Articles
1.
УДК 669.018.44:669.245
Kapitanenko D.V.1, Razuvaev E.I.1, Sidorov S.A.1, Chebotareva E.S.2
INFLUENCE OF «WORKPIECE–TOOL» TEMPERATURE GRADIENT ON HOT DEFORMATION OF NICKEL-BASED SUPERALLOYS
Hardly-deformed heat-resistant nickel-based alloys have limited plasticity in narrow temperature interval of hot deformation and have a high sensitivity to the deformation rate.
The results of hardly-deformed heat-resistant nickel-based alloys rolling researches shows efficiency of using controlled rolls heating and thermal insulation coating.
Application of controlled rolls heating and glass enamel thermal insulation coating provides increase of technological plasticity, decrease of required technological force of deformation, decrease of deformed semi-finished products laboriousness and their quality improvement.
Keywords: heat-resistant nickel-based alloys, rolls, manufacturing process, technology, heating, plasticity, rolling.
Reference List
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2. Ponomarenko D.A., Moiseev N.V., Skugorev A.V. Shtampovka diskov GTD iz zharoprochnykh splavov na izotermicheskikh pressakh [Punching of disks GTD from hot strength alloys on isothermal presses] // Aviacionnye materialy i tekhnologii. 2013. №1. S. 13–16.
3. Bakradze M.M., Ovsepyan S.V., Shugaev S.A., Letnikov M.N. Vliyanie rezhimov zakalki na strukturu i svojstva shtampovok diskov iz zharoprochnogo nikelevogo splava EK151-ID [The influence of quenching on structure and properties nickel-based superalloy EK151-ID forgings] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №9. St. 01. Available at: http://www.viam-works.ru (accessed: February 1, 2018).
4. Kablov E.N. Razrabotki VIAM dlya gazoturbinnykh dvigateley i ustanovok [Development of VIAM for gas turbine engines and installations] // Krylya Rodiny. 2010. №4. S. 31–33.
5. Kablov E.N., Golubovskij E.R. Zharoprochnost nikelevyh splavov: ucheb. Posobie [Thermal stability of nickel alloys: manual]. M.: Mashinostroenie, 1998. 464 s.
6. Lomberg B.S., Ovsepjan S.V., Bakradze M.M. Osobennosti legirovaniya i termicheskoj obrabotki zharoprochnyh nikelevyh splavov dlja diskov gazoturbinnyh dvigatelej novogo pokolenija [Features of alloying and thermal processing of heat resisting nickel alloys for disks of gas turbine engines of new generation] //Aviacionnye materialy i tehnologii. 2010. №2. S. 3–8.
7. Kononov S.A., Lomberg B.S., Kolachev B.A., Nosov V.K. Obshhie principy termomehanicheskoj obrabotki pri izgotovlenii shtampovok diskov gazoturbinnyh dvigatelej iz vysokozharoprochnyh nikelevyh splavov [The general principles of thermomechanical processing when manufacturing punchings of disks of gas turbine engines from high-heat resisting nickel alloys] // Izvestija vuzov. Cvetnaja metallurgija. 2003. №2. C. 62–74.
8. Lomberg B.S., Bakradze M.M., Chabina E.B., Filonova E.V. Vzaimosvyaz struktury i svojstv vysokozharoprochnykh nikelevykh splavov dlya diskov gazoturbinnykh dvigatelej [Interrelation of structure and properties of high-heat resisting nickel alloys for disks of gas turbine engines] // Aviacionnye materialy i tekhnologii. 2011. №2. S. 25–30.
9. Razuvaev E.I., Bubnov M.V., Grigoreva G.A., Sidorov S.A. Razvitie i prakticheskoe primenenie fiziko-himicheskoj teorii v processah obrabotki davleniem aviacionnyh stalej i splavov [Development and practical application of the physical and chemical theory in processes of processing by pressure aviation stееls and alloys] // Novosti materialovedenija. Nauka i tehnika: jelektron. nauch.-tehnich. zhurn. 2015. №1. St. 07. Available at: http://www.materialsnews.ru (accessed: February 1, 2018).
10. Ponomarenko D.A., Skugorev A.V., Sidorov S.A., Shpagin A.S. Vliyanie teploobmena mezhdu zagotovkoj i shtampom na process shtampovki zagotovok detalej aviacionno-kosmicheskogo naznacheniya na specializirovannyh izotermicheksih pressah [Influence of heat exchange between workpiece and die on forming process of aerospace parts by special isothermal presses] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2016. №10. St. 03. Available at: http://www.viam-works.ru (accessed: February 1, 2018). DOI: 10.18577/2307-6046-2016-0-10-3-3.
11. Shilov V.I., Sirotin M.I. Opredelenie zon tverdenija i srednej temperatury polosy pri gorjachej prokatke [Definition of zones of solidification and average temperature of strip at hot rolling] // Tr. in-ta metallurgii AN SSSR. 1971. Vyp. 23. S. 34–39.
12. Razuvaev E.I., Moiseev N.V., Kapitanenko D.V., Bubnov M.V. Sovremennye tehnologii obrabotki metallov davleniem [Modern technologies of plastic working of metals] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №2. St. 03. Available at: http://www.viam-works.ru (accessed: February 1, 2018). DOI: 10.18577/2307-6046-2015-0-2-3-3.
13. Bubnov M.V., Sidorov S.A., Bazhenov A.R., Chebotareva E.S. Razvitie teorii i praktiki proizvodstva shtampovok diskov GTD iz geterofaznyh zharoprochnyh nikelevyh splavov [Development of the theory and practice of production of punchings of disks of from gas turbine engines of heterophase nickel-based superalloys] // Novosti materialovedenija. Nauka i tehnika: jelektron. nauch.-tehnich. zhurn. 2017. №2. St. 02. Available at: http://www.materialsnews.ru (accessed: February 1, 2018).
14. Ponomarenko D.A., Skugorev A.V., Sidorov S.A., Strokov V.V. Tehnologicheskie vozmozhnosti specializirovannyh izotermicheskih pressov siloj 6,3 i 16 MN v proizvodstve detalej aviacionno-kosmicheskogo naznachenija [Technological capabilities specialized isothermal pressov with a force of 6,3 and 16 MN in production of details of aerospace as-signment] // KShP OMD. 2015. №9. S. 36–41.
15. Kablov E.N., Lomberg B.S., Ospennikova O.G. Sozdanie sovremennykh zharoprochnykh materialov i tekhnologii ikh proizvodstva dlia aviatsionnogo dvigatelestroeniia [Creation of modern heat resisting materials and technologies of their production for aviation engine building] // Krylya Rodiny. 2012. №3–4. S. 34–38.
