov [Gluing materials in the design of blades of helicopters] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2016. №7. St. 07. Available at: http://www.viam-works.ru (accessed: July 2, 2018). DOI: 10.18577/2307-6046-2016-0-7-7-7.
5. Lukina N.F., Dementeva L.A., Petrova A.P., Serezhenkov A.A. Konstrukcionnye i termostojkie klei [Constructional and heat-resistant glues] // Aviacionnye materialy i tehnologii. 2012. №S. S. 328–335.
6. Anihovskaya L.I., Batizat D.V., Petrova A.P. Vysokoelastichnyj konstruktsionnyj plenochnyj klej VK-50 [Highly elastic constructional film VK-50 glue] // Klei. Germetiki. Tekhnologii. 2016. №3. S. 16–20.
7. Dementeva L.A., Petrova A.P., Lukina N.F. Primenenie i naznachenie epoksidnogo plenochnogo kleya VK-31 [Application and assignment of epoxy film VK-31 glue] // Vse materialy. Entsiklopedicheskij spravochnik. 2015. №1. S. 25–29.
8. Dementeva L.A., Bocharova L.I., Lukina N.F., Petrova A.P. Vysokoprochnye plenochnye klei VK-51 i VK-51A [High-strength film adhesives VK-51 and VK-51A] // Klei. Germetiki. Tekhnologii. 2015. №4. S. 17–19.
9. Kablov E.N., Chursova L.V., Lukina N.F., Petrova A.P. Issledovanie jepoksidno-polisulfonovyh polimernyh sistem kak osnovy vysokoprochnyh kleev aviacionnogo naznachenija [Research of epoxy and polysulfonic polymeric systems as bases of high-strength adhesives of aviation assignment] // Klei. Germetiki. Tehnologii. 2017. №3. S. 7–12.
10. Lukina N.F., Dement'eva L.A., Petrova A.P., Kirienko T.A., Chursova L.V. Kleevye svyazuyushchie dlya detalej iz PKM sotovoj konstruktsii [Glue binding for details from PCM of cellular design] // Klei. Germetiki. Tekhnologii. 2016. №5. S. 12–16.
11. Petrovа A.P., Dementyevа L.A., Lukina N.F., Chursova L.V. Kleevye svjazujushhie dlja polimernyh kompozicionnyh materialov na ugle- i steklonapolniteljah [Adhesive binders for polymer composite materials based on carbon- and glass fillers] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №9. St. 11. Available at: http://www.viam-works.ru (accessed: July 2, 2018). DOI: 10.18577/2307-6046-2015-0-9-11-11.
12. Petrova A.P. Vspenivayushchiesya klei i ikh primenenie v aviastroenii [Foaming glues and their application in aircraft industry] // Klei. Germetiki. Tekhnologii. 2015. №1. S. 2–5.
13. Lukina N.F., Petrova A.P., Muhametov R.R., Kogtjonkov A.S. Novye razrabotki v oblasti kleyashhih materialov aviacionnogo naznacheniya [New developments in the field of adhesive aviation materials] // Aviacionnye materialy i tehnologii. 2017. №S. S. 452–459. DOI: 10.18577/2071-9140-2017-0-S-452-459.
14. Sharova I.A., Lukina N.F. Zazorozapolnyayushchij epoksidnyj klej VK-67M holodnogo otverzhdeniya [Gap filling epoxy VK-67M glue of cold curing] // Klei. Germetiki. Tekhnologii. 2012. №3. S. 10–12.
15. Avdonina I.A., Lukina N.F. Bystrootverzhdayushchijsya epoksidnyj klej VK-93 holodnogo otverzhdeniya [Quick-hardening epoxy VK-93 glue of cold curing] // Klei. Germetiki. Tekhnologii. 2009. №3. S. 14–17.
16. Petrova A.P., Lukina N.F., Pavlyuk B.F., Isaev A.YU., Besednov K.L. Napolniteli dlya tokoprovodyashchih kleev (obzor literatury) [Fillers for conducting glues (literature review)] // Novosti materialovedeniya. Nauka i tekhnika: elektron. nauch.-tekhnich. zhurn. 2017. №5–6 (28). St. 06. Available at: http://materialsnews.ru (accessed: July 2, 2018).
17. Petrova A.P., Malysheva G.V. Klei, kleevye svyazuyushchie i kleevye prepregi [Glues, glue binding and glue prepregs]. Pod obshchej redaktsiej E.N. Kablova. M.: VIAM, 2017. 472 s.
18. Lukina N.F., Petrova A.P., Kotova E.V. Termostojkie klei dlya izdelij aviakosmicheskoj tekhniki [Heat-resistent adhesives used in aviation and space technique] // Trudy VIAM: elektron. nauch.-tekhnich. zhurn. 2014. №3. St. 06. Available at: http://www.viam-works.ru (accessed: July 2, 2018). DOI: 10.18577/2307-6046-2014-0-3-6-6.
19. Petrova A.P. Kak nakleivali plitku s pokrytiem [As pasted tile with covering] // Dospekhi dlya «Burana». Materialy i tekhnologii VIAM dlya MKS «Energiya–Buran» / pod obshch. red. E.N. Kablova. M.: Nauka i zhizn', 2013. S. 64–69.
20. Petrova A.P., Lukina N.F. Prikleivanie teplozashchitnyh elementov v izdelii «Buran» [Gluing of heat-protective elements in the product «Buran»] // Klei. Germetiki. Tekhnologii. 2014. №6. S. 37–41.
21. Tyumeneva T.YU., Lukina N.F., Petrova A.P. Povyshenie adgezii elastomernyh kleev k rezinam pri ispol'zovanii adgezionnogo podsloya [Increase of adhesion of elastomeric glues to rubbers when using adhesive intermediate layer] // Klei. Germetiki. Tekhnologii. 2015. №11. S. 7–10.
22. Zhadova N.S., Tyumeneva T.Yu., Sharova I.A., Lukina N.F. Perspektivnye tehnologii dlya vremennogo operativnogo remonta aviacionnoj tehniki [Perspective technologies for field repair if aviation engineering] // Aviacionnye materialy i tehnologii. 2013. №2. S. 67–70.
23. Karimova S.A., Pavlovskaya T.G., Petrova A.P. Podgotovka poverhnosti alyuminievyh splavov s primeneniem anodnogo oksidirovaniya [Surface preparation of aluminum alloys using anodic oxidation] // Klei. Germetiki. Tekhnologii. 2014. №1. S. 34–38.
2. Kablov E.N. Strategicheskie napravleniya razvitiya materialov i tekhnologiy ikh pererabotki na period do 2030 goda [The strategic directions of development of materials and technologies of their processing for the period till 2030] // Aviatsionnye materialy i tekhnologii. 2012. №S. S. 7–17.
3. Petrova A.P., Lukina N.F., Starodubtseva O.A., Dementeva L.A. 50 let laboratorii «Klei i kleevye prepregi» [50 years of laboratory «Glues and glue prepregs»]. M.: VIAM, 2008. 26 s.
4. Lukina N.F., Dementeva L.A., Petrova A.P., Anihovskaya L.I. Kleyashhie materialy v konstrukcii lopastej vertoletov [Gluing materials in the design of blades of helicopters] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2016. №7. St. 07. Available at: http://www.viam-works.ru (accessed: July 2, 2018). DOI: 10.18577/2307-6046-2016-0-7-7-7.
5. Lukina N.F., Dementeva L.A., Petrova A.P., Serezhenkov A.A. Konstrukcionnye i termostojkie klei [Constructional and heat-resistant glues] // Aviacionnye materialy i tehnologii. 2012. №S. S. 328–335.
6. Anihovskaya L.I., Batizat D.V., Petrova A.P. Vysokoelastichnyj konstruktsionnyj plenochnyj klej VK-50 [Highly elastic constructional film VK-50 glue] // Klei. Germetiki. Tekhnologii. 2016. №3. S. 16–20.
7. Dementeva L.A., Petrova A.P., Lukina N.F. Primenenie i naznachenie epoksidnogo plenochnogo kleya VK-31 [Application and assignment of epoxy film VK-31 glue] // Vse materialy. Entsiklopedicheskij spravochnik. 2015. №1. S. 25–29.
8. Dementeva L.A., Bocharova L.I., Lukina N.F., Petrova A.P. Vysokoprochnye plenochnye klei VK-51 i VK-51A [High-strength film adhesives VK-51 and VK-51A] // Klei. Germetiki. Tekhnologii. 2015. №4. S. 17–19.
9. Kablov E.N., Chursova L.V., Lukina N.F., Petrova A.P. Issledovanie jepoksidno-polisulfonovyh polimernyh sistem kak osnovy vysokoprochnyh kleev aviacionnogo naznachenija [Research of epoxy and polysulfonic polymeric systems as bases of high-strength adhesives of aviation assignment] // Klei. Germetiki. Tehnologii. 2017. №3. S. 7–12.
10. Lukina N.F., Dement'eva L.A., Petrova A.P., Kirienko T.A., Chursova L.V. Kleevye svyazuyushchie dlya detalej iz PKM sotovoj konstruktsii [Glue binding for details from PCM of cellular design] // Klei. Germetiki. Tekhnologii. 2016. №5. S. 12–16.
11. Petrovа A.P., Dementyevа L.A., Lukina N.F., Chursova L.V. Kleevye svjazujushhie dlja polimernyh kompozicionnyh materialov na ugle- i steklonapolniteljah [Adhesive binders for polymer composite materials based on carbon- and glass fillers] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №9. St. 11. Available at: http://www.viam-works.ru (accessed: July 2, 2018). DOI: 10.18577/2307-6046-2015-0-9-11-11.
12. Petrova A.P. Vspenivayushchiesya klei i ikh primenenie v aviastroenii [Foaming glues and their application in aircraft industry] // Klei. Germetiki. Tekhnologii. 2015. №1. S. 2–5.
13. Lukina N.F., Petrova A.P., Muhametov R.R., Kogtjonkov A.S. Novye razrabotki v oblasti kleyashhih materialov aviacionnogo naznacheniya [New developments in the field of adhesive aviation materials] // Aviacionnye materialy i tehnologii. 2017. №S. S. 452–459. DOI: 10.18577/2071-9140-2017-0-S-452-459.
14. Sharova I.A., Lukina N.F. Zazorozapolnyayushchij epoksidnyj klej VK-67M holodnogo otverzhdeniya [Gap filling epoxy VK-67M glue of cold curing] // Klei. Germetiki. Tekhnologii. 2012. №3. S. 10–12.
15. Avdonina I.A., Lukina N.F. Bystrootverzhdayushchijsya epoksidnyj klej VK-93 holodnogo otverzhdeniya [Quick-hardening epoxy VK-93 glue of cold curing] // Klei. Germetiki. Tekhnologii. 2009. №3. S. 14–17.
16. Petrova A.P., Lukina N.F., Pavlyuk B.F., Isaev A.YU., Besednov K.L. Napolniteli dlya tokoprovodyashchih kleev (obzor literatury) [Fillers for conducting glues (literature review)] // Novosti materialovedeniya. Nauka i tekhnika: elektron. nauch.-tekhnich. zhurn. 2017. №5–6 (28). St. 06. Available at: http://materialsnews.ru (accessed: July 2, 2018).
17. Petrova A.P., Malysheva G.V. Klei, kleevye svyazuyushchie i kleevye prepregi [Glues, glue binding and glue prepregs]. Pod obshchej redaktsiej E.N. Kablova. M.: VIAM, 2017. 472 s.
18. Lukina N.F., Petrova A.P., Kotova E.V. Termostojkie klei dlya izdelij aviakosmicheskoj tekhniki [Heat-resistent adhesives used in aviation and space technique] // Trudy VIAM: elektron. nauch.-tekhnich. zhurn. 2014. №3. St. 06. Available at: http://www.viam-works.ru (accessed: July 2, 2018). DOI: 10.18577/2307-6046-2014-0-3-6-6.
19. Petrova A.P. Kak nakleivali plitku s pokrytiem [As pasted tile with covering] // Dospekhi dlya «Burana». Materialy i tekhnologii VIAM dlya MKS «Energiya–Buran» / pod obshch. red. E.N. Kablova. M.: Nauka i zhizn', 2013. S. 64–69.
20. Petrova A.P., Lukina N.F. Prikleivanie teplozashchitnyh elementov v izdelii «Buran» [Gluing of heat-protective elements in the product «Buran»] // Klei. Germetiki. Tekhnologii. 2014. №6. S. 37–41.
21. Tyumeneva T.YU., Lukina N.F., Petrova A.P. Povyshenie adgezii elastomernyh kleev k rezinam pri ispol'zovanii adgezionnogo podsloya [Increase of adhesion of elastomeric glues to rubbers when using adhesive intermediate layer] // Klei. Germetiki. Tekhnologii. 2015. №11. S. 7–10.
22. Zhadova N.S., Tyumeneva T.Yu., Sharova I.A., Lukina N.F. Perspektivnye tehnologii dlya vremennogo operativnogo remonta aviacionnoj tehniki [Perspective technologies for field repair if aviation engineering] // Aviacionnye materialy i tehnologii. 2013. №2. S. 67–70.
23. Karimova S.A., Pavlovskaya T.G., Petrova A.P. Podgotovka poverhnosti alyuminievyh splavov s primeneniem anodnogo oksidirovaniya [Surface preparation of aluminum alloys using anodic oxidation] // Klei. Germetiki. Tekhnologii. 2014. №1. S. 34–38.
4.