16. Vydrin V.N., Serdega Ju.P. Prokatnaja klet s chetyrehvalkovym kalibrom [Rolling cage with four-roller calibre] // Izvestija vuzov. Mashinostroenie, 1971. №3 S. 148–154.
17. Berezin E.N., Vydrin V.N., Tishhenko O.I. Novaja tehnologija poluchenija zagotovok iz stalej i splavov s nizkoj tehnologichnostju [New technology of receiving preparations from staly and alloys with low technological effectiveness] // Teorija i tehnologija prokatki. Sverdlovsk, 1972. №196. S. 62–69.
18. Pastuhov V.V., Barnov L.A. Jeksperimentalnye issledovanija kontaktnyh naprjazhenij pri prokatke v chetyrehvalkovyh kalibrah [Pilot studies of contact tension when rolling in four-roller calibres] // Prokatnoe proizvodstvo. Cheljabinsk, 1974. №130. S. 88–97.
19. Bulat S.I. Poverhnostnyj temperaturnyj jeffekt pri gorjachej prokatke [Surface temperature effect at hot rolling] // Sb. tr. CNIIChM. 1967. Vyp. 53. S. 54–58.
20. Ponomarenko D.A., Rozenenkova V.A., Skugorev A.V., Shishkov S.Ju. Jeffektivnoe ispolzovanie zashhitnyh tehnologicheskih pokrytij pri izotermicheskoj shtampovke na vozduhe tochnyh slozhnoprofilnyh detalej iz titanovyh splavov [Effective use of protective technological coverings at isothermal punching on air of exact slozhnoprofilny details from titanium alloys] // Kuznechno-shtampovochnoe proizvodstvo. 2014. №9. S. 44–48.
21. Solncev S.S. Kompleksnoe issledovanie zashhitno-tehnologicheskih pokrytij [Complex research of protective and technological coverings] // Aviacionnye materialy. 1977. №4. S. 11–28.
2. Ponomarenko D.A., Moiseev N.V., Skugorev A.V. Shtampovka diskov GTD iz zharoprochnykh splavov na izotermicheskikh pressakh [Punching of disks GTD from hot strength alloys on isothermal presses] // Aviacionnye materialy i tekhnologii. 2013. №1. S. 13–16.
3. Bakradze M.M., Ovsepyan S.V., Shugaev S.A., Letnikov M.N. Vliyanie rezhimov zakalki na strukturu i svojstva shtampovok diskov iz zharoprochnogo nikelevogo splava EK151-ID [The influence of quenching on structure and properties nickel-based superalloy EK151-ID forgings] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №9. St. 01. Available at: http://www.viam-works.ru (accessed: February 1, 2018).
4. Kablov E.N. Razrabotki VIAM dlya gazoturbinnykh dvigateley i ustanovok [Development of VIAM for gas turbine engines and installations] // Krylya Rodiny. 2010. №4. S. 31–33.
5. Kablov E.N., Golubovskij E.R. Zharoprochnost nikelevyh splavov: ucheb. Posobie [Thermal stability of nickel alloys: manual]. M.: Mashinostroenie, 1998. 464 s.
6. Lomberg B.S., Ovsepjan S.V., Bakradze M.M. Osobennosti legirovaniya i termicheskoj obrabotki zharoprochnyh nikelevyh splavov dlja diskov gazoturbinnyh dvigatelej novogo pokolenija [Features of alloying and thermal processing of heat resisting nickel alloys for disks of gas turbine engines of new generation] //Aviacionnye materialy i tehnologii. 2010. №2. S. 3–8.
7. Kononov S.A., Lomberg B.S., Kolachev B.A., Nosov V.K. Obshhie principy termomehanicheskoj obrabotki pri izgotovlenii shtampovok diskov gazoturbinnyh dvigatelej iz vysokozharoprochnyh nikelevyh splavov [The general principles of thermomechanical processing when manufacturing punchings of disks of gas turbine engines from high-heat resisting nickel alloys] // Izvestija vuzov. Cvetnaja metallurgija. 2003. №2. C. 62–74.
8. Lomberg B.S., Bakradze M.M., Chabina E.B., Filonova E.V. Vzaimosvyaz struktury i svojstv vysokozharoprochnykh nikelevykh splavov dlya diskov gazoturbinnykh dvigatelej [Interrelation of structure and properties of high-heat resisting nickel alloys for disks of gas turbine engines] // Aviacionnye materialy i tekhnologii. 2011. №2. S. 25–30.
9. Razuvaev E.I., Bubnov M.V., Grigoreva G.A., Sidorov S.A. Razvitie i prakticheskoe primenenie fiziko-himicheskoj teorii v processah obrabotki davleniem aviacionnyh stalej i splavov [Development and practical application of the physical and chemical theory in processes of processing by pressure aviation stееls and alloys] // Novosti materialovedenija. Nauka i tehnika: jelektron. nauch.-tehnich. zhurn. 2015. №1. St. 07. Available at: http://www.materialsnews.ru (accessed: February 1, 2018).
10. Ponomarenko D.A., Skugorev A.V., Sidorov S.A., Shpagin A.S. Vliyanie teploobmena mezhdu zagotovkoj i shtampom na process shtampovki zagotovok detalej aviacionno-kosmicheskogo naznacheniya na specializirovannyh izotermicheksih pressah [Influence of heat exchange between workpiece and die on forming process of aerospace parts by special isothermal presses] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2016. №10. St. 03. Available at: http://www.viam-works.ru (accessed: February 1, 2018). DOI: 10.18577/2307-6046-2016-0-10-3-3.
11. Shilov V.I., Sirotin M.I. Opredelenie zon tverdenija i srednej temperatury polosy pri gorjachej prokatke [Definition of zones of solidification and average temperature of strip at hot rolling] // Tr. in-ta metallurgii AN SSSR. 1971. Vyp. 23. S. 34–39.
12. Razuvaev E.I., Moiseev N.V., Kapitanenko D.V., Bubnov M.V. Sovremennye tehnologii obrabotki metallov davleniem [Modern technologies of plastic working of metals] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №2. St. 03. Available at: http://www.viam-works.ru (accessed: February 1, 2018). DOI: 10.18577/2307-6046-2015-0-2-3-3.
13. Bubnov M.V., Sidorov S.A., Bazhenov A.R., Chebotareva E.S. Razvitie teorii i praktiki proizvodstva shtampovok diskov GTD iz geterofaznyh zharoprochnyh nikelevyh splavov [Development of the theory and practice of production of punchings of disks of from gas turbine engines of heterophase nickel-based superalloys] // Novosti materialovedenija. Nauka i tehnika: jelektron. nauch.-tehnich. zhurn. 2017. №2. St. 02. Available at: http://www.materialsnews.ru (accessed: February 1, 2018).