№1-2, 2018
УДК 678.8
Sinyakov S.D.1, Zastrogina O.B.1, Pavlyuk B.F.1
COMPOSITIONS BASED ON PHENOLIC RESINS MODIFIED WITH POLYVINYL ACETALS (review)
The present article provides an overview of compositions based on phenol-formaldehyde resins and polyvinyl acetals. The mutual influence of the components on each other and on the final properties of the products obtained is considered. The features of the chemical interaction of the initial components and the changes in their physicochemical properties are studied depending on their structure. In the review, the most widely known brands of resins and adhesives, which are made on the basis of these compositions, their properties and applications, are considered.
Keywords: phenolic resin, polyvinyl acetal, modification.
Reference List
1. Grashhenkov D.V., Chursova L.V. Strategiya razvitiya kompozicionnyh i funkcionalnyh materialov [Strategy of development of composite and functional materials] // Aviacionnye materialy i tehnologii. 2012. №S. S. 231–242.
2. Kablov E.N. Materialy i khimicheskie tekhnologii dlya aviatsionnoy tekhniki [Materials and chemical technologies for aviation engineering] // Vestnik Rossiyskoy akademii nauk. 2012. T. 82. №6. S. 520–530.
3. Kablov E.N., Minakov V.T., Anikhovskaya L.I. Klei i materialy na ikh osnove dlya remonta kon-struktsiy aviatsionnoy tekhniki [Glues and materials on their basis for repair of designs of aviation engineering] // Aviatsionnye materialy i tekhnologii. 2002. №1. S. 61–65.
4. Lukina N.F., Dementeva L.A., Petrova A.P., Serezhenkov A.A. Konstrukcionnye i termostojkie klei [Constructional and heat-resistant glues] // Aviacionnye materialy i tehnologii. 2012. №S. S. 328–335.
5. Dementeva L.A., Serezhenkov A.A., Lukina N.F., Kucevich K.E. Kleevye prepregi i sloistye materialy na ih osnove [Adhesive prepregs and layered materials on their basis] // Aviacionnye materialy i tehnologii. 2013. №2. S. 19–21.
6. Kablov E.N. Khimiya v aviatsionnom materialovedenii [Chemistry in aviation materials science] // Rossiyskiy khimicheskiy zhurnal. 2010. T. LIV. №1. S. 3–4.
7. Kablov E.N. Strategicheskie napravleniya razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda [The strategic directions of development of materials and technologies of their processing for the period to 2030] // Aviacionnye materialy i tehnologii. 2012. №S. S. 7–17.
8. Pilato L. Phenolic Resins: A Century оf Progress. Springer, 2010. 545 с.
9. Gardziella А., Pilato L.A., Knop A. Phenolic resins: chemistry, applications, standardization and ecology. 2000. 562 с.
10. Bahman A., Mjuller K. Fenoplasty [Phenoplasts]. Per. s nem. M.: Himija, 1978. 288 s.
11. Kiselev B.A. Stekloplastiki [Fibreglasses]. M.: Goshimizdat, 1961. 240 s.
12. Knop A., Shejb V. Fenolnye smoly i materialy na ih osnove [Phenolic resins and materials on their basis]. Per. s angl. M.: Himija, 1983. 280 s.
13. Kardashov D.A. Sinteticheskie klei [Synthetic glues]. Izd. 3-e, pererab. i dop. M.: Himija, 1976. 504 s.
14. Jenciklopedija polimerov [Encyclopedia of polymers] / Pod red. V.A. Kargina. M.: Sovetskaja Jenciklopedija, 1972. T. 1. S. 227–231.
15. Losev I.P., Trostjanskaja E.B. Himija sinteticheskih polimerov [Chemistry of synthetic polymers]. Izd. 3-e. M.: Himija, 1971. 616 s.
16. Tehnologija plasticheskih mass [Technology of plastics] / pod red. V.V. Korshaka. M.: Himija, 1972. 616 s.
17. Mihajlin Ju.A. Konstrukcionnye polimernye kompozicionnye materialy [Constructional polymeric composite materials]. SPb.: Nauchnye osnovy i tehnologi, 2008. 822 s.
18. Spravochnik po plasticheskim massam [Directory on plastics]. Izd. 2-e, per. i dop. / pod red. V.M. Kataeva, V.A. Popova, B.I. Sazhina. M.: Himija [], 1975. T. 1. 448 s.
19. Shalun G.B., Surzhenko E.M. Sloistye plastiki [Layered plastics]. L.: Himija, 1978. 232 s.
20. Kablov V.F., Nosenko V.A., Kejbal N.A., Bondarenko S.N. Klei i tehnologii skleivanija detalej v mashinostroenii [Glues and technologies of pasting of details in mechanical engineering]: ucheb. posobie. Staryj Oskol: TNT, 2015. 188 s.
21. Stekloplastiki [Fibreglasses]. Pod red. F. Morgana. Per. s angl. M.: Izdatelstvo inostrannoj literatury, 1961. 486 s.
22. Petrova A.P. Klejashhie materialy: spravochnik [Gluing materials: directory]. M.: Kauchuk i rezina, 2002. 196 s.
23. Skleivanie v mashinostroenii: spravochnik v 2 t. [Pasting in mechanical engineering: the directory in 2 v.] / pod obshh. red. G.V. Malyshevoj. M.: Nauka i tehnologii, 2005. T. 1. 544 s.
24. Ebnesajjad S., Landrock A.H. Adhesive Technology Handbook. 3rd ed. Elsevier, 2015. 414 p.
25. Karadashov D.A. Konstrukcionnye klei [Constructional glues]. M.: Himija, 1980. 288 s.
26. Gurtovnik I.G., Sokolov V.I., Trofimov N.N., Shalgunov S.G. Radioprozrachnye izdelija iz stekloplastikov [Radio transparent products from fibreglasses]. M.: Mir, 2002. 368 s.
27. Spravochnik po klejam i klejashhim mastikam v stroitelstve [The directory on glues and gluing mastics in construction] / pod red. V.G. Mikul'skogo, O.L. Figovskogo. M.: Strojizdat, 1984. 240 s.
28. Shuklina O.V., Lukina N.F. Svojstva novogo teplostojkogo kleja VS-10T-U [Properties of new heatresistant glue VS-10T-U] // Klei. Germetiki. Tehnologii. 2012. №5. S. 8–9.
29. Brodskij G.S., Chervinskaja M.A., Radchik L.D., Sheveleva R.A. Fenolo-polivinilacetalnye klei [Fenolo-polivinilatsetalnye glues] // Plasticheskie massy. 1973. №6. S. 29–30.
30. Bazarova F.F., Kolesova L.S. Klei v proizvodstve radiotehnicheskoj apparatury [Glues in production of radio engineering equipment]. M.: Jenergija, 1975. 120 s.
31. Zastrogina O.B., Shvec N.I., Serkova E.A., Veshkin E.A. Pozharobezopasnye materialy na osnove fenolformaldegidnyh svjazujushhih [proof materials on the basis of the fenolformaldegidny binding] // Klei. Germetiki. Tehnologii. 2017. №7. S. 22–27.
32. Shidlz Dzh. Klejashhie materialy: spravochnik [Gluing materials: directory]. Per. s angl. M.: Mashinostroenie, 1980. 368 s.
33. Vilnav Zh.-Zh. Kleevye soedinenija [Glued joints]. Moskva: Tehnosfera, 2007. 384 s.
34. Da Silva L.F.M., Öchsner A., Adams R.D. Handbook of Adhesion Technology. Springer, 2011. 1554 p.
35. Pizzi А., Mittal K.L. Handbook of Adhesive Technology. 2nd ed., rev. and exp. Marcel Dekker, Inc, 2003. 999 p.
36. Adhesion Science and Engineering. Elsevier Science B.V., 2002. Vol. 2: Surfaces, Chemistry and Application / ed. by M. Chaudhury, A.V. Pocius. 1224 с.
37. Gerald L. Schneberger. Adhesion in Manufacturing. Marcel Dekker, Inc., 1983. 696 c.
2. Kablov E.N. Materialy i khimicheskie tekhnologii dlya aviatsionnoy tekhniki [Materials and chemical technologies for aviation engineering] // Vestnik Rossiyskoy akademii nauk. 2012. T. 82. №6. S. 520–530.
3. Kablov E.N., Minakov V.T., Anikhovskaya L.I. Klei i materialy na ikh osnove dlya remonta kon-struktsiy aviatsionnoy tekhniki [Glues and materials on their basis for repair of designs of aviation engineering] // Aviatsionnye materialy i tekhnologii. 2002. №1. S. 61–65.
4. Lukina N.F., Dementeva L.A., Petrova A.P., Serezhenkov A.A. Konstrukcionnye i termostojkie klei [Constructional and heat-resistant glues] // Aviacionnye materialy i tehnologii. 2012. №S. S. 328–335.
5. Dementeva L.A., Serezhenkov A.A., Lukina N.F., Kucevich K.E. Kleevye prepregi i sloistye materialy na ih osnove [Adhesive prepregs and layered materials on their basis] // Aviacionnye materialy i tehnologii. 2013. №2. S. 19–21.
6. Kablov E.N. Khimiya v aviatsionnom materialovedenii [Chemistry in aviation materials science] // Rossiyskiy khimicheskiy zhurnal. 2010. T. LIV. №1. S. 3–4.
7. Kablov E.N. Strategicheskie napravleniya razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda [The strategic directions of development of materials and technologies of their processing for the period to 2030] // Aviacionnye materialy i tehnologii. 2012. №S. S. 7–17.
8. Pilato L. Phenolic Resins: A Century оf Progress. Springer, 2010. 545 с.
9. Gardziella А., Pilato L.A., Knop A. Phenolic resins: chemistry, applications, standardization and ecology. 2000. 562 с.
10. Bahman A., Mjuller K. Fenoplasty [Phenoplasts]. Per. s nem. M.: Himija, 1978. 288 s.
11. Kiselev B.A. Stekloplastiki [Fibreglasses]. M.: Goshimizdat, 1961. 240 s.
12. Knop A., Shejb V. Fenolnye smoly i materialy na ih osnove [Phenolic resins and materials on their basis]. Per. s angl. M.: Himija, 1983. 280 s.
13. Kardashov D.A. Sinteticheskie klei [Synthetic glues]. Izd. 3-e, pererab. i dop. M.: Himija, 1976. 504 s.
14. Jenciklopedija polimerov [Encyclopedia of polymers] / Pod red. V.A. Kargina. M.: Sovetskaja Jenciklopedija, 1972. T. 1. S. 227–231.
15. Losev I.P., Trostjanskaja E.B. Himija sinteticheskih polimerov [Chemistry of synthetic polymers]. Izd. 3-e. M.: Himija, 1971. 616 s.
16. Tehnologija plasticheskih mass [Technology of plastics] / pod red. V.V. Korshaka. M.: Himija, 1972. 616 s.
17. Mihajlin Ju.A. Konstrukcionnye polimernye kompozicionnye materialy [Constructional polymeric composite materials]. SPb.: Nauchnye osnovy i tehnologi, 2008. 822 s.
18. Spravochnik po plasticheskim massam [Directory on plastics]. Izd. 2-e, per. i dop. / pod red. V.M. Kataeva, V.A. Popova, B.I. Sazhina. M.: Himija [], 1975. T. 1. 448 s.
19. Shalun G.B., Surzhenko E.M. Sloistye plastiki [Layered plastics]. L.: Himija, 1978. 232 s.
20. Kablov V.F., Nosenko V.A., Kejbal N.A., Bondarenko S.N. Klei i tehnologii skleivanija detalej v mashinostroenii [Glues and technologies of pasting of details in mechanical engineering]: ucheb. posobie. Staryj Oskol: TNT, 2015. 188 s.
21. Stekloplastiki [Fibreglasses]. Pod red. F. Morgana. Per. s angl. M.: Izdatelstvo inostrannoj literatury, 1961. 486 s.
22. Petrova A.P. Klejashhie materialy: spravochnik [Gluing materials: directory]. M.: Kauchuk i rezina, 2002. 196 s.
23. Skleivanie v mashinostroenii: spravochnik v 2 t. [Pasting in mechanical engineering: the directory in 2 v.] / pod obshh. red. G.V. Malyshevoj. M.: Nauka i tehnologii, 2005. T. 1. 544 s.
24. Ebnesajjad S., Landrock A.H. Adhesive Technology Handbook. 3rd ed. Elsevier, 2015. 414 p.
25. Karadashov D.A. Konstrukcionnye klei [Constructional glues]. M.: Himija, 1980. 288 s.
26. Gurtovnik I.G., Sokolov V.I., Trofimov N.N., Shalgunov S.G. Radioprozrachnye izdelija iz stekloplastikov [Radio transparent products from fibreglasses]. M.: Mir, 2002. 368 s.
27. Spravochnik po klejam i klejashhim mastikam v stroitelstve [The directory on glues and gluing mastics in construction] / pod red. V.G. Mikul'skogo, O.L. Figovskogo. M.: Strojizdat, 1984. 240 s.
28. Shuklina O.V., Lukina N.F. Svojstva novogo teplostojkogo kleja VS-10T-U [Properties of new heatresistant glue VS-10T-U] // Klei. Germetiki. Tehnologii. 2012. №5. S. 8–9.
29. Brodskij G.S., Chervinskaja M.A., Radchik L.D., Sheveleva R.A. Fenolo-polivinilacetalnye klei [Fenolo-polivinilatsetalnye glues] // Plasticheskie massy. 1973. №6. S. 29–30.
30. Bazarova F.F., Kolesova L.S. Klei v proizvodstve radiotehnicheskoj apparatury [Glues in production of radio engineering equipment]. M.: Jenergija, 1975. 120 s.