14. Ponomarenko D.A., Skugorev A.V., Sidorov S.A., Strokov V.V. Tehnologicheskie vozmozhnosti specializirovannyh izotermicheskih pressov siloj 6,3 i 16 MN v proizvodstve detalej aviacionno-kosmicheskogo naznachenija [Technological capabilities specialized isothermal pressov with a force of 6,3 and 16 MN in production of details of aerospace as-signment] // KShP OMD. 2015. №9. S. 36–41.
15. Kablov E.N., Lomberg B.S., Ospennikova O.G. Sozdanie sovremennykh zharoprochnykh materialov i tekhnologii ikh proizvodstva dlia aviatsionnogo dvigatelestroeniia [Creation of modern heat resisting materials and technologies of their production for aviation engine building] // Krylya Rodiny. 2012. №3–4. S. 34–38.
16. Vydrin V.N., Serdega Ju.P. Prokatnaja klet s chetyrehvalkovym kalibrom [Rolling cage with four-roller calibre] // Izvestija vuzov. Mashinostroenie, 1971. №3 S. 148–154.
17. Berezin E.N., Vydrin V.N., Tishhenko O.I. Novaja tehnologija poluchenija zagotovok iz stalej i splavov s nizkoj tehnologichnostju [New technology of receiving preparations from staly and alloys with low technological effectiveness] // Teorija i tehnologija prokatki. Sverdlovsk, 1972. №196. S. 62–69.
18. Pastuhov V.V., Barnov L.A. Jeksperimentalnye issledovanija kontaktnyh naprjazhenij pri prokatke v chetyrehvalkovyh kalibrah [Pilot studies of contact tension when rolling in four-roller calibres] // Prokatnoe proizvodstvo. Cheljabinsk, 1974. №130. S. 88–97.
19. Bulat S.I. Poverhnostnyj temperaturnyj jeffekt pri gorjachej prokatke [Surface temperature effect at hot rolling] // Sb. tr. CNIIChM. 1967. Vyp. 53. S. 54–58.
20. Ponomarenko D.A., Rozenenkova V.A., Skugorev A.V., Shishkov S.Ju. Jeffektivnoe ispolzovanie zashhitnyh tehnologicheskih pokrytij pri izotermicheskoj shtampovke na vozduhe tochnyh slozhnoprofilnyh detalej iz titanovyh splavov [Effective use of protective technological coverings at isothermal punching on air of exact slozhnoprofilny details from titanium alloys] // Kuznechno-shtampovochnoe proizvodstvo. 2014. №9. S. 44–48.
21. Solncev S.S. Kompleksnoe issledovanie zashhitno-tehnologicheskih pokrytij [Complex research of protective and technological coverings] // Aviacionnye materialy. 1977. №4. S. 11–28.
2.
УДК 669.018.44:669.245
Treninkov I.A.1, Filonova E.V.1, Medvedev P.N.1, Lukina E.A.1
TEXTURE AND MICROSTRUCTURE FORMATION IN THE NICKEL-BASE SUPERALLOY DURING SELECTIVE LASER MELTING
The research of the texture and microstructure modification of the nickel-base superalloy ZHS6K-VI synthesised by the selective laser melting method with the different scan strategies (various speeds of scanning, power of a laser beam) was carried out by methods of X-ray and scanning electronic microscopy. The quantitative estimation of structure recrystallization the extent after selective laser melting was spend. The melting parameters influence on the structure changes was defined.
Keywords: selective laser melting (SLM), texture, nickel-base superalloy, γ/γ′-phases.
Reference List
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3. Shalin R.E., Svetlov I.L., Kachanov E.B. Monokristally nikelevyh zharoprochnyh splavov [Monocrystals of nickel hot strength alloys]. M.: Mashinostroenie, 1997. 336 s.
4. Sidorov V.V., Rigin V.E., Burcev V.T. Osobennosti vyplavki renijsoderzhashhih zharo-prochnyh splavov dlja litja monokristallicheskih lopatok GTD [Features of smelting of reniysoderzhashchy hot strength alloys for molding of single-crystal blades of GTЕ] // Aviacionnye materialy i tehnologii. M.: VIAM. 2004. Vyp.: Vysokorenievye zharoprochnye splavy, tehnologija i oborudovanie dlja proizvodstva splavov i litja monokristallicheskih tur-binnyh lopatok GTD. S. 72–80.
5. Gerasimov V.V. Ot monokristallicheskih neohlazhdaemyh lopatok k lopatkam turbin s pronikayushhim (transpiracionnym) ohlazhdeniem, izgotovlennym po additivnym tehnologiyam (obzor po tehnologii litya monokristallicheskih lopatok GTD) [From single-crystal uncooled blades to turbines blades with penetration (transpiration) cooling made by additive technologies (review on technology of single-crystal GTE bladescasting)] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2016. №10. St. 01. Available at: http://www.viam-works.ru (accessed: February 19, 2018). DOI: 10.18577/2307-6046-2016-0-10-1-1.
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2. Treninkov I.A., Alekseev A.A., Zaitsev D.V., Filonova E.V. Issledovaniia fazovykh i strukturnykh izmenenii, a takzhe ostatochnykh napriazhenii v protsesse vysokotemperaturnoi polzuchesti v splave VZhM4 [Researches of phase and structural changes, and also residual stresses in the course of high-temperature creep in VZhM4 alloy]// Aviatsionnye materialy i tekhnologii, 2011. №2. S. 11–19.
3. Shalin R.E., Svetlov I.L., Kachanov E.B. Monokristally nikelevyh zharoprochnyh splavov [Monocrystals of nickel hot strength alloys]. M.: Mashinostroenie, 1997. 336 s.
4. Sidorov V.V., Rigin V.E., Burcev V.T. Osobennosti vyplavki renijsoderzhashhih zharo-prochnyh splavov dlja litja monokristallicheskih lopatok GTD [Features of smelting of reniysoderzhashchy hot strength alloys for molding of single-crystal blades of GTЕ] // Aviacionnye materialy i tehnologii. M.: VIAM. 2004. Vyp.: Vysokorenievye zharoprochnye splavy, tehnologija i oborudovanie dlja proizvodstva splavov i litja monokristallicheskih tur-binnyh lopatok GTD. S. 72–80.
5. Gerasimov V.V. Ot monokristallicheskih neohlazhdaemyh lopatok k lopatkam turbin s pronikayushhim (transpiracionnym) ohlazhdeniem, izgotovlennym po additivnym tehnologiyam (obzor po tehnologii litya monokristallicheskih lopatok GTD) [From single-crystal uncooled blades to turbines blades with penetration (transpiration) cooling made by additive technologies (review on technology of single-crystal GTE bladescasting)] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2016. №10. St. 01. Available at: http://www.viam-works.ru (accessed: February 19, 2018). DOI: 10.18577/2307-6046-2016-0-10-1-1.
6. Zlenko M.A., Popovich A.A., Mutylina I.N. Additivnye tehnologi v mashinostroenii [The additive technologists in mechanical engineering]. SPb.: Izd-vo Politeh. un-ta, 2013. 222 s.
7. Yadroitsev I., Gusarov A., Yadroitsava I., Smurov I. Single track formation in selective laser melting of metal powders // Journal of Materials Processing Technology. 2010. Vol. 210. P. 1624–1631.
8. Murr L.E., Gaytan S.M., Ramirez D.A. et al. Metal fabrication by additivemanufacturing using laser and electron beam melting technologies // J. Mater. Sci. Technol. 2012. Vol. 28. P. 1–14.
9. Lukina E.A., Filonova E.V., Treninkov I.A. Mikrostruktura i preimushhestvennye kristallograficheskie orientirovki zharoprochnogo nikelevogo splava, sintezirovannogo metodom SLS, v zavisimosti ot energeticheskogo vozdejstviya i termoobrabotki [The microstructure and preferential crystallographic orientation of nickel superalloy, synthesized by SLM method, depending of the energy impact and heat treatment] // Aviacionnye materialy i tehnologii. 2017. №1 (46). S. 38–44. DOI: 10.18577/2071-9140-2017-0-1-38-44.
10. Ospennikova O.G., Orlov M.R., Avtaev V.V. Anizotropija uprugoplasticheskih harakteristik zharoprochnyh nikelevyh splavov – osnova konstruirovanija monokristallicheskih turbinnyh lopatok [Anisotropy of elasto-plastic characteristics of heat resisting nickel alloys – basis of designing of single-crystal turbine blades] // Deformacija i razrushenie materialov. 2013. №11. S. 12–19.
11. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] //Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
12. Kablov E.N. Tendentsii i orientiry innovatsionnogo razvitiya Rossii [Tendencies and reference points of innovative development of Russia]. M.: VIAM, 2015. 720 s.
13. Kablov E.N. Additivnye tehnologii – dominanta nacionalnoj tehnologicheskoj iniciativy [The additive technologies – dominant of national technological initiative] // Intellekt i tehnologii. 2015. №2 (11). S. 52–55.
14. Evgenov A.G., Nerush S.V., Vasilenko S.A. Poluchenie i oprobovanie melkodispersnogo metallicheskogo poroshka vysokohromistogo splava na nikelevoj osnove primenitelno k lazernoj LMD-naplavke [The obtaining and testing of the fine-dispersed metal powder of the high-chromium alloy on nickel-base for laser metal deposition] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2014. №5. St. 04. Available at: http://www.viam-works.ru (accessed: February 19, 2018). DOI: 10.18577/2307-6046-2014-0-5-4-4.
15. Vostrikov A.V., Suhov D.I. Proizvodstvo granul metodom PREP dlja additivnyh tehnologij – tekushhij status i perspektivy razvitija [The production of powders by PREP method for addictive manufacturing – current situation and development prospects] // Trudy VIAM: jelektron. nauch.-tehnich. zhurn. 2016. №8 (44). St. 03. Available at: http://www.viam-works.ru (accessed: February 19, 2018). DOI: 10.18577/2307-6046-2016-0-8-3
3.
УДК 669.018.44
Kochubey A.Ya.1, Zhuravleva P.L.1
TEXTURAL CONDITIONS DIAGRAMS OF NICKEL SUPERALLOY AND MAGNESIAN ALLOY AT HOT AXISYMMETRIC COMPRESSION
Axisymmetric hot compression experiments of nickel superalloy ЭК151 and MA5 alloy specimens in a wide temperatures and deformations intervals were carried out. Axial texture formation was studied by X-ray diffractometry methods. The complex studying method of texture forming depending on temperature and deformation was developed. The plotting method of textural diagrams is universal and is applicable for other based alloys.
Keywords: hot plastic deformation, axisymmetric compression, axial texture, pole figure,
X-ray diffractometry, textural condition diagrams.
Reference List
1. Borodkina M.M., Spektor Je.N. Rentgenograficheskij analiz tekstury metallov i splavov [Radiographic analysis of structure of metals and alloys]. M.: Metallurgija, 1981. 272 s.
2. Razuvaev E.I., Lebedev D.Yu., Bubnov M.V. Formirovanie ultramelkozernistoj i nanorazmernoj struktury v metallah i splavah metodami deformacii [Forming of ultrafine grained and nanodimensional structure in metals and alloys deformation methods] // Aviacionnye materialy i tehnologii. 2010. №3. S. 3–8.
3. Volkova E.F., Antipov V.V., Morozova G.I. Osobennosti formirovanija struktury i fazovogo sostava deformirovannyh polufabrikatov serijnogo splava MA14 [Features of forming of structure and phase structure of the deformed semi-finished products of serial alloy МА14] // Aviacionnye materialy i tehnologii. 2011. №3. S. 8–15.
4. Filonova E.V., Bakradze M.M., Kochubey A.Ya., Vavilin N.L. Issledovanie izmenenij strukturno-fazovogo sostoyaniya splava VZh175 v processe goryachej deformacii i termicheskoj obrabotki [Structural-phase evolution of VZH175-alloy during hot deformation and heat treatment] // Aviacionnye materialy i tehnologii. 2014. №3. S. 10–13. DOI: 10.18577/2071-9140-2014-0-3-10-13.
5. Lomberg B.S., Ovsepjan S.V., Bakradze M.M., Letnikov M.N., Mazalov I.S. Primenenie novyh deformiruemyh nikelevyh splavov dlja perspektivnyh gazoturbinnyh dvigatelej [The application of new wrought nickel alloys for advanced gas turbine engines] // Aviacionnye materialy i tehnologii. 2017. №S. S. 116–129. DOI: 10.18577/2071-9140-2017-0-S-116-129.
6. Mazalov I.S., Filonova E.V., Lomberg B.S. Formirovanie struktury pri deformacii i termicheskoj obrabotke zagotovok detalej iz nikelevogo vysokoprochnogo svarivaemogo splava VZh172 [Formation of microstructure of nickel weldable VGH172 superalloy in process of deformation and heat treatment of semi-finished products] // Trudy VIAM: jel-ektron. nauch.-tehnich. zhurn. 2013. №12. St. 01. Available at: http://www.viam-works.ru (accessed: January 26, 2018).