31. Zastrogina O.B., Shvec N.I., Serkova E.A., Veshkin E.A. Pozharobezopasnye materialy na osnove fenolformaldegidnyh svjazujushhih [proof materials on the basis of the fenolformaldegidny binding] // Klei. Germetiki. Tehnologii. 2017. №7. S. 22–27.
32. Shidlz Dzh. Klejashhie materialy: spravochnik [Gluing materials: directory]. Per. s angl. M.: Mashinostroenie, 1980. 368 s.
33. Vilnav Zh.-Zh. Kleevye soedinenija [Glued joints]. Moskva: Tehnosfera, 2007. 384 s.
34. Da Silva L.F.M., Öchsner A., Adams R.D. Handbook of Adhesion Technology. Springer, 2011. 1554 p.
35. Pizzi А., Mittal K.L. Handbook of Adhesive Technology. 2nd ed., rev. and exp. Marcel Dekker, Inc, 2003. 999 p.
36. Adhesion Science and Engineering. Elsevier Science B.V., 2002. Vol. 2: Surfaces, Chemistry and Application / ed. by M. Chaudhury, A.V. Pocius. 1224 с.
37. Gerald L. Schneberger. Adhesion in Manufacturing. Marcel Dekker, Inc., 1983. 696 c.
5.
№5-6, 2017
УДК 665.939.5
Petrova A.P.1
INFLUENCE OF СARBORANE GROUPS ON CURING PROCESSES OF CARBORANE-CONTAINING ADHESIVES OF DIFFERENT CHEMICAL NATURE
Part 2. Curing of the carboranconteined polyurethane and siloxane adhesive
Mechanisms of curing of glues as a part of which carboranconteined components are used are considered. Curing processes in сarboranconteined, polyurethane and siloxane adhesive are investigated. Researches carried out using methods IR-spectrum, TGA and on change of the maintenance of soluble fraction in cured compositions. Influence of structure of сarborane groups on curing processes is shown.
Results of experiments on decrease in temperature of curing of сarboranconteined glue compositions are given.
Keywords: carboranes, polyurethane, siloxane, adhesive, curing, curing catalysts, IK spektry, TGA, durability of glued joints, thermomechanical characteristics, dilatometry, x-ray diffraction analysis, diffractogram.
Reference List
1. Grajms R. Karborany [Carboranes]. Per. s angl. / pod red. A.F. Zhigacha. M.: Mir, 1974. 264 s.
2. Petrova A.P. Povyshenie termostojkosti poliuretanovyh klejashhih sistem pri modifikacii karboranami [Increase of thermal stability of polyurethane gluing systems when updating by carboranes] // Novosti materialovedenija. Nauka i tehnika: jelektron. nauch.-tehnich. zhurn. 2017. №1. St. 04. Available at: http://www.materialsnews.ru (accessed: June 27, 2017).
3. Petrova A.P., Laptev A.B. Termicheskaja ustojchivost karboransoderzhashhih poliuretanovyh klejashhih sistem [Thermal stability carborane of containing polyurethane gluing systems] // Klei. Germetiki. Tehnologii. 2017. №8. S. 2–5.
4. Lipatova T.Je., Bakalo L.A. Kinetika i mehanizm reakcij obrazovanija poliuretanov [Kinetics and mechanism of reactions of education poliuretanov] // Uspehi himii poliuretanov. Kiev: Naukova Dumka, 1972. S. 195–213.
5. Valeckij P.M., Petrova A.P. Polimernye klei na osnove karboransoderzhashhih soedinenij [Polymeric glues on basis carborane of containing connections] // Klei. Germetiki. Tehnologii. 2005. №3. S. 2–5.
6. Lukina N.F., Dementeva L.A., Petrova A.P., Serezhenkov A.A. Konstrukcionnye i termostojkie klei [Constructional and heat-resistant glues] // Aviacionnye materialy i tehnologii. 2012. №S. S. 328–335.
7. Sharova I.A., Petrova A.P. Obzor po materialam mezhdunarodnoj konferencii po kleyam i germetikam (WAC-2012, Franciya) [Review of world adhesive and sealant conference (WAC-2012, France] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №8. St. 06. Available at: http://www.viam-works.ru (accessed: June 19, 2017).
8. Petrova A.P. Magnitoprovodjashhie kleevye kompozicii na osnove karboransoderzhashhih soedinenij [Magneto carrying-out glue compositions on basis carborane of containing connections] // Klei. Germetiki. Tehnologii. 2006. №11. S. 3–4.
9. Petrova A.P. Povyshenie termostojkosti klejashhih sistem na osnove fenolformaldegidnyh oligomerov pri modifikacii karboranami [Increasing thermal resistance of the adhesive systems based on phenol-formaldehyde oligomers with modification of the carborane] // Novosti materialovedenija. Nauka i tehnika: jelektron. nauch.-tehnich. zhurn. 2017. №1. St. 03. Available at: http://www.materialsnews.ru (accessed: June 27, 2017).
10. Petrova A.P. Laptev A.B. Termicheskaja ustojchivost karboransoderzhashhih klejashhih sistem na osnove fenolformaldegidnyh oligomerov [Thermal stability of karboransoderzhashchy gluing systems on the basis of fenolformaldegidny oligomers] // Klei. Germetiki. Tehnologii. 2017. №7. S. 2–6.
11. Petrova A.P., Laptev A.B. Fenolno-kauchukovye klei, modificirovannye karboranami [The phenolic and rubber glues modified by carboranes] // Klei. Germetiki. Tehnologii. 2017. №6. S. 2–6.
12. Petrova A.P., Valeckij P.M. Fenolno-kauchukovye karboransoderzhashhie klei s sobstvennym fer-romagnetizmom [Phenolic and rubber carborane containing glues with own ferromagnetizm] // Klei. Germetiki. Tehnologii. 2007. №4. S. 6–10.
13. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the develop-ment of materials and technologies of their processing for the period until 2030»] //Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
14. Kablov E.N. Aviatsionnoe materialovedenie v XXI veke. Perspektivy i zadachi [Aviation materials science in the XXI century. Perspectives and tasks] // Aviatsionnye materialy. Izbrannye trudy «VIAM» 1932–2002. M.: VIAM, 2002. S. 23–47.
15. Grashhenkov D.V., Chursova L.V. Strategiya razvitiya kompozicionnyh i funkcionalnyh materialov [Strategy of development of composite and functional materials] // Aviacionnye materialy i tehnologii. 2012. №S. S. 231–242.
2. Petrova A.P. Povyshenie termostojkosti poliuretanovyh klejashhih sistem pri modifikacii karboranami [Increase of thermal stability of polyurethane gluing systems when updating by carboranes] // Novosti materialovedenija. Nauka i tehnika: jelektron. nauch.-tehnich. zhurn. 2017. №1. St. 04. Available at: http://www.materialsnews.ru (accessed: June 27, 2017).
3. Petrova A.P., Laptev A.B. Termicheskaja ustojchivost karboransoderzhashhih poliuretanovyh klejashhih sistem [Thermal stability carborane of containing polyurethane gluing systems] // Klei. Germetiki. Tehnologii. 2017. №8. S. 2–5.
4. Lipatova T.Je., Bakalo L.A. Kinetika i mehanizm reakcij obrazovanija poliuretanov [Kinetics and mechanism of reactions of education poliuretanov] // Uspehi himii poliuretanov. Kiev: Naukova Dumka, 1972. S. 195–213.
5. Valeckij P.M., Petrova A.P. Polimernye klei na osnove karboransoderzhashhih soedinenij [Polymeric glues on basis carborane of containing connections] // Klei. Germetiki. Tehnologii. 2005. №3. S. 2–5.
6. Lukina N.F., Dementeva L.A., Petrova A.P., Serezhenkov A.A. Konstrukcionnye i termostojkie klei [Constructional and heat-resistant glues] // Aviacionnye materialy i tehnologii. 2012. №S. S. 328–335.
7. Sharova I.A., Petrova A.P. Obzor po materialam mezhdunarodnoj konferencii po kleyam i germetikam (WAC-2012, Franciya) [Review of world adhesive and sealant conference (WAC-2012, France] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №8. St. 06. Available at: http://www.viam-works.ru (accessed: June 19, 2017).
8. Petrova A.P. Magnitoprovodjashhie kleevye kompozicii na osnove karboransoderzhashhih soedinenij [Magneto carrying-out glue compositions on basis carborane of containing connections] // Klei. Germetiki. Tehnologii. 2006. №11. S. 3–4.
9. Petrova A.P. Povyshenie termostojkosti klejashhih sistem na osnove fenolformaldegidnyh oligomerov pri modifikacii karboranami [Increasing thermal resistance of the adhesive systems based on phenol-formaldehyde oligomers with modification of the carborane] // Novosti materialovedenija. Nauka i tehnika: jelektron. nauch.-tehnich. zhurn. 2017. №1. St. 03. Available at: http://www.materialsnews.ru (accessed: June 27, 2017).
10. Petrova A.P. Laptev A.B. Termicheskaja ustojchivost karboransoderzhashhih klejashhih sistem na osnove fenolformaldegidnyh oligomerov [Thermal stability of karboransoderzhashchy gluing systems on the basis of fenolformaldegidny oligomers] // Klei. Germetiki. Tehnologii. 2017. №7. S. 2–6.
11. Petrova A.P., Laptev A.B. Fenolno-kauchukovye klei, modificirovannye karboranami [The phenolic and rubber glues modified by carboranes] // Klei. Germetiki. Tehnologii. 2017. №6. S. 2–6.
12. Petrova A.P., Valeckij P.M. Fenolno-kauchukovye karboransoderzhashhie klei s sobstvennym fer-romagnetizmom [Phenolic and rubber carborane containing glues with own ferromagnetizm] // Klei. Germetiki. Tehnologii. 2007. №4. S. 6–10.
13. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the develop-ment of materials and technologies of their processing for the period until 2030»] //Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
14. Kablov E.N. Aviatsionnoe materialovedenie v XXI veke. Perspektivy i zadachi [Aviation materials science in the XXI century. Perspectives and tasks] // Aviatsionnye materialy. Izbrannye trudy «VIAM» 1932–2002. M.: VIAM, 2002. S. 23–47.
15. Grashhenkov D.V., Chursova L.V. Strategiya razvitiya kompozicionnyh i funkcionalnyh materialov [Strategy of development of composite and functional materials] // Aviacionnye materialy i tehnologii. 2012. №S. S. 231–242.
6.
№5-6, 2017
УДК 621.792.053:678.046.3
Petrova A.P.1, Lukina N.Ph.1, Pavlyuk B.F.1, Isaev A.Yu.1, Besednov K.L.1
FILLERS FOR CONDUCTING GLUES (literature review)
The review of scientific and technical literature and patents on fillers used in the composition of conductive adhesives to give them the properties of electrical conductivity. For compile this review, a search, selection, systematization and analysis of scientific, technical and patent literature by countries: Russia, USA, Japan, Germany, France, Great Britain and China, has been carried out. Retrospective search was 27 years. The most commonly fillers used in the conductive adhesives, the advantages and disadvantages of each of the fillers, the level of electrical conductivity achieved is determined. The influence of form of the filler particles on the electrical conductivity is shown.
Keywords: filler, conductivity, the conducting composition, electro carrying-out adhesive, silver powder, unit volume electrical resistance, filler structure.
Reference List
1. Kardashov D.A., Petrova A.P. Polimernye klei [Polymeric glues]. M.: Khimiia, 1983. 256 s.
2. Petrova A.P., Lukina N.F. Klei dlia mnogorazovoi kosmicheskoi sistemy [Adhesives for «Вuran» reusable spaceship] //Aviatsionnye materialy i tekhnologii. 2013. №S1. S. 131–136.
3. Conductive adhesive and article made therewith: pat. 5173765 А USA; publ. 22.12.92.
4. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] //Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
5. Kablov E.N. Strategicheskie napravleniya razvitiya materialov i tekhnologiy ikh pererabotki na period do 2030 goda [The strategic directions of development of materials and technologies of their processing for the period till 2030] // Aviatsionnye materialy i tekhnologii. 2012. №S. S. 7–17.
6. Kablov E.N. Kontrol kachestva materialov – garantiya bezopasnosti ekspluatatsii aviatsionnoy tekhniki [Quality control of materials – security accreditation of operation of aviation engineering] // Aviatsionnye materialy i tekhnologii. 2001. №1. S. 3–8.
7. Kablov E.N. Aviatsionnoe materialovedenie v XXI veke. Perspektivy i zadachi [Aviation materials science in the XXI century. Perspectives and tasks] // Aviatsionnye materialy. Izbrannye trudy «VIAM» 1932–2002. M.: VIAM, 2002. S. 23–47.
8. Grashhenkov D.V., Chursova L.V. Strategiya razvitiya kompozicionnyh i funkcionalnyh materialov [Strategy of development of composite and functional materials] // Aviacionnye materialy i tehnologii. 2012. №S. S. 231–242.
9. Conductive adhesive and method for mounting electronic part using same: pat. 3681907 В2 JP; publ. 10.08.05.
10. Conductive adhesive composition: pat. 7345105 В2 USA; publ. 18.03.08.
11. Conductive resin compositions and electronic parts using the same: pat. 6680007 В2 USA;
publ. 20.01.2004.
12. Conductive adhesive and circuit using the same: app. 2005/0230667 А1 USA; publ. 20.10.05.
13. Conductive adhesive: app. EP 2042580 А1; publ. 01.04.09.
14. Electroconductive paste: app. EP 2911160 А1; publ. 26.08.15.
15. Thermosetting type conductive paste and laminated ceramic electronic component having an external electrode formed by using such thermosetting type conductive paste: app. 1965397 А1 EP; publ. 03.09.08.
16. Conductive paste, laminated ceramic component, printed circuit board, and electronic device: pat. 3121819 А1 EP; publ. 25.01.17.
17. High thermally conductive polymeric adhesive: pat. 6265471 В1 USA; publ. 24.07.01.
18. Adhesives With Thermal Conductivity Enhanced By Mixed Silver Fillers: pat. 8795837 В2 USA; publ. 05.08.14.
19. Conductive adhesives comprising silver-coated particles: app. 2014178671 A1 USA; publ. 26.06.14.
20. Conductive inks and pastes: app. 2010009153 А1 USA; publ. 14.01.10.
21. Silver conductive adhesive and preparation: pat. 9567496 В2 USA; publ. 14.02.17.
22. Highly conductive electrically conductive: pat. 9490043 В2; publ. 08.11.16.
23. Tokoprovodiashchaia kleevaia kompozitsiia [Conducting glue composition]: pat. 2408642 S1 Ros. Federatsiia; 10.01.11, Biul. №1.
24. Tokoprovodiashchaia kleevaia kompozitsiia [Conducting glue composition]: pat. 2246519 S2 Ros. Federatsiia; 20.02.05, Biul. №5.
25. Conductive adhesive: app. 2010/0044088 А1 USA; publ. 25.02.10.
26. Polymeric adhesive: app. 6140402 А USA; publ. 31.10.00.
27. Adhesive paste containing polymeric resin: pat. 0719299 В1 EP; publ. 14.11.01.
28. Electroconductive adhesive: pat. 2748615 B2 USA; publ. 11.02.92.
29. Electrically conductive adhesives and methods of making: pat. 7527749 В2 USA; publ. 05.05.09.
30. Flexible microelectronics adhesive: app. 2010/219526 А1 USA; publ. 02.09.10.
31. Die attach adhesive compositions: app. 6147141 А USA, publ. 14.11.00.
32. Snap-cure epoxy adhesives: app. 5770706 А USA; publ. 23.06.98.
33. Silver coated flaky material filled conductive curable composition and the application in die:
app. 20110095241 А1 USA; publ. 28.04.11.
34. Electrically conductive: app. 20160035910 А1 USA; publ. 04.02.16.
35. Sinterable silver flake adhesive for use in electronics: app. 2013/0187102 А1 USA; publ. 25.07.13.
36. Tokoprovodiashchaia kleevaia kompozitsiia [Conducting glue composition]: pat. 2058361 S1 Ros. Federatsiia; 20.04.96.
37. Conductive adhesive and the semiconductor device: pat. 2893782 В2 JP; publ. 24.05.99.
38. Electrically conductive adhesive composition, electrically conductive adhesive sheet and use thereof: pat. 6344155 В1 USA; publ. 05.02.02.
39. Electrically conductive adhesive: pat. 2748615 В2 JP; publ. 18.07.91.
40. Tokoprovodiashchaia kleevaia kompozitsiia [Conducting glue composition]: pat. 2308105 S1 Ros. Federatsiia; 10.10.07, Biul. №28.
41. Carbon nanotube composite structure and adhesive member: app. 2011077784 А1, WO; publ. 30.06.11.
2. Petrova A.P., Lukina N.F. Klei dlia mnogorazovoi kosmicheskoi sistemy [Adhesives for «Вuran» reusable spaceship] //Aviatsionnye materialy i tekhnologii. 2013. №S1. S. 131–136.
3. Conductive adhesive and article made therewith: pat. 5173765 А USA; publ. 22.12.92.
4. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] //Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
5. Kablov E.N. Strategicheskie napravleniya razvitiya materialov i tekhnologiy ikh pererabotki na period do 2030 goda [The strategic directions of development of materials and technologies of their processing for the period till 2030] // Aviatsionnye materialy i tekhnologii. 2012. №S. S. 7–17.
6. Kablov E.N. Kontrol kachestva materialov – garantiya bezopasnosti ekspluatatsii aviatsionnoy tekhniki [Quality control of materials – security accreditation of operation of aviation engineering] // Aviatsionnye materialy i tekhnologii. 2001. №1. S. 3–8.
7. Kablov E.N. Aviatsionnoe materialovedenie v XXI veke. Perspektivy i zadachi [Aviation materials science in the XXI century. Perspectives and tasks] // Aviatsionnye materialy. Izbrannye trudy «VIAM» 1932–2002. M.: VIAM, 2002. S. 23–47.
8. Grashhenkov D.V., Chursova L.V. Strategiya razvitiya kompozicionnyh i funkcionalnyh materialov [Strategy of development of composite and functional materials] // Aviacionnye materialy i tehnologii. 2012. №S. S. 231–242.
9. Conductive adhesive and method for mounting electronic part using same: pat. 3681907 В2 JP; publ. 10.08.05.
10. Conductive adhesive composition: pat. 7345105 В2 USA; publ. 18.03.08.
11. Conductive resin compositions and electronic parts using the same: pat. 6680007 В2 USA;
publ. 20.01.2004.
12. Conductive adhesive and circuit using the same: app. 2005/0230667 А1 USA; publ. 20.10.05.
13. Conductive adhesive: app. EP 2042580 А1; publ. 01.04.09.
14. Electroconductive paste: app. EP 2911160 А1; publ. 26.08.15.
15. Thermosetting type conductive paste and laminated ceramic electronic component having an external electrode formed by using such thermosetting type conductive paste: app. 1965397 А1 EP; publ. 03.09.08.
16. Conductive paste, laminated ceramic component, printed circuit board, and electronic device: pat. 3121819 А1 EP; publ. 25.01.17.
17. High thermally conductive polymeric adhesive: pat. 6265471 В1 USA; publ. 24.07.01.
18. Adhesives With Thermal Conductivity Enhanced By Mixed Silver Fillers: pat. 8795837 В2 USA; publ. 05.08.14.
19. Conductive adhesives comprising silver-coated particles: app. 2014178671 A1 USA; publ. 26.06.14.
20. Conductive inks and pastes: app. 2010009153 А1 USA; publ. 14.01.10.
21. Silver conductive adhesive and preparation: pat. 9567496 В2 USA; publ. 14.02.17.
22. Highly conductive electrically conductive: pat. 9490043 В2; publ. 08.11.16.
23. Tokoprovodiashchaia kleevaia kompozitsiia [Conducting glue composition]: pat. 2408642 S1 Ros. Federatsiia; 10.01.11, Biul. №1.
24. Tokoprovodiashchaia kleevaia kompozitsiia [Conducting glue composition]: pat. 2246519 S2 Ros. Federatsiia; 20.02.05, Biul. №5.
25. Conductive adhesive: app. 2010/0044088 А1 USA; publ. 25.02.10.
26. Polymeric adhesive: app. 6140402 А USA; publ. 31.10.00.
27. Adhesive paste containing polymeric resin: pat. 0719299 В1 EP; publ. 14.11.01.
28. Electroconductive adhesive: pat. 2748615 B2 USA; publ. 11.02.92.
29. Electrically conductive adhesives and methods of making: pat. 7527749 В2 USA; publ. 05.05.09.
30. Flexible microelectronics adhesive: app. 2010/219526 А1 USA; publ. 02.09.10.
31. Die attach adhesive compositions: app. 6147141 А USA, publ. 14.11.00.
32. Snap-cure epoxy adhesives: app. 5770706 А USA; publ. 23.06.98.
33. Silver coated flaky material filled conductive curable composition and the application in die:
app. 20110095241 А1 USA; publ. 28.04.11.
34. Electrically conductive: app. 20160035910 А1 USA; publ. 04.02.16.
35. Sinterable silver flake adhesive for use in electronics: app. 2013/0187102 А1 USA; publ. 25.07.13.
36. Tokoprovodiashchaia kleevaia kompozitsiia [Conducting glue composition]: pat. 2058361 S1 Ros. Federatsiia; 20.04.96.
37. Conductive adhesive and the semiconductor device: pat. 2893782 В2 JP; publ. 24.05.99.
38. Electrically conductive adhesive composition, electrically conductive adhesive sheet and use thereof: pat. 6344155 В1 USA; publ. 05.02.02.
39. Electrically conductive adhesive: pat. 2748615 В2 JP; publ. 18.07.91.
40. Tokoprovodiashchaia kleevaia kompozitsiia [Conducting glue composition]: pat. 2308105 S1 Ros. Federatsiia; 10.10.07, Biul. №28.
41. Carbon nanotube composite structure and adhesive member: app. 2011077784 А1, WO; publ. 30.06.11.
7.
№3-4, 2017
УДК 665.939.5
Petrova A.P.1
Influence of сarborane groups on curing processes of carborane-containing adhesives of different chemical nature. Part 1. Curing of adhesive on the basis of phenolformaldehyde oligomers
Mechanisms of curing of glues as a part of which carboranconteining components are used are considered. Curing processes in carboranconteined phenolic and rubber and phenolic and organic silicon adhesives are investigated. Researches carried out using methods IR spectroscopy, TGA and on change of the maintenance of soluble fraction in hardened compositions. Influence of structure of carborane groups on curing processes is shown.
It is shown that carborane groups make essential impact on the speed of processes of thermochemical transformations when curing adhesives, shifting them in area of more high temperatures.
Keywords: phenolformaldehyde oligomers, carboranes, adhesive, curing, IR spectrum, TGA, durability of adhesived joints, thermomechanical characteristics, dilatometry, x-ray diffraction analysis, diffractogram.
Reference List
1. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [In-novative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the develop-ment of materials and technologies of their processing for the period until 2030»] //Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
2. Kablov E.N. Aviatsionnoe materialovedenie v XXI veke. Perspektivy i zadachi [Aviation materials science in the XXI century. Perspectives and tasks] // Aviatsionnye materialy. Iz-brannye trudy «VIAM» 1932–2002. M.: VIAM, 2002. S. 23–47.
3. Grashhenkov D.V., Chursova L.V. Strategiya razvitiya kompozicionnyh i funkcionalnyh materialov [Strategy of development of composite and functional materials] // Aviacionnye materialy i tehnologii. 2012. №S. S. 231–242.
4. Petrova A.P. Povyshenie termostojkosti klejashhih sistem na osnove fenolformaldegidnyh oligomerov pri modifikacii karboranami [Increasing thermal resistance of the adhesive sys-tems based on phenol-formaldehyde oligomers with modification of the carborane] // Novosti materialovedenija. Nauka i tehnika: jelektron. nauch.-tehnich. zhurn. 2017. №1. St. 03. Available at: http://www.materialsnews.ru (accessed: June 27, 2017).
5. Petrova A.P. Laptev A.B. Termicheskaja ustojchivost karboransoderzhashhih klejashhih sistem na osnove fenolformaldegidnyh oligomerov [Thermal stability of karbor-ansoderzhashchy gluing systems on the basis of fenolformaldegidny oligomers] // Klei. Germetiki. Tehnologii. 2017. №7. S. 2–6.
6. Petrova A.P., Laptev A.B. Fenolno-kauchukovye klei, modificirovannye karboranami [The phenolic and rubber glues modified by carboranes] // Klei. Germetiki. Tehnologii. 2017. №6. S. 2–6.
7. Grajms R. Karborany [Carboranes]. Per. s angl. / pod red. A.F. Zhigacha. M.: Mir, 1974. 264 s.
8. Petrova A.P., Valeckij P.M. Fenolno-kauchukovye karboransoderzhashhie klei s sobstvennym ferromagnetizmom [Phenolic and rubber carborane containing glues with own ferromagnetizm] // Klei. Germetiki. Tehnologii. 2007. №4. S. 6–10.
9. Petrova A.P. Povyshenie termostojkosti poliuretanovyh klejashhih sistem pri modifikacii karboranami [Increase of thermal stability of polyurethane gluing systems when updating by carboranes] // Novosti materialovedenija. Nauka i tehnika: jelektron. nauch.-tehnich. zhurn. 2017. №1. St. 04. Available at: http://www.materialsnews.ru (accessed: June 27, 2017).
10. Petrova A.P., Laptev A.B. Termicheskaja ustojchivost karboransoderzhashhih poliuretanovyh klejashhih sistem [Thermal stability carborane of containing polyurethane gluing systems] // Klei. Germetiki. Tehnologii. 2017. №8. S. 2–5.
11. Lipatova T.Je., Bakalo L.A. Kinetika i mehanizm reakcij obrazovanija poliuretanov [Kinetics and mechanism of reactions of education poliuretanov] // Uspehi himii poliuretanov. Kiev: Naukova Dumka, 1972. S. 195–213.
12. Valeckij P.M., Petrova A.P. Polimernye klei na osnove karboransoderzhashhih soedinenij [Polymeric glues on basis carborane of containing connections] // Klei. Germetiki. Tehnologii. 2005. №3. S. 2–5.
13. Petrova A.P. Magnitoprovodjashhie kleevye kompozicii na osnove karboransoderzhashhih soedinenij [Magneto carrying-out glue compositions on basis carborane of containing con-nections] // Klei. Germetiki. Tehnologii. 2006. №11. S. 3–4.
14. Lukina N.F., Dementeva L.A., Petrova A.P., Serezhenkov A.A. Konstrukcionnye i termostojkie klei [Constructional and heat-resistant glues] // Aviacionnye materialy i tehnologii. 2012. №S. S. 328–335.