7. Kochubej A.Ja., Medvedev P.N. Primenenie prjamyh poljusnyh figur v issledovanijah processov strukturoobrazovanija pri nagrevah deformirovannyh metallov i splavov [Direct pole figures in the study of structure formation processes during heating of deformed metals and alloys] // Novosti materialovedenija. Nauka i tehnika. 2016. №5 (23). St. 02. Available at: http://www.materialsnews.ru (accessed: January 26, 2018).
8. Blohin N.N., Ovechkin B.I. Struktura i diagrammy strukturnyh sostojanij deformiruemyh magnievyh splavov [Structure and charts of structural conditions of deformable magnesium alloys] // Cvetnye metally. 1992. №11. S. 56–59.
9. Kochubej A.Ja., Medvedev P.N., Klochkov G.G., Avtaev V.V. Zakonomernosti teksturoobrazovanija pri ploskoj osadke splava sistemy Al–Cu–Li [Patterns education structure at flat deposit of alloy of Al–Cu–Li system] // Tehnologija legkih splavov. 2016. №1. S. 74–79.
10. Kochubej A.Ja., Serebrjanyj V.N. Vlijanie termomehanicheskih parametrov na formirovanie struktury i tekstury pri gorjachej deformacii splava Mg–Al–Zn [Influence of thermomechanical parameters on structure and structure forming at hot deformation of alloy of Mg–Al–Zn] // Tehnologija legkih splavov. 2007. №2. S. 105–109.
11. Serebrjanyj V.N., Kochubej A.Ja., Kurtasov S.F., Mel'nikov K.E. Teksturnye sostojanija gorjachedeformirovannogo magnievogo splava MA2-1 [Textural conditions of hot formed MA2-1 magnesium alloy] // Metally. 2007. №1. S. 87–93.
12. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the devel-op-ment of materials and technologies of their processing for the period until 2030»] //Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
13. Kablov E.N. Strategicheskie napravleniya razvitiya materialov i tekhnologiy ikh pererabotki na period do 2030 goda [The strategic directions of development of materials and technologies of their pro-cessing for the period till 2030] // Aviatsionnye materialy i tekhnologii. 2012. №S. S. 7–17.
14. Kablov E.N. Kontrol kachestva materialov – garantiya bezopasnosti ekspluatatsii aviatsionnoy tekhniki [Quality control of materials – security accreditation of operation of aviation engineering] // Aviatsionnye materialy i tekhnologii. 2001. №1. S. 3–8.
15. Kablov E.N. Aviatsionnoe materialovedenie v XXI veke. Perspektivy i zadachi [Aviation materials science in the XXI century. Perspectives and tasks] // Aviatsionnye materialy. Izbrannye trudy VIAM 1932–2002. M.: MISIS–VIAM. 2002. S. 23–47.
16. Vajnblat Ju.M. Diagrammy strukturnyh sostojanij i karty struktur aljuminievyh splavov [Charts of structural conditions and card of structures of aluminum alloys] // Izvestija AN SSSR. Ser.: Metally.1982. №2. S. 82–89.
17. Bubnov M.V., Skljarenko V.G. Formirovanie reglamentirovannoj struktury pri deformacii granulirovannogo splava JeP741NP [Forming of the regulated structure at deformation of granulated alloy ЭП741НП] // Tehnologija legkih splavov. 2007. №2 S. 54–55.
2. Razuvaev E.I., Lebedev D.Yu., Bubnov M.V. Formirovanie ultramelkozernistoj i nanorazmernoj struktury v metallah i splavah metodami deformacii [Forming of ultrafine grained and nanodimensional structure in metals and alloys deformation methods] // Aviacionnye materialy i tehnologii. 2010. №3. S. 3–8.
3. Volkova E.F., Antipov V.V., Morozova G.I. Osobennosti formirovanija struktury i fazovogo sostava deformirovannyh polufabrikatov serijnogo splava MA14 [Features of forming of structure and phase structure of the deformed semi-finished products of serial alloy МА14] // Aviacionnye materialy i tehnologii. 2011. №3. S. 8–15.
4. Filonova E.V., Bakradze M.M., Kochubey A.Ya., Vavilin N.L. Issledovanie izmenenij strukturno-fazovogo sostoyaniya splava VZh175 v processe goryachej deformacii i termicheskoj obrabotki [Structural-phase evolution of VZH175-alloy during hot deformation and heat treatment] // Aviacionnye materialy i tehnologii. 2014. №3. S. 10–13. DOI: 10.18577/2071-9140-2014-0-3-10-13.
5. Lomberg B.S., Ovsepjan S.V., Bakradze M.M., Letnikov M.N., Mazalov I.S. Primenenie novyh deformiruemyh nikelevyh splavov dlja perspektivnyh gazoturbinnyh dvigatelej [The application of new wrought nickel alloys for advanced gas turbine engines] // Aviacionnye materialy i tehnologii. 2017. №S. S. 116–129. DOI: 10.18577/2071-9140-2017-0-S-116-129.
6. Mazalov I.S., Filonova E.V., Lomberg B.S. Formirovanie struktury pri deformacii i termicheskoj obrabotke zagotovok detalej iz nikelevogo vysokoprochnogo svarivaemogo splava VZh172 [Formation of microstructure of nickel weldable VGH172 superalloy in process of deformation and heat treatment of semi-finished products] // Trudy VIAM: jel-ektron. nauch.-tehnich. zhurn. 2013. №12. St. 01. Available at: http://www.viam-works.ru (accessed: January 26, 2018).
7. Kochubej A.Ja., Medvedev P.N. Primenenie prjamyh poljusnyh figur v issledovanijah processov strukturoobrazovanija pri nagrevah deformirovannyh metallov i splavov [Direct pole figures in the study of structure formation processes during heating of deformed metals and alloys] // Novosti materialovedenija. Nauka i tehnika. 2016. №5 (23). St. 02. Available at: http://www.materialsnews.ru (accessed: January 26, 2018).
8. Blohin N.N., Ovechkin B.I. Struktura i diagrammy strukturnyh sostojanij deformiruemyh magnievyh splavov [Structure and charts of structural conditions of deformable magnesium alloys] // Cvetnye metally. 1992. №11. S. 56–59.
9. Kochubej A.Ja., Medvedev P.N., Klochkov G.G., Avtaev V.V. Zakonomernosti teksturoobrazovanija pri ploskoj osadke splava sistemy Al–Cu–Li [Patterns education structure at flat deposit of alloy of Al–Cu–Li system] // Tehnologija legkih splavov. 2016. №1. S. 74–79.
10. Kochubej A.Ja., Serebrjanyj V.N. Vlijanie termomehanicheskih parametrov na formirovanie struktury i tekstury pri gorjachej deformacii splava Mg–Al–Zn [Influence of thermomechanical parameters on structure and structure forming at hot deformation of alloy of Mg–Al–Zn] // Tehnologija legkih splavov. 2007. №2. S. 105–109.