15. Sharova I.A., Petrova A.P. Obzor po materialam mezhdunarodnoj konferencii po kleyam i germetikam (WAC-2012, Franciya) [Review of world adhesive and sealant conference (WAC-2012, France] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №8. St. 06. Available at: http://www.viam-works.ru (accessed: June 19, 2017).
2. Kablov E.N. Aviatsionnoe materialovedenie v XXI veke. Perspektivy i zadachi [Aviation materials science in the XXI century. Perspectives and tasks] // Aviatsionnye materialy. Iz-brannye trudy «VIAM» 1932–2002. M.: VIAM, 2002. S. 23–47.
3. Grashhenkov D.V., Chursova L.V. Strategiya razvitiya kompozicionnyh i funkcionalnyh materialov [Strategy of development of composite and functional materials] // Aviacionnye materialy i tehnologii. 2012. №S. S. 231–242.
4. Petrova A.P. Povyshenie termostojkosti klejashhih sistem na osnove fenolformaldegidnyh oligomerov pri modifikacii karboranami [Increasing thermal resistance of the adhesive sys-tems based on phenol-formaldehyde oligomers with modification of the carborane] // Novosti materialovedenija. Nauka i tehnika: jelektron. nauch.-tehnich. zhurn. 2017. №1. St. 03. Available at: http://www.materialsnews.ru (accessed: June 27, 2017).
5. Petrova A.P. Laptev A.B. Termicheskaja ustojchivost karboransoderzhashhih klejashhih sistem na osnove fenolformaldegidnyh oligomerov [Thermal stability of karbor-ansoderzhashchy gluing systems on the basis of fenolformaldegidny oligomers] // Klei. Germetiki. Tehnologii. 2017. №7. S. 2–6.
6. Petrova A.P., Laptev A.B. Fenolno-kauchukovye klei, modificirovannye karboranami [The phenolic and rubber glues modified by carboranes] // Klei. Germetiki. Tehnologii. 2017. №6. S. 2–6.
7. Grajms R. Karborany [Carboranes]. Per. s angl. / pod red. A.F. Zhigacha. M.: Mir, 1974. 264 s.
8. Petrova A.P., Valeckij P.M. Fenolno-kauchukovye karboransoderzhashhie klei s sobstvennym ferromagnetizmom [Phenolic and rubber carborane containing glues with own ferromagnetizm] // Klei. Germetiki. Tehnologii. 2007. №4. S. 6–10.
9. Petrova A.P. Povyshenie termostojkosti poliuretanovyh klejashhih sistem pri modifikacii karboranami [Increase of thermal stability of polyurethane gluing systems when updating by carboranes] // Novosti materialovedenija. Nauka i tehnika: jelektron. nauch.-tehnich. zhurn. 2017. №1. St. 04. Available at: http://www.materialsnews.ru (accessed: June 27, 2017).
10. Petrova A.P., Laptev A.B. Termicheskaja ustojchivost karboransoderzhashhih poliuretanovyh klejashhih sistem [Thermal stability carborane of containing polyurethane gluing systems] // Klei. Germetiki. Tehnologii. 2017. №8. S. 2–5.
11. Lipatova T.Je., Bakalo L.A. Kinetika i mehanizm reakcij obrazovanija poliuretanov [Kinetics and mechanism of reactions of education poliuretanov] // Uspehi himii poliuretanov. Kiev: Naukova Dumka, 1972. S. 195–213.
12. Valeckij P.M., Petrova A.P. Polimernye klei na osnove karboransoderzhashhih soedinenij [Polymeric glues on basis carborane of containing connections] // Klei. Germetiki. Tehnologii. 2005. №3. S. 2–5.
13. Petrova A.P. Magnitoprovodjashhie kleevye kompozicii na osnove karboransoderzhashhih soedinenij [Magneto carrying-out glue compositions on basis carborane of containing con-nections] // Klei. Germetiki. Tehnologii. 2006. №11. S. 3–4.
14. Lukina N.F., Dementeva L.A., Petrova A.P., Serezhenkov A.A. Konstrukcionnye i termostojkie klei [Constructional and heat-resistant glues] // Aviacionnye materialy i tehnologii. 2012. №S. S. 328–335.
15. Sharova I.A., Petrova A.P. Obzor po materialam mezhdunarodnoj konferencii po kleyam i germetikam (WAC-2012, Franciya) [Review of world adhesive and sealant conference (WAC-2012, France] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №8. St. 06. Available at: http://www.viam-works.ru (accessed: June 19, 2017).
8.
№2, 2017
УДК 665.939.5
Petrova A.P.1
Heightening of thermal stability of glue at modification of organosilicone oligomers by carboranes
There are shown data of influence of carborane groups on properties of glue based on hetero-organic oligomers, are shown data of influence of isomer structure of carboranes group and data of influence of structure of siloxane oligomers on thermal stability of аdgesive joint.
The work has been executed by complex scientific direction 15.1. «Мultifunctional gluing systems» («Strategic direction of progress of materials and of refining technology thereof for the period till 2030»)
Keywords: methylphenylsiloxane, methylphenylcarboransiloxan, adhesives systems, thermal stability, thermal destruction, strength characteristics.
Reference List
1. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the develop-ment of materials and technologies of their processing for the period until 2030»] //Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
2. Grashhenkov D.V., Chursova L.V. Strategiya razvitiya kompozicionnyh i funkcionalnyh materialov [Strategy of development of composite and functional materials] // Aviacionnye materialy i tehnologii. 2012. №S. S. 231–242.
3. Petrova A.P., Lukina N.F., Dementeva L.A., Avdonina I.A., Tiumeneva T.Iu., Zhadova N.S. Klei dlia aviatsionnoi tekhniki [Glues for aviation engineering] // RZhKh. 2010. T. LIV. №1. S. 46–52.
4. Valetskii P.M., Petrova A.P. Polimernye klei na osnove karboransoderzhashchikh soedinenii [Polymeric glues on basis carborane of containing connections] // Klei. Germetiki. Tekhnologii. 2005. №3. S. 2–5.
5. Petrova A.P. Povyshenie termostoikosti kleiashchikh sistem na osnove fenolformaldegidnykh oligomerov pri modifikatsii karboranami [Increasing thermal resistance of the adhesive systems based on phenol-formaldehyde oligomers with modification of the carborane] // Novosti materialovedeniia. Nauka i tekhnika: elektron. nauch.-tekhnich. zhurn. 2017. №1. St. 03. Available at: http://www.materialsnews.ru (accessed: March 01, 2017).
6. Petrova A.P. Povyshenie termostoikosti poliuretanovykh kleiashchikh sistem pri modifika-tsii karboranami [Increasing thermal resistance of polyurethane adhesive systems with modification of the carborane] // Novosti materialovedeniia. Nauka i tekhnika: elektron. nauch.-tekhnich. zhurn. 2017. №1. St. 04. Available at: http://www.materialsnews.ru (accessed: March 01, 2017).
7. Graims R. Karborany. Per. s angl. [Carboranes. Trans. from Engl.] / pod red. A.F. Zhigacha. M.: Mir, 1974. 264 s.
8. Petrova A.P., Valetskii P.M. Fenolno-kauchukovye karboransoderzhashchie klei s sobstvennym ferromagnetizmom [Phenolic and rubber carborane containing glues with own ferro magnetism] // Klei. Germetiki. Tekhnologii. 2007. №4. S. 6–10.
9. Petrova A.P. Magnitoprovodiashchie kleevye kompozitsii na osnove karboransoderzhashchikh so-edinenii [Magneto carrying-out glue compositions on basis carborane of containing connections] // Klei. Germetiki. Tekhnologii. 2006. №11. S. 3–4.
10. Petrova A.P., Dementeva L.A., Lukina N.F., Anikhovskaia L.I. Plenochnye konstruktsionnye klei [Film constructional glues] // Klei. Germetiki. Tekhnologii. 2014. №10. S. 7–12.
11. Sharova I.A., Petrova A.P. Obzor po materialam mezhdunarodnoj konferencii po kleyam i germetikam (WAC-2012, Franciya) [Review of world adhesive and sealant conference (WAC-2012, France] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №8. St. 06. Available at: http://www.viam-works.ru (accessed: January 19, 2017).
12. Lukina N.F., Dementeva L.A., Petrova A.P., Serezhenkov A.A. Konstrukcionnye i termostojkie klei [Constructional and heat-resistant glues] // Aviacionnye materialy i tehnologii. 2012. №S. S. 328–335.
13. Petrova A.P., Laptev A.B. Fenolno-kauchukovye klei, modifitsirovannye karboranami [The phenolic and rubber glues modified by carboranes] // Klei. Germetiki. Tekhnologii. 2017. №6 (v pechati).
14. Petrova A.P., Donskoi A.A., Chalykh A.E., Shcherbina A.A. Kleiashchie materialy. Germetiki: spravochnik [Gluing materials. Hermetics: directory]. SPb.: Professional, 2008. 589 s.
15. Lukina N.F., Dementeva L.A., Petrova A.P., Tiumeneva T.Iu. Svoistva kleev i kleiashchikh materialov dlia izdelii aviatsionnoi tekhniki [Properties of glues and gluing materials for products of aviation engineering] // Klei. Germetiki. Tekhnologii. 2009. №1. S. 14–24.
2. Grashhenkov D.V., Chursova L.V. Strategiya razvitiya kompozicionnyh i funkcionalnyh materialov [Strategy of development of composite and functional materials] // Aviacionnye materialy i tehnologii. 2012. №S. S. 231–242.
3. Petrova A.P., Lukina N.F., Dementeva L.A., Avdonina I.A., Tiumeneva T.Iu., Zhadova N.S. Klei dlia aviatsionnoi tekhniki [Glues for aviation engineering] // RZhKh. 2010. T. LIV. №1. S. 46–52.
4. Valetskii P.M., Petrova A.P. Polimernye klei na osnove karboransoderzhashchikh soedinenii [Polymeric glues on basis carborane of containing connections] // Klei. Germetiki. Tekhnologii. 2005. №3. S. 2–5.
5. Petrova A.P. Povyshenie termostoikosti kleiashchikh sistem na osnove fenolformaldegidnykh oligomerov pri modifikatsii karboranami [Increasing thermal resistance of the adhesive systems based on phenol-formaldehyde oligomers with modification of the carborane] // Novosti materialovedeniia. Nauka i tekhnika: elektron. nauch.-tekhnich. zhurn. 2017. №1. St. 03. Available at: http://www.materialsnews.ru (accessed: March 01, 2017).
6. Petrova A.P. Povyshenie termostoikosti poliuretanovykh kleiashchikh sistem pri modifika-tsii karboranami [Increasing thermal resistance of polyurethane adhesive systems with modification of the carborane] // Novosti materialovedeniia. Nauka i tekhnika: elektron. nauch.-tekhnich. zhurn. 2017. №1. St. 04. Available at: http://www.materialsnews.ru (accessed: March 01, 2017).
7. Graims R. Karborany. Per. s angl. [Carboranes. Trans. from Engl.] / pod red. A.F. Zhigacha. M.: Mir, 1974. 264 s.
8. Petrova A.P., Valetskii P.M. Fenolno-kauchukovye karboransoderzhashchie klei s sobstvennym ferromagnetizmom [Phenolic and rubber carborane containing glues with own ferro magnetism] // Klei. Germetiki. Tekhnologii. 2007. №4. S. 6–10.
9. Petrova A.P. Magnitoprovodiashchie kleevye kompozitsii na osnove karboransoderzhashchikh so-edinenii [Magneto carrying-out glue compositions on basis carborane of containing connections] // Klei. Germetiki. Tekhnologii. 2006. №11. S. 3–4.
10. Petrova A.P., Dementeva L.A., Lukina N.F., Anikhovskaia L.I. Plenochnye konstruktsionnye klei [Film constructional glues] // Klei. Germetiki. Tekhnologii. 2014. №10. S. 7–12.
11. Sharova I.A., Petrova A.P. Obzor po materialam mezhdunarodnoj konferencii po kleyam i germetikam (WAC-2012, Franciya) [Review of world adhesive and sealant conference (WAC-2012, France] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №8. St. 06. Available at: http://www.viam-works.ru (accessed: January 19, 2017).
12. Lukina N.F., Dementeva L.A., Petrova A.P., Serezhenkov A.A. Konstrukcionnye i termostojkie klei [Constructional and heat-resistant glues] // Aviacionnye materialy i tehnologii. 2012. №S. S. 328–335.
13. Petrova A.P., Laptev A.B. Fenolno-kauchukovye klei, modifitsirovannye karboranami [The phenolic and rubber glues modified by carboranes] // Klei. Germetiki. Tekhnologii. 2017. №6 (v pechati).
14. Petrova A.P., Donskoi A.A., Chalykh A.E., Shcherbina A.A. Kleiashchie materialy. Germetiki: spravochnik [Gluing materials. Hermetics: directory]. SPb.: Professional, 2008. 589 s.
15. Lukina N.F., Dementeva L.A., Petrova A.P., Tiumeneva T.Iu. Svoistva kleev i kleiashchikh materialov dlia izdelii aviatsionnoi tekhniki [Properties of glues and gluing materials for products of aviation engineering] // Klei. Germetiki. Tekhnologii. 2009. №1. S. 14–24.
9.
№1, 2017
УДК 665.939.5
Petrova A.P.1
Increasing thermal resistance of polyurethane adhesive systems with modification of the carborane
Shows data on the effect of carborane groups on the properties of polyurethane adhesive systems, influence of the isomeric structure of carborane groups on the thermal resistance and other properties of the adhesive compositions, dependence of the strength of the adhesive joints from the structure included in the composition of the adhesive polyester carborane. The properties of polyurethane adhesives containing carborane VK-20, VK-20M, VK-20T and their applications are considered.