11. Serebrjanyj V.N., Kochubej A.Ja., Kurtasov S.F., Mel'nikov K.E. Teksturnye sostojanija gorjachedeformirovannogo magnievogo splava MA2-1 [Textural conditions of hot formed MA2-1 magnesium alloy] // Metally. 2007. №1. S. 87–93.
12. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the devel-op-ment of materials and technologies of their processing for the period until 2030»] //Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
13. Kablov E.N. Strategicheskie napravleniya razvitiya materialov i tekhnologiy ikh pererabotki na period do 2030 goda [The strategic directions of development of materials and technologies of their pro-cessing for the period till 2030] // Aviatsionnye materialy i tekhnologii. 2012. №S. S. 7–17.
14. Kablov E.N. Kontrol kachestva materialov – garantiya bezopasnosti ekspluatatsii aviatsionnoy tekhniki [Quality control of materials – security accreditation of operation of aviation engineering] // Aviatsionnye materialy i tekhnologii. 2001. №1. S. 3–8.
15. Kablov E.N. Aviatsionnoe materialovedenie v XXI veke. Perspektivy i zadachi [Aviation materials science in the XXI century. Perspectives and tasks] // Aviatsionnye materialy. Izbrannye trudy VIAM 1932–2002. M.: MISIS–VIAM. 2002. S. 23–47.
16. Vajnblat Ju.M. Diagrammy strukturnyh sostojanij i karty struktur aljuminievyh splavov [Charts of structural conditions and card of structures of aluminum alloys] // Izvestija AN SSSR. Ser.: Metally.1982. №2. S. 82–89.
17. Bubnov M.V., Skljarenko V.G. Formirovanie reglamentirovannoj struktury pri deformacii granulirovannogo splava JeP741NP [Forming of the regulated structure at deformation of granulated alloy ЭП741НП] // Tehnologija legkih splavov. 2007. №2 S. 54–55.
4.
category: Testing of materials and structures
УДК 539.26
Kochubey A.Ya.1, Treninkov I.A.1
APPLICATION OF THE WHITE X-RADIATION IN THE STRUCTURAL ANALYSIS OF CRYSTAL MATERIALS
A crystal structure analysis of different materials by construction of pole figures in white (continuous spectrum) a X-radiation and them indicating was carried out. On polе figures types of crystal lattices and them crystal system was defined. Pole figures from metals with different type of a cubic lattice was built and analysed: silicon (a diamond lattice), molybdenum (body-centered) and nickel (face-centered).
Keywords: white X-radiation, X-ray crystal analysis, crystal structure, metal research.
Reference List
1. Arginbaeva E.G., Bazyleva O.A., Kolodochkina V.G., Khvatskij K.K. Vliyanie kristallograficheskoj orientacii na strukturu i fiziko-mehanicheskie svojstva intermetallidnogo splava na osnove Ni3Al [The influence of crystallographic oriental on structure, physical and mechanical properties of intermetallic alloys based on Ni3Al] // Aviacionnye materialy i tehnologii. 2013. №2. S. 3–7.
2. Kelli A., Grovs G. Kristallografija i defekty v kristallah [Crystallography and defects in crystals] / Per s angl S.N. Gorina, O.M. Kugaenko i V.S. Savchenko pod red. M.P. Shaskolskoj. M.: Mir, 1974. 504 s.
3. Van Bjuren. Defekty v kristallah [Defects in crystals]. Per s angl. / pod red A.N. Orlova i V.R. Regelja. M.: Inostr. lit., 1962. 584 s.
4. Novikov I.I., Rozin K.M. Kristallografija i defekty kristallicheskoj reshetki [Crystallography and defects of crystal lattice]: ucheb. dlja vuzov. M.: Metallurgija, 1990. 336 s.
5. Nazarkin R.M. Rentgenodifrakcionnye metodiki precizionnogo opredeleniya parametrov kristallicheskih reshetok nikelevyh zharoprochnyh splavov (kratkij obzor) [X-ray diffraction techniques for precise determination of lattice constants in Ni-based superalloys: a brief review] //Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 41–48.
6. Chabina E.B., Alekseev A.A., Filonova E.V., Lukina E.A. Primenenie metodov analiticheskoj mikroskopii i rentgenostrukturnogo analiza dlya issledovaniya strukturno-fazovogo sostoyaniya materialov [Application of methods of analytical microscopy and X-ray of the structural analysis for research of structural and phase condition of materials] //Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №5. St. 06. Available at: http://www.viam-works.ru (accessed: March 30, 2018).
7. Barret Ch.S., Massalskij T.B. Struktura metallov v 2 ch. [Structure of metals in 2 p.]. Per. s angl. M.: Metallurgija, 1984. Ch. 1. 352 s.
8. Boujen D.K., Tanner B.K. Vysokorazreshajushhaja rentgenovskaja difraktometrija i topografija [High-allowing x-ray diffractometry and topography] / Per. s angl. I.L. Shulpinoj i T.S. Argunovoj. SPb.: Nauka, 2002. 274 s.
9. Brandon D., Kaplan U. Mikrostruktura materialov. Metody issledovanija i kontrolja [Microstructure of materials. Research and control methods]. M.: Tehnosfera, 2004. 384 s.
10. Umanskij Ja.S., Skakov Ju.A., Novikov A.N., Rastorguev L.N. Kristallografija, rentgenografija i jelektronnaja mikroskopija [Crystallography, roentgenography and electron microscopy]. M.: Metallurgija, 1982. 632 s.
11. Gine A. Rentgenografija kristallov. Teorija i praktika [Roentgenography of crystals. Theory and practice]. Per. s fr. / pod red. N.V. Belova. M.: Gos. izd. fiz-mat. lit., 1961. 604 s.
12. Gorelik S.S., Skakov Ju.A., Rastorguev L.N. Rentgenograficheskij i jelektronno-opticheskij analiz [Radiographic and electron-optical analysis]: ucheb. posobie dlja vuzov. 4-e izd., dop. i pererab. M.: MISIS, 2002. 360 s.
13. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strate-gicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] //Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
14. Kablov E.N. Tendentsii i orientiry innovatsionnogo razvitiya Rossii [Tendencies and reference points of innovative development of Russia]. M.: VIAM, 2015. 720 s.
15. Kablov E.N. Additivnye tehnologii – dominanta nacionalnoj tehnologicheskoj iniciativy [The additive technologies – dominant of national technological initiative] // Intellekt i tehnologii. 2015. №2 (11). S. 52–55.