The work is done in the framework of the comprehensive research directions 15.1. multi-purpose adhesive systems («Strategic directions of development of materials and technologies of their reprocessing for the period till 2030»)
Keywords: adhesive, carborane, polyester carboranes, polyisocyanate, thermodestruction, internal stresses, adhesive bonding, performance characteristics, conductive properties.
Reference List
1. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the develop-ment of materials and technologies of their processing for the period until 2030»] //Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
2. Kablov E.N. Aviatsionnoe materialovedenie v XXI veke. Perspektivy i zadachi [Aviation materials science in the XXI century. Perspectives and tasks] // Aviatsionnye materialy. Izbrannye trudy «VIAM» 1932–2002. M.: VIAM, 2002. S. 23–47.
3. Petrova A.P. Povyshenie termostoikosti kleiashchikh sistem na osnove fenolformal-degidnykh oligomerov pri modifikatsii ikh karboranami [Increase of thermal stability of gluing systems on the basis of fenolformaldegidny oligomers when updating by their carboranes] // Novosti materialovedeniia. Nauka i tekhnika: elektron. nauch.-tekhnich. zhurn. 2017. №1. St. 03. Available at: http://www.materialsnews.ru.
4. Petrova A.P., Lukina N.F., Dementeva L.A., Avdonina I.A., Tiumeneva T.Iu., Zhadova N.S. Klei dlia aviatsionnoi tekhniki [Glues for aviation engineering] // RZhKh. 2010. T. LIV. №1. S. 46–52.
5. Petrova A.P., Dementeva L.A., Lukina N.F., Anikhovskaia L.I. Plenochnye konstruktsionnye klei [Film constructional glues] // Klei. Germetiki. Tekhnologii. 2014. №10. S. 7–12.
6. Graims R. Karborany. Per. s angl. [Carboranes. Trans. from Engl.] / pod red. A.F. Zhigacha. M.: Mir, 1974. 264 s.
7. Valetskii P.M., Petrova A.P. Polimernye klei na osnove karboransoderzhashchikh soedinenii [Polymeric glues on basis carborane of containing connections] // Klei. Germetiki. Tekhnologii. 2005. №3. S. 2–5.
8. Petrova A.P., Valetskii P.M. Fenolno-kauchukovye karboransoderzhashchie klei s sobstvennym ferromagnetizmom [Phenolic and rubber carborane containing glues with own ferromagnetizm] // Klei. Germetiki. Tekhnologii. 2007. №4. S. 6–10.
9. Petrova A.P. Magnitoprovodiashchie kleevye kompozitsii na osnove karboransoder-zhashchikh so-edinenii [Magneto carrying-out glue compositions on basis carborane of containing connections] // Klei. Germetiki. Tekhnologii. 2006. №11. S. 3–4.
10. Grashhenkov D.V., Chursova L.V. Strategiya razvitiya kompozicionnyh i funkcionalnyh materialov [Strategy of development of composite and functional materials] // Aviacionnye materialy i tehnologii. 2012. №S. S. 231–242.
11. Sharova I.A., Petrova A.P. Obzor po materialam mezhdunarodnoj konferencii po kleyam i germetikam (WAC-2012, Franciya) [Review of world adhesive and sealant conference (WAC-2012, France] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №8. St. 06. Available at: http://www.viam-works.ru (accessed: January 19, 2017).
12. Lukina N.F., Dementeva L.A., Petrova A.P., Serezhenkov A.A. Konstrukcionnye i termostojkie klei [Constructional and heat-resistant glues] // Aviacionnye materialy i tehnologii. 2012. №S. S. 328–335.
13. Petrova A.P. Fenolno-kauchukovye klei, modifitsirovannye karboranami [The phenolic and rubber glues modified by carboranes] // Klei. Germetiki. Tekhnologii. 2017 (v pechati).
14. Petrova A.P., Donskoi A.A., Chalykh A.E., Shcherbina A.A. Kleiashchie materialy. Germetiki: spravochnik [Gluing materials. Hermetics: directory]. SPb.: Professional, 2008. 589 s.
15. Kablov E.N., Minakov V.T., Anikhovskaya L.I. Klei i materialy na ikh osnove dlya remonta kon-struktsiy aviatsionnoy tekhniki [Glues and materials on their basis for repair of designs of aviation engineering] // Aviatsionnye materialy i tekhnologii. 2002. №1. S. 61–65.
16. Lukina N.F., Dementeva L.A., Petrova A.P., Tiumeneva T.Iu. Svoistva kleev i kleiashchikh materialov dlia izdelii aviatsionnoi tekhniki [Properties of glues and gluing materials for products of aviation engineering] // Klei. Germetiki. Tekhnologii. 2009. №1. S. 14–24.
2. Kablov E.N. Aviatsionnoe materialovedenie v XXI veke. Perspektivy i zadachi [Aviation materials science in the XXI century. Perspectives and tasks] // Aviatsionnye materialy. Izbrannye trudy «VIAM» 1932–2002. M.: VIAM, 2002. S. 23–47.
3. Petrova A.P. Povyshenie termostoikosti kleiashchikh sistem na osnove fenolformal-degidnykh oligomerov pri modifikatsii ikh karboranami [Increase of thermal stability of gluing systems on the basis of fenolformaldegidny oligomers when updating by their carboranes] // Novosti materialovedeniia. Nauka i tekhnika: elektron. nauch.-tekhnich. zhurn. 2017. №1. St. 03. Available at: http://www.materialsnews.ru.
4. Petrova A.P., Lukina N.F., Dementeva L.A., Avdonina I.A., Tiumeneva T.Iu., Zhadova N.S. Klei dlia aviatsionnoi tekhniki [Glues for aviation engineering] // RZhKh. 2010. T. LIV. №1. S. 46–52.
5. Petrova A.P., Dementeva L.A., Lukina N.F., Anikhovskaia L.I. Plenochnye konstruktsionnye klei [Film constructional glues] // Klei. Germetiki. Tekhnologii. 2014. №10. S. 7–12.
6. Graims R. Karborany. Per. s angl. [Carboranes. Trans. from Engl.] / pod red. A.F. Zhigacha. M.: Mir, 1974. 264 s.
7. Valetskii P.M., Petrova A.P. Polimernye klei na osnove karboransoderzhashchikh soedinenii [Polymeric glues on basis carborane of containing connections] // Klei. Germetiki. Tekhnologii. 2005. №3. S. 2–5.
8. Petrova A.P., Valetskii P.M. Fenolno-kauchukovye karboransoderzhashchie klei s sobstvennym ferromagnetizmom [Phenolic and rubber carborane containing glues with own ferromagnetizm] // Klei. Germetiki. Tekhnologii. 2007. №4. S. 6–10.
9. Petrova A.P. Magnitoprovodiashchie kleevye kompozitsii na osnove karboransoder-zhashchikh so-edinenii [Magneto carrying-out glue compositions on basis carborane of containing connections] // Klei. Germetiki. Tekhnologii. 2006. №11. S. 3–4.
10. Grashhenkov D.V., Chursova L.V. Strategiya razvitiya kompozicionnyh i funkcionalnyh materialov [Strategy of development of composite and functional materials] // Aviacionnye materialy i tehnologii. 2012. №S. S. 231–242.
11. Sharova I.A., Petrova A.P. Obzor po materialam mezhdunarodnoj konferencii po kleyam i germetikam (WAC-2012, Franciya) [Review of world adhesive and sealant conference (WAC-2012, France] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №8. St. 06. Available at: http://www.viam-works.ru (accessed: January 19, 2017).
12. Lukina N.F., Dementeva L.A., Petrova A.P., Serezhenkov A.A. Konstrukcionnye i termostojkie klei [Constructional and heat-resistant glues] // Aviacionnye materialy i tehnologii. 2012. №S. S. 328–335.
13. Petrova A.P. Fenolno-kauchukovye klei, modifitsirovannye karboranami [The phenolic and rubber glues modified by carboranes] // Klei. Germetiki. Tekhnologii. 2017 (v pechati).
14. Petrova A.P., Donskoi A.A., Chalykh A.E., Shcherbina A.A. Kleiashchie materialy. Germetiki: spravochnik [Gluing materials. Hermetics: directory]. SPb.: Professional, 2008. 589 s.
15. Kablov E.N., Minakov V.T., Anikhovskaya L.I. Klei i materialy na ikh osnove dlya remonta kon-struktsiy aviatsionnoy tekhniki [Glues and materials on their basis for repair of designs of aviation engineering] // Aviatsionnye materialy i tekhnologii. 2002. №1. S. 61–65.
16. Lukina N.F., Dementeva L.A., Petrova A.P., Tiumeneva T.Iu. Svoistva kleev i kleiashchikh materialov dlia izdelii aviatsionnoi tekhniki [Properties of glues and gluing materials for products of aviation engineering] // Klei. Germetiki. Tekhnologii. 2009. №1. S. 14–24.
10.
№1, 2017
УДК 665.939.5
Petrova A.P.1
Increasing thermal resistance of the adhesive systems based on phenol-formaldehyde oligomers with modification of the carborane
Shows the effect of carborane groups and their structure on thermal and thermooxidative degradation of phenol-formaldehyde, phenolic-elastomer and phenolic-silicone adhesive systems.
Work is executed within implementation of the complex scientific direction 15.1. «Multifunction gluing systems» («The strategic directions of development of materials and technologies of their processing for the period till 2030»)
Keywords: carborane, phenolic-elastomer adhesives, adhesive bonding, thermal resistance, thermodestruction, performance characteristics.
Reference List
1. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the develop-ment of materials and technologies of their processing for the period until 2030»] //Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
2. Petrova A.P., Lukina N.F., Dementeva L.A. i dr. Klei dlia aviatsionnoi tekhniki [Glues for aviation engineering] // RZhKh. 2010. T. LIV. №1. S. 46–52.
3. Petrova A.P., Dementeva L.A., Lukina N.F., Anikhovskaia L.I. Plenochnye konstruktsionnye klei [Film constructional glues] // Klei. Germetiki. Tekhnologii. 2014. №10. S. 7–12.
4. Graims R. Karborany. Per. s angl. [Carboranes. Trans. from Engl.] / pod red. A.F. Zhigacha. M.: Mir, 1974. 264 s.
5. Valetskii P.M., Petrova A.P. Polimernye klei na osnove karboransoderzhashchikh soedinenii [Polymeric glues on basis carborane of containing connections] // Klei. Germetiki. Tekhnologii. 2005. №3. S. 2–5.
6. Petrova A.P., Valetskii P.M. Fenolno-kauchukovye karboransoderzhashchie klei s sobstven-nym ferromagnetizmom [Phenolic and rubber carborane containing glues with own ferromagnetizm] // Klei. Germetiki. Tekhnologii. 2007. №4. S. 6–10.
7. Sharova I.A., Petrova A.P. Obzor po materialam mezhdunarodnoj konferencii po kleyam i germetikam (WAC-2012, Franciya) [Review of world adhesive and sealant conference (WAC-2012, France] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №8. St. 06. Available at: http://www.viam-works.ru (accessed: January 19, 2017).
8. Lukina N.F., Dementeva L.A., Petrova A.P., Serezhenkov A.A. Konstrukcionnye i termostojkie klei [Constructional and heat-resistant glues] // Aviacionnye materialy i tehnologii. 2012. №S. S. 328–335.
9. Petrova A.P. Magnitoprovodiashchie kleevye kompozitsii na osnove karboransoderzhashchikh so-edinenii [Magneto carrying-out glue compositions on basis carborane of containing connections] // Klei. Germetiki. Tekhnologii. 2006. №11. S. 3–4.
10. Grashchenkov D.V., Chursova L.V. Strategiia razvitiia kompozitsionnykh i funktsionalnykh ma-terialov [Strategy of development of composite and functional materials] // Aviatsionnye materialy i tekhnologii. 2012. №S. S. 231–242.
11. Petrova A.P. Fenolokauchukovye klei, modifitsirovannye karboranami [Phenol the rubber glues modified by carboranes] // Klei. Germetiki. Tekhnologii. 2017 (v pechati).
12. Petrova A.P., Donskoi A.A., Chalykh A.E., Shcherbina A.A. Kleiashchie materialy. Germetiki: spravochnik [Gluing materials. Hermetics: directory]. SPb.: Professional, 2008. 589 s.
13. Kablov E.N., Minakov V.T., Anikhovskaia L.I. Klei i materialy na ikh osnove dlia remonta kon-struktsii aviatsionnoi tekhniki [Glues and materials on their basis for repair of designs of aviation engineering] // Aviatsionnye materialy i tekhnologii. M.: VIAM, 2002. №1. S. 61–65.
14. Lukina N.F., Dementeva L.A., Petrova A.P., Tiumeneva T.Iu. Svoistva kleev i kleiashchikh materialov dlia izdelii aviatsionnoi tekhniki [Properties of glues and gluing materials for products of aviation engineering] // Klei. Germetiki. Tekhnologii. 2009. №1. S. 14–24.
15. Kablov E.N. Aviatsionnoe materialovedenie v XXI veke. Perspektivy i zadachi [Aviation materials science in the XXI century. Perspectives and tasks] // Aviatsionnye materialy. Izbrannye trudy VIAM 1932–2002. M.: MISIS–VIAM. 2002. S. 23–47.
2. Petrova A.P., Lukina N.F., Dementeva L.A. i dr. Klei dlia aviatsionnoi tekhniki [Glues for aviation engineering] // RZhKh. 2010. T. LIV. №1. S. 46–52.