16. Treninkov I.A. Razrabotka rentgenovskih difrakcionnyh metodov kompleksnoj ocenki strukturnogo stroenija monokristallov zharoprochnyh nikelevyh splavov: avtoref. dis. ... kand. tehn. Nauk [Development of x-ray diffraction methods of complex assessment of structural structure of monocrystals of heat resisting nickel alloys: thesis cand. Sc. (Tech.)]. M., 2013. 25 s.
17. Kochubej A.Ja., Treninkov I.A. Opredelenie parametrov orientirovki monokristallov di-fraktometricheskim metodom [Definition single crystals orientation parametres of nickel-base superalloys by diffractometer method] // Novosti materialovedenija. Nauka i tehnika. 2017. №2 (26). St. 08. Available at: http://www.mterialsnews.ru (accessed: March 30, 2018).
2. Kelli A., Grovs G. Kristallografija i defekty v kristallah [Crystallography and defects in crystals] / Per s angl S.N. Gorina, O.M. Kugaenko i V.S. Savchenko pod red. M.P. Shaskolskoj. M.: Mir, 1974. 504 s.
3. Van Bjuren. Defekty v kristallah [Defects in crystals]. Per s angl. / pod red A.N. Orlova i V.R. Regelja. M.: Inostr. lit., 1962. 584 s.
4. Novikov I.I., Rozin K.M. Kristallografija i defekty kristallicheskoj reshetki [Crystallography and defects of crystal lattice]: ucheb. dlja vuzov. M.: Metallurgija, 1990. 336 s.
5. Nazarkin R.M. Rentgenodifrakcionnye metodiki precizionnogo opredeleniya parametrov kristallicheskih reshetok nikelevyh zharoprochnyh splavov (kratkij obzor) [X-ray diffraction techniques for precise determination of lattice constants in Ni-based superalloys: a brief review] //Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 41–48.
6. Chabina E.B., Alekseev A.A., Filonova E.V., Lukina E.A. Primenenie metodov analiticheskoj mikroskopii i rentgenostrukturnogo analiza dlya issledovaniya strukturno-fazovogo sostoyaniya materialov [Application of methods of analytical microscopy and X-ray of the structural analysis for research of structural and phase condition of materials] //Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №5. St. 06. Available at: http://www.viam-works.ru (accessed: March 30, 2018).
7. Barret Ch.S., Massalskij T.B. Struktura metallov v 2 ch. [Structure of metals in 2 p.]. Per. s angl. M.: Metallurgija, 1984. Ch. 1. 352 s.
8. Boujen D.K., Tanner B.K. Vysokorazreshajushhaja rentgenovskaja difraktometrija i topografija [High-allowing x-ray diffractometry and topography] / Per. s angl. I.L. Shulpinoj i T.S. Argunovoj. SPb.: Nauka, 2002. 274 s.
9. Brandon D., Kaplan U. Mikrostruktura materialov. Metody issledovanija i kontrolja [Microstructure of materials. Research and control methods]. M.: Tehnosfera, 2004. 384 s.
10. Umanskij Ja.S., Skakov Ju.A., Novikov A.N., Rastorguev L.N. Kristallografija, rentgenografija i jelektronnaja mikroskopija [Crystallography, roentgenography and electron microscopy]. M.: Metallurgija, 1982. 632 s.
11. Gine A. Rentgenografija kristallov. Teorija i praktika [Roentgenography of crystals. Theory and practice]. Per. s fr. / pod red. N.V. Belova. M.: Gos. izd. fiz-mat. lit., 1961. 604 s.
12. Gorelik S.S., Skakov Ju.A., Rastorguev L.N. Rentgenograficheskij i jelektronno-opticheskij analiz [Radiographic and electron-optical analysis]: ucheb. posobie dlja vuzov. 4-e izd., dop. i pererab. M.: MISIS, 2002. 360 s.
13. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strate-gicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] //Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
14. Kablov E.N. Tendentsii i orientiry innovatsionnogo razvitiya Rossii [Tendencies and reference points of innovative development of Russia]. M.: VIAM, 2015. 720 s.
15. Kablov E.N. Additivnye tehnologii – dominanta nacionalnoj tehnologicheskoj iniciativy [The additive technologies – dominant of national technological initiative] // Intellekt i tehnologii. 2015. №2 (11). S. 52–55.
16. Treninkov I.A. Razrabotka rentgenovskih difrakcionnyh metodov kompleksnoj ocenki strukturnogo stroenija monokristallov zharoprochnyh nikelevyh splavov: avtoref. dis. ... kand. tehn. Nauk [Development of x-ray diffraction methods of complex assessment of structural structure of monocrystals of heat resisting nickel alloys: thesis cand. Sc. (Tech.)]. M., 2013. 25 s.
17. Kochubej A.Ja., Treninkov I.A. Opredelenie parametrov orientirovki monokristallov di-fraktometricheskim metodom [Definition single crystals orientation parametres of nickel-base superalloys by diffractometer method] // Novosti materialovedenija. Nauka i tehnika. 2017. №2 (26). St. 08. Available at: http://www.mterialsnews.ru (accessed: March 30, 2018).
5.
УДК 620.197
Denisova V.S.1, Rozenenkova V.A.1, Agarkov A.B.1
HIGH TEMPERATURE GLASS CERAMIC COATING FOR HEAT RESISTANT NICKEL ALLOYS PROTECTION
The heat resistant glass ceramic coating was developed for heat resistant nickel alloy protection. The technology heat-resistant glass-ceramic coating fabrication was obtained for protection of combustion chambers made of high-strength weldable alloy. The main properties of heat resistant glass-ceramic coating were investigated, e.g. bonding strength, thermal stress resistance, heat resistance. Heat-resistant glass-ceramic coating fabrication is easy to provide, the coating is non-porous and fine for dimentional complex details.
Keywords: thermal stress resistance, heat resistance, coating, nickel alloy, hot corrosion, glass.
Reference List
1. Kablov E.N., Solncev S.S., Rozenenkova V.A., Mironova N.A. Sovremennye polifunkcional'nye vysokotemperaturnye pokrytija dlja nikelevyh splavov, uplotnitel'nyh metallicheskih materialov i berillievyh splavov [Modern multifunctional high temperature coatings for nickel alloys, sealing metal materials and beryllium alloys] // Novosti materialovedenija. Nauka i tehnika: jelektron. nauch.-tehnich. zhurn. 2013. №1. St. 05. Available at: http://www.materialsnews.ru (accessed: February 5, 2018).
2. Solncev S.S. Zashhitnye tehnologicheskie pokrytija i tugoplavkie jemali [Protective technological coverings and high-melting enamels]. M.: Mashinostroenie, 1984. 256 s.