3. Petrova A.P., Dementeva L.A., Lukina N.F., Anikhovskaia L.I. Plenochnye konstruktsionnye klei [Film constructional glues] // Klei. Germetiki. Tekhnologii. 2014. №10. S. 7–12.
4. Graims R. Karborany. Per. s angl. [Carboranes. Trans. from Engl.] / pod red. A.F. Zhigacha. M.: Mir, 1974. 264 s.
5. Valetskii P.M., Petrova A.P. Polimernye klei na osnove karboransoderzhashchikh soedinenii [Polymeric glues on basis carborane of containing connections] // Klei. Germetiki. Tekhnologii. 2005. №3. S. 2–5.
6. Petrova A.P., Valetskii P.M. Fenolno-kauchukovye karboransoderzhashchie klei s sobstven-nym ferromagnetizmom [Phenolic and rubber carborane containing glues with own ferromagnetizm] // Klei. Germetiki. Tekhnologii. 2007. №4. S. 6–10.
7. Sharova I.A., Petrova A.P. Obzor po materialam mezhdunarodnoj konferencii po kleyam i germetikam (WAC-2012, Franciya) [Review of world adhesive and sealant conference (WAC-2012, France] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №8. St. 06. Available at: http://www.viam-works.ru (accessed: January 19, 2017).
8. Lukina N.F., Dementeva L.A., Petrova A.P., Serezhenkov A.A. Konstrukcionnye i termostojkie klei [Constructional and heat-resistant glues] // Aviacionnye materialy i tehnologii. 2012. №S. S. 328–335.
9. Petrova A.P. Magnitoprovodiashchie kleevye kompozitsii na osnove karboransoderzhashchikh so-edinenii [Magneto carrying-out glue compositions on basis carborane of containing connections] // Klei. Germetiki. Tekhnologii. 2006. №11. S. 3–4.
10. Grashchenkov D.V., Chursova L.V. Strategiia razvitiia kompozitsionnykh i funktsionalnykh ma-terialov [Strategy of development of composite and functional materials] // Aviatsionnye materialy i tekhnologii. 2012. №S. S. 231–242.
11. Petrova A.P. Fenolokauchukovye klei, modifitsirovannye karboranami [Phenol the rubber glues modified by carboranes] // Klei. Germetiki. Tekhnologii. 2017 (v pechati).
12. Petrova A.P., Donskoi A.A., Chalykh A.E., Shcherbina A.A. Kleiashchie materialy. Germetiki: spravochnik [Gluing materials. Hermetics: directory]. SPb.: Professional, 2008. 589 s.
13. Kablov E.N., Minakov V.T., Anikhovskaia L.I. Klei i materialy na ikh osnove dlia remonta kon-struktsii aviatsionnoi tekhniki [Glues and materials on their basis for repair of designs of aviation engineering] // Aviatsionnye materialy i tekhnologii. M.: VIAM, 2002. №1. S. 61–65.
14. Lukina N.F., Dementeva L.A., Petrova A.P., Tiumeneva T.Iu. Svoistva kleev i kleiashchikh materialov dlia izdelii aviatsionnoi tekhniki [Properties of glues and gluing materials for products of aviation engineering] // Klei. Germetiki. Tekhnologii. 2009. №1. S. 14–24.
15. Kablov E.N. Aviatsionnoe materialovedenie v XXI veke. Perspektivy i zadachi [Aviation materials science in the XXI century. Perspectives and tasks] // Aviatsionnye materialy. Izbrannye trudy VIAM 1932–2002. M.: MISIS–VIAM. 2002. S. 23–47.
11.
№1, 2017
УДК 667.621:678.8
Lukina N.Ph.1, Moskvitin L.V.1
Multi-layer materials for compensation of gaps between constructive elements of units of aviation engineering
Domestic and foreign experiment on development of multi-layer materials of different structure and their application as compensators of gaps between constructive elements is provided at assembly operations of manufacturing of units from metal and non-metallic materials.
Work is executed within implementation of the complex scientific direction 15.1. «Multifunction gluing systems» («The strategic directions of development of materials and technologies of their processing for the period till 2030»)
Keywords: multi-layer material, glue structure, laying, the adjustable thickness, exfoliating layers.
Reference List
1. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the develop-ment of materials and technologies of their processing for the period until 2030»] //Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33
2. Kablov E.N. Strategicheskie napravleniya razvitiya materialov i tekhnologiy ikh pererabotki na period do 2030 goda [The strategic directions of development of materials and technologies of their processing for the period till 2030] // Aviatsionnye materialy i tekhnologii. 2012. №S. S. 7–17.
3. Grashhenkov D.V., Chursova L.V. Strategiya razvitiya kompozicionnyh i funkcionalnyh materialov [Strategy of development of composite and functional materials] // Aviacionnye materialy i tehnologii. 2012. №S. S. 231–242.
4. Lukina N.F., Anikhovskaya L.I., Dementeva L.A., Petpova A.P., Tyumeneva T.Yu. Klei i kleyashchie materialy dlya izdeliy aviatsionnoy tekhniki [Glues and gluing materials for products of aviation engineering] // Tekhnologiya mashinostroeniya. 2007. №6. S. 32–39.
5. Lukina N.F., Dementeva L.A., Anikhovskaya L.I. Kleevye prepregi dlya sloistykh alyumostekloplastikov klassa SIAL [Adhesive prepregs for alumo-glass laminate (SIAL)] // Trudy VIAM: elektron. nauch.-tekhnich. zhurnal. 2014. №1. St. 05. URL: http://www.viam-works.ru (accessed: September 20, 2016).DOI: 10.18577/2307-6046-2014-0-1-5-5.
6. Dementeva L.A., Serezhenkov A.A., Lukina N.F., Kucevich K.E. Kleevye prepregi i sloistye materialy na ih osnove [Adhesive prepregs and layered materials on their basis] // Aviacionnye materialy i tehnologii. 2013. №2. S. 19–21.
7. Antipov V.V., Senatorova O.G., Lukina N.F. i dr. Sloistye metallopolimernye kompozicionnye materialy [Layered metalpolymeric composite materials] // Aviacionnye materialy i tehnologii. 2012. №S. S. 226–230.
8. Kablov E.N., Antipov V.V., Senatorova O.G., Lukina N.F. Novyy klass sloistykh alyumostekloplastikov na osnove alyuminiy-litievogo splava 1441 s ponizhennoy plotnostyu [New class layered aluminum of fibreglasses on basis aluminum-lithium alloy 1441 with lowered density] // Vestnik Moskovskogo gosudarstvennogo tekhnicheskogo universiteta im. N.E. Baumana. Ser.: Mashinostroenie. 2011. № SP2. S. 174–183.
9. Fridlyander I.N., Senatorova O.G., Lukina N.F., Antipov V.V. Sloistye alyumopolimernye materialy SIAL [SIAL layered alyumopolimerny materials] // 75 let. Aviatsionnye materialy. Izbrannye trudy «VIAM» 1932–2007: yubileynyy nauch.-tekhnich. sb. M.: VIAM, 2007. S. 188–192.
10. Serebrennikova N.Yu., Antipov V.V., Senatorova O.G., Lukina N.F., Shestov V.V. Ispolzovanie kleevykh prepregov v sloistykh gibridnykh konstruktsiyakh na osnove alyuminiy-litievykh splavov i SIALa [Use of glue prepregs in layered hybrid designs on basis aluminum-lithium alloys and SIAL] // Novosti mate-rialovedeniya. Nauka i tekhnika: elektron. nauch.-tekhnich. zhurn. 2016. №3. St. 03. URL: http://www.materialsnews.ru (accessed: September 19, 2016).
11. Kablov E.N., Minakov V.T., Anikhovskaya L.I. Klei i materialy na ikh osnove dlya remonta konstruktsiy aviatsionnoy tekhniki [Glues and materials on their basis for repair of designs of aviation engineering] // Aviatsionnye materialy i tekhnologii. 2002. №1. S. 61–65.
12. Kleevaya kompozitsiya i samokleyashchiysya material, soderzhashchiy ee [Glue composition and the being self-glued material containing it]: pat. 2322470 Ros. Federatsiya; zayavl. 24.01.07; opubl. 20.04.08.
13. Kleevaya kompozitsiya i samokleyashchiysya material na ee osnove [Glue composition and being self-glued material on its basis]: pat. 2346970 Ros. Federatsiya; zayavl. 08.11.07; opubl. 20.02.09. Byul. №5 (ΙΙΙ ch).
14. Zhadova N.S., Tyumeneva T.Yu., Sharova I.A., Lukina N.F. Perspektivnye tekhnologii dlya vremennogo operativnogo remonta aviatsionnoy tekhniki [Perspective technologies for temporary operational repair of aviation engineering] // Aviatsionnye materialy i tekhnologii. 2013. №2. S. 67–70.
15. Sharova I.A., Zhadova N.S., Lukina N.F. Kleyashchie materialy i tekhnologii dlya vremennogo operativnogo remonta sotovykh agregatov iz polimernykh kompozitsionnykh materialov [Gluing materials and technologies for temporary operational repair of cellular units from polymeric composite materials] // Klei. Germetiki. Tekhnologii. 2012. №5. S. 36–39.
16. Zhadova N.S., Lukina N.F., Tyumeneva T.Yu. Samokleyash-chiesya materialy dlya vremennogo operativnogo remonta vneshney poverkh-nosti izdeliy aviatsionnoy tekhniki [Being self-glued materials for temporary operational repair of exterior surface of products of aviation engineering] // Klei. Germetiki. Tekhnologii. 2012. №6. S. 2–4.
2. Kablov E.N. Strategicheskie napravleniya razvitiya materialov i tekhnologiy ikh pererabotki na period do 2030 goda [The strategic directions of development of materials and technologies of their processing for the period till 2030] // Aviatsionnye materialy i tekhnologii. 2012. №S. S. 7–17.
3. Grashhenkov D.V., Chursova L.V. Strategiya razvitiya kompozicionnyh i funkcionalnyh materialov [Strategy of development of composite and functional materials] // Aviacionnye materialy i tehnologii. 2012. №S. S. 231–242.
4. Lukina N.F., Anikhovskaya L.I., Dementeva L.A., Petpova A.P., Tyumeneva T.Yu. Klei i kleyashchie materialy dlya izdeliy aviatsionnoy tekhniki [Glues and gluing materials for products of aviation engineering] // Tekhnologiya mashinostroeniya. 2007. №6. S. 32–39.
5. Lukina N.F., Dementeva L.A., Anikhovskaya L.I. Kleevye prepregi dlya sloistykh alyumostekloplastikov klassa SIAL [Adhesive prepregs for alumo-glass laminate (SIAL)] // Trudy VIAM: elektron. nauch.-tekhnich. zhurnal. 2014. №1. St. 05. URL: http://www.viam-works.ru (accessed: September 20, 2016).DOI: 10.18577/2307-6046-2014-0-1-5-5.
6. Dementeva L.A., Serezhenkov A.A., Lukina N.F., Kucevich K.E. Kleevye prepregi i sloistye materialy na ih osnove [Adhesive prepregs and layered materials on their basis] // Aviacionnye materialy i tehnologii. 2013. №2. S. 19–21.
7. Antipov V.V., Senatorova O.G., Lukina N.F. i dr. Sloistye metallopolimernye kompozicionnye materialy [Layered metalpolymeric composite materials] // Aviacionnye materialy i tehnologii. 2012. №S. S. 226–230.
8. Kablov E.N., Antipov V.V., Senatorova O.G., Lukina N.F. Novyy klass sloistykh alyumostekloplastikov na osnove alyuminiy-litievogo splava 1441 s ponizhennoy plotnostyu [New class layered aluminum of fibreglasses on basis aluminum-lithium alloy 1441 with lowered density] // Vestnik Moskovskogo gosudarstvennogo tekhnicheskogo universiteta im. N.E. Baumana. Ser.: Mashinostroenie. 2011. № SP2. S. 174–183.
9. Fridlyander I.N., Senatorova O.G., Lukina N.F., Antipov V.V. Sloistye alyumopolimernye materialy SIAL [SIAL layered alyumopolimerny materials] // 75 let. Aviatsionnye materialy. Izbrannye trudy «VIAM» 1932–2007: yubileynyy nauch.-tekhnich. sb. M.: VIAM, 2007. S. 188–192.
10. Serebrennikova N.Yu., Antipov V.V., Senatorova O.G., Lukina N.F., Shestov V.V. Ispolzovanie kleevykh prepregov v sloistykh gibridnykh konstruktsiyakh na osnove alyuminiy-litievykh splavov i SIALa [Use of glue prepregs in layered hybrid designs on basis aluminum-lithium alloys and SIAL] // Novosti mate-rialovedeniya. Nauka i tekhnika: elektron. nauch.-tekhnich. zhurn. 2016. №3. St. 03. URL: http://www.materialsnews.ru (accessed: September 19, 2016).
11. Kablov E.N., Minakov V.T., Anikhovskaya L.I. Klei i materialy na ikh osnove dlya remonta konstruktsiy aviatsionnoy tekhniki [Glues and materials on their basis for repair of designs of aviation engineering] // Aviatsionnye materialy i tekhnologii. 2002. №1. S. 61–65.
12. Kleevaya kompozitsiya i samokleyashchiysya material, soderzhashchiy ee [Glue composition and the being self-glued material containing it]: pat. 2322470 Ros. Federatsiya; zayavl. 24.01.07; opubl. 20.04.08.
13. Kleevaya kompozitsiya i samokleyashchiysya material na ee osnove [Glue composition and being self-glued material on its basis]: pat. 2346970 Ros. Federatsiya; zayavl. 08.11.07; opubl. 20.02.09. Byul. №5 (ΙΙΙ ch).
14. Zhadova N.S., Tyumeneva T.Yu., Sharova I.A., Lukina N.F. Perspektivnye tekhnologii dlya vremennogo operativnogo remonta aviatsionnoy tekhniki [Perspective technologies for temporary operational repair of aviation engineering] // Aviatsionnye materialy i tekhnologii. 2013. №2. S. 67–70.
15. Sharova I.A., Zhadova N.S., Lukina N.F. Kleyashchie materialy i tekhnologii dlya vremennogo operativnogo remonta sotovykh agregatov iz polimernykh kompozitsionnykh materialov [Gluing materials and technologies for temporary operational repair of cellular units from polymeric composite materials] // Klei. Germetiki. Tekhnologii. 2012. №5. S. 36–39.
16. Zhadova N.S., Lukina N.F., Tyumeneva T.Yu. Samokleyash-chiesya materialy dlya vremennogo operativnogo remonta vneshney poverkh-nosti izdeliy aviatsionnoy tekhniki [Being self-glued materials for temporary operational repair of exterior surface of products of aviation engineering] // Klei. Germetiki. Tekhnologii. 2012. №6. S. 2–4.
12.
№6, 2016
УДК 667.621.262.2
Rubtsova E.V.1, I.A. Sharova1, Petrova A.P.1
High-strength adhesive film based epoxy-polysulfon system
It shows that modification polysulfones improves adhesion and physicomechanical properties of epoxy adhesives. The properties of epoxy-polysulfon adhesive film, heat resistance, water resistance, artificial tropical conditions, long-term strength, vibration, air resistance are presrnts.
The work is executed within the implementation of the complex scientific direction 15.1. «Computer designing and modeling of compositions of cast and deformable alloys and steels, including natural composites and intermetallic compound, processes of their manufacturing and processing» («The strategic directions of development of materials and technologies of their processing for the period till 2030»)
Keywords: epoxy resin, polysulfon, adhesive, properties of adhesive joints, adhesive film, curing temperature.
Reference List
1. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the develop-ment of materials and technologies of their processing for the period until 2030»] //Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
2. Kochergin Yu.S., Grigorenko T.I., Kulik T.A. Svoystva epoksidnykh kleev, modifitsirovannykh oligosulfonami [Properties of the epoxy glues modified oligosulfonami] // Klei. Germetiki. Tekhnologii. 2005. №11. S. 3–7.
3. Dementeva L.A., Kutsevich K.E., Lukina N.F., Petrova A.P. Svoystva epoksidnykh konstruktsionnykh kleev, modifitsirovannykh polisulfonami [Properties of the epoxy constructional glues modified by polysulphones] // Klei. Germetiki. Tekhnologii. 2016. №11. S. 13–18.
4. Kablov E.N., Chursova L.V., Lukina N.F., Kutsevich K.E., Rubtsova E.V., Petrova A.P. Issledovanie epoksidno-polisulfonovykh sistem kak osnovy vysokoprochnykh kleev aviatsionnogo naznacheniya [Research of epoxy and polysulfonic systems as bases of high-strength adhesives of aviation assignment] // Klei. Germetiki. Tekhnologii. 2017. №2 (v pechati).
5. Petrova A.P., Lukina N.F., Dementeva L.A. i dr. Klei dlya aviatsionnoy tekhniki [Glues for aviation engineering] // RZhKh. 2010. T. LIV. №1. S. 46–52.
6. Petrova A.P., Dementeva L.A., Lukina N.F., Anikhovskaya L.I. Plenochnye konstruktsionnye klei [Film constructional glues] // Klei. Germetiki. Tekhnologii. 2014. №10. S. 7–12.
7. Dementeva L.A., Bocharova L.I., Lukina N.F., Petrova A.P. Mnogo-funtsionalnye epoksidnye klei dlya aviatsionnoy tekhniki [Much funtsionalny epoxy glues for aviation engineering] // Klei. Germetiki. Tekhnologii. 2006. №7. S. 18–20.
8. Grashchenkov D.V., Chursova L.V. Strategiya razvitiya kompozitsion-nykh i funktsionalnykh ma-terialov [Strategy of development of composite and functional materials] // Aviatsionnye materialy i tekhnologii. 2012. №S. S. 231–242.
9. Sharova I.A., Petrova A.P. Obzor po materialam mezhdunarodnoj konferencii po kleyam i germetikam (WAC-2012, Franciya) [Review of world adhesive and sealant conference (WAC-2012, France] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №8. St. 06. Available at: http://www.viam-works.ru (accessed: October 17, 2016).
10. Lukina N.F., Dementeva L.A., Petrova A.P., Tyumeneva T.Yu. Svoystva kleev i kleyashchikh materialov dlya izdeliy aviatsionnoy tekhniki [Properties of glues and gluing materials for products of aviation engineering] // Klei. Germetiki. Tekhnologii. 2009. №1. S. 14–24.
11. Lukina N.F., Dementeva L.A., Petrova A.P., Serezhenkov A.A. Konstrukcionnye i termostojkie klei [Constructional and heat-resistant glues] // Aviacionnye materialy i tehnologii. 2012. №S. S. 328–335.
12. Karimova S.A., Pavlovskaya T.G., Petrova A.P. Podgotovka po-verkhnosti alyuminievykh splavov s primeneniem anodnogo oksidirovaniya [Surface preparation of aluminum alloys using anodic oxidation] // Klei. Germetiki. Tekhnologii. 2014. №1. S. 34–38.
13. Petrova A.P., Lukina N.F. Primenenie adgezionnykh gruntov i sistem modifikatsii poverkhnosti pri skleivanii [Application of adhesive soil and systems of updating of surface when pasting] // Klei. Germetiki. Tekhnologii. 2013. №9. S. 24–28.
14. Petrova A.P. Osnovnye etapy tekhnologii skleivaniya [Main stages of technology of pasting] // Klei. Germetiki. Tekhnologii. 2014. №2. S. 24–30.
15. Kurshubadze I.V., Petrova A.P. Rabotosposobnost kleevykh soedi-neniy v usloviyakh morskikh subtropikov [Operability of glued joints in the conditions of sea subtropics] // Klei. Germetiki. Tekhnologii. 2005. №12. S. 14–17.
16. Petrova A.P., Lukina N.F., Sharova I.A. Otsenka prochnosti kleevykh soedineniy, vypolnennykh epoksidnymi kleyami, pri vozdeystvii razlichnykh faktorov [Assessment of durability of the glued joints executed by epoxy glues, at influence of different factors] // Vse materialy. Entsiklopedicheskiy spravochnik. 2013. №8. S. 28–34.
17. Dementeva L.A., Serezhenkov A.A., Lukina N.F., Kucevich K.E. Kleevye prepregi i sloistye materialy na ih osnove [Adhesive prepregs and layered materials on their basis] // Aviacionnye materialy i tehnologii. 2013. №2. S. 19–21.
18. Petrova A.P., Donskoy A.A., Chalykh A.E., Shcherbina A.A. Kleyashchie materialy. Germetiki: spravochnik [Gluing materials. Hermetics: directory]. SPb.: Professional, 2008. 589 s.
19. Kablov E.N., Minakov V.T., Anikhovskaya L.I. Klei i materialy na ikh osnove dlya remonta konstruktsiy aviatsionnoy tekhniki [Glues and materials on their basis for repair of designs of aviation engineering] // Aviatsionnye materialy i tekhnologii. 2002. №1. S. 61–65.
20. Kutsevich K.E., Dementeva L.A., Lukina N.F., Chursova L.V. Svoystva i naznacheniya kleya VK-36RM dlya aviatsionnoy tekhniki [Properties and glue assignments VK-36RM of aviation engineering] // Klei. Germetiki. Tekhnologii. 2013. №8. S. 5–6.
2. Kochergin Yu.S., Grigorenko T.I., Kulik T.A. Svoystva epoksidnykh kleev, modifitsirovannykh oligosulfonami [Properties of the epoxy glues modified oligosulfonami] // Klei. Germetiki. Tekhnologii. 2005. №11. S. 3–7.
3. Dementeva L.A., Kutsevich K.E., Lukina N.F., Petrova A.P. Svoystva epoksidnykh konstruktsionnykh kleev, modifitsirovannykh polisulfonami [Properties of the epoxy constructional glues modified by polysulphones] // Klei. Germetiki. Tekhnologii. 2016. №11. S. 13–18.
4. Kablov E.N., Chursova L.V., Lukina N.F., Kutsevich K.E., Rubtsova E.V., Petrova A.P. Issledovanie epoksidno-polisulfonovykh sistem kak osnovy vysokoprochnykh kleev aviatsionnogo naznacheniya [Research of epoxy and polysulfonic systems as bases of high-strength adhesives of aviation assignment] // Klei. Germetiki. Tekhnologii. 2017. №2 (v pechati).
5. Petrova A.P., Lukina N.F., Dementeva L.A. i dr. Klei dlya aviatsionnoy tekhniki [Glues for aviation engineering] // RZhKh. 2010. T. LIV. №1. S. 46–52.
6. Petrova A.P., Dementeva L.A., Lukina N.F., Anikhovskaya L.I. Plenochnye konstruktsionnye klei [Film constructional glues] // Klei. Germetiki. Tekhnologii. 2014. №10. S. 7–12.
7. Dementeva L.A., Bocharova L.I., Lukina N.F., Petrova A.P. Mnogo-funtsionalnye epoksidnye klei dlya aviatsionnoy tekhniki [Much funtsionalny epoxy glues for aviation engineering] // Klei. Germetiki. Tekhnologii. 2006. №7. S. 18–20.
8. Grashchenkov D.V., Chursova L.V. Strategiya razvitiya kompozitsion-nykh i funktsionalnykh ma-terialov [Strategy of development of composite and functional materials] // Aviatsionnye materialy i tekhnologii. 2012. №S. S. 231–242.
9. Sharova I.A., Petrova A.P. Obzor po materialam mezhdunarodnoj konferencii po kleyam i germetikam (WAC-2012, Franciya) [Review of world adhesive and sealant conference (WAC-2012, France] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №8. St. 06. Available at: http://www.viam-works.ru (accessed: October 17, 2016).
10. Lukina N.F., Dementeva L.A., Petrova A.P., Tyumeneva T.Yu. Svoystva kleev i kleyashchikh materialov dlya izdeliy aviatsionnoy tekhniki [Properties of glues and gluing materials for products of aviation engineering] // Klei. Germetiki. Tekhnologii. 2009. №1. S. 14–24.
11. Lukina N.F., Dementeva L.A., Petrova A.P., Serezhenkov A.A. Konstrukcionnye i termostojkie klei [Constructional and heat-resistant glues] // Aviacionnye materialy i tehnologii. 2012. №S. S. 328–335.
12. Karimova S.A., Pavlovskaya T.G., Petrova A.P. Podgotovka po-verkhnosti alyuminievykh splavov s primeneniem anodnogo oksidirovaniya [Surface preparation of aluminum alloys using anodic oxidation] // Klei. Germetiki. Tekhnologii. 2014. №1. S. 34–38.
13. Petrova A.P., Lukina N.F. Primenenie adgezionnykh gruntov i sistem modifikatsii poverkhnosti pri skleivanii [Application of adhesive soil and systems of updating of surface when pasting] // Klei. Germetiki. Tekhnologii. 2013. №9. S. 24–28.
14. Petrova A.P. Osnovnye etapy tekhnologii skleivaniya [Main stages of technology of pasting] // Klei. Germetiki. Tekhnologii. 2014. №2. S. 24–30.
15. Kurshubadze I.V., Petrova A.P. Rabotosposobnost kleevykh soedi-neniy v usloviyakh morskikh subtropikov [Operability of glued joints in the conditions of sea subtropics] // Klei. Germetiki. Tekhnologii. 2005. №12. S. 14–17.
16. Petrova A.P., Lukina N.F., Sharova I.A. Otsenka prochnosti kleevykh soedineniy, vypolnennykh epoksidnymi kleyami, pri vozdeystvii razlichnykh faktorov [Assessment of durability of the glued joints executed by epoxy glues, at influence of different factors] // Vse materialy. Entsiklopedicheskiy spravochnik. 2013. №8. S. 28–34.
17. Dementeva L.A., Serezhenkov A.A., Lukina N.F., Kucevich K.E. Kleevye prepregi i sloistye materialy na ih osnove [Adhesive prepregs and layered materials on their basis] // Aviacionnye materialy i tehnologii. 2013. №2. S. 19–21.
18. Petrova A.P., Donskoy A.A., Chalykh A.E., Shcherbina A.A. Kleyashchie materialy. Germetiki: spravochnik [Gluing materials. Hermetics: directory]. SPb.: Professional, 2008. 589 s.
19. Kablov E.N., Minakov V.T., Anikhovskaya L.I. Klei i materialy na ikh osnove dlya remonta konstruktsiy aviatsionnoy tekhniki [Glues and materials on their basis for repair of designs of aviation engineering] // Aviatsionnye materialy i tekhnologii. 2002. №1. S. 61–65.
20. Kutsevich K.E., Dementeva L.A., Lukina N.F., Chursova L.V. Svoystva i naznacheniya kleya VK-36RM dlya aviatsionnoy tekhniki [Properties and glue assignments VK-36RM of aviation engineering] // Klei. Germetiki. Tekhnologii. 2013. №8. S. 5–6.