3. Kablov E.N., Grashhenkov D.V., Isaeva N.V., Solncev S.S., Sevastjanov V.G. Vysokotemperaturnye konstrukcionnye kompozicionnye materialy na osnove stekla i keramiki dlja perspektivnyh izdelij aviacionnoj tehniki [High-temperature constructional composite materials on the basis of glass and ceramics for perspective products of aviation engineering] // Steklo i keramika. 2012. №4. S. 7–11.
4. Solncev S.S. Vysokotemperaturnye kompozicionnye materialy i pokrytija na osnove stekla i keramiki [High-temperature composite materials and coverings on the basis of glass and ceramics] // 75 let. Aviacionnye materialy. Izbrannye trudy «VIAM» 1932–2007: jubil. nauch.-tehnich. sb. M.: VIAM, 2007. S. 90–99.
5. Solncev S.S. Vysokotemperaturnye steklokeramicheskie materialy i pokrytija – perspektivnoe napravlenie aviacionnogo materialovedenija [High-temperature glass-ceramics materials and coverings – the perspective direction of aviation materials science] // Vse materialy. Jenciklopedicheskij spravochnik. 2009. №1. S. 26–37.
6. Solncev S.S., Denisova V.S., Rozenenkova V.A. Zharostojkie jemali dlja zashhity nikelevyh splavov i stalej [Heat resisting enamels for protection of nickel alloys and steels] // Vse materialy. Jenciklopedicheskij spravochnik. 2016. №1. S. 22–28.
7. Denisova V.S., Solncev S.St., Soloveva G.A. Stekloemalevye pokrytiya dlya zashhity korrozionnostojkih stalej ot vysokotemperaturnoj gazovoj korrozii: svojstva i oblasti primeneniya (obzor) [Glass enamel coatings for stainless steels protection against attacks of hot gas corrosion: properties and application fields (review)] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №5. St. 05. Available at: http://www.viam-works.ru (accessed: February 5, 2018). DOI: 10.18577/23071-6046-2015-0-5-5-5.
8. Denisova V.S., Solncev S.S., Soloveva G.A., Malinina G.A. Sovremennoe sostoyanie issledovanij v oblasti zharostojkih resursnyh pokrytij dlya nikelevyh i titanovyh splavov (obzor) [Current state of investigations in the field of heat-resistant coatings for nickel and titanium alloys (review)] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №4. St. 02. Available at: http://www.viam-works.ru (accessed: February 5, 2018). DOI: 10.18577/23071-6046-2015-0-4-2-2.
9. Solntsev S.S. Nekotorye osobennosti pokrytij dlya plitok mnogorazovoj teplozashhity orbitalnyh kosmicheskih korablej [Some features of coatings for tiles reusable heat-protection orbiting spacecraft] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2014. №2. St. 01. Available at: http://www.viam-works.ru (accessed: February 5, 2018). DOI: 10.18577/2307-6046-2014-0-2-1-1.
10. Solntsev S.S., Rozenenkova V.A., Mironova N.A., Soloveva G.A. Vysokotemperaturnye pokrytiya na osnove zol-gel tehnologii [High-temperature coatings on basis of sol-gel technology] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2014. №1. St. 03. Available at: http://www.viam-works.ru (accessed: February 5, 2018). DOI: 10.18577/2307-6046-2014-0-1-3-3.
11. Solncev S.S., Shvagireva V.V., Isaeva N.V., Soloveva G.A. Armirovannye zharostojkie steklojemali dlja kamer sgoranija gazoturbinnyh dvigatelej [Reinforced heat-resistant glass-enamels for combustion chambers of gas-turbine engines] // Aviacionnye materialy i tehnologii. 2010. №1. S. 26–29.
12. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
13. Lomberg B.S., Ovsepyan S.V., Bakradze M.M., Mazalov I.S. Vysokotemperaturnye zharoprochnye nikelevye splavy dlya detalej gazoturbinnyh dvigatelej [High-temperature heat resisting nickel alloys for details of gas turbine engines] // Aviacionnye materialy i tehnologii. 2012. №S.
S. 52–57.
14. Ovsepyan S.V., Lukina E.A., Filonova E.V., Mazalov I.S. Formirovanie uprochnyayushhej fazy v processe vysokotemperaturnogo azotirovaniya svarivaemogo zharoprochnogo deformiruemogo splava na osnove sistemy Ni–Co–Cr [Formation of the Strengthening Phase during the High-Temperature Nitriding of Ni–Co–Cr Weldable Wrought Superalloy] // Aviacionnye materialy i tehnologii. 2013. №1. S. 3–8.
15. Solntsev St.S., Rozenenkova V.A., Mironova N.A. Vysokotemperaturnye steklokeramicheskie pokrytiya i kompozicionnye materialy [The high-temperature glass ceramic coatings and composite materials] // Aviacionnye materialy i tehnologii. 2012. №S. S. 359–368.
16. Solntsev S.S., Shvagireva V.V., Isaeva N.V., Soloveva G.A. Zharostojkoe pokrytie dlya zashhity vysokoprochnyh slozhnolegirovannyh nikelevyh splavov ot vysokotemperaturnoj gazovoj korrozii [High temperature coating for protection of high-strength complex alloyed of nickel alloys of high-temperature gas corrosion] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2014. №6. St. 04. Available at: http://www.viam-works.ru (accessed: February 5, 2018). DOI: 10.18577/2307-6046-2014-0-6-4-4.
2. Solncev S.S. Zashhitnye tehnologicheskie pokrytija i tugoplavkie jemali [Protective technological coverings and high-melting enamels]. M.: Mashinostroenie, 1984. 256 s.
3. Kablov E.N., Grashhenkov D.V., Isaeva N.V., Solncev S.S., Sevastjanov V.G. Vysokotemperaturnye konstrukcionnye kompozicionnye materialy na osnove stekla i keramiki dlja perspektivnyh izdelij aviacionnoj tehniki [High-temperature constructional composite materials on the basis of glass and ceramics for perspective products of aviation engineering] // Steklo i keramika. 2012. №4. S. 7–11.
4. Solncev S.S. Vysokotemperaturnye kompozicionnye materialy i pokrytija na osnove stekla i keramiki [High-temperature composite materials and coverings on the basis of glass and ceramics] // 75 let. Aviacionnye materialy. Izbrannye trudy «VIAM» 1932–2007: jubil. nauch.-tehnich. sb. M.: VIAM, 2007. S. 90–99.
5. Solncev S.S. Vysokotemperaturnye steklokeramicheskie materialy i pokrytija – perspektivnoe napravlenie aviacionnogo materialovedenija [High-temperature glass-ceramics materials and coverings – the perspective direction of aviation materials science] // Vse materialy. Jenciklopedicheskij spravochnik. 2009. №1. S. 26–37.
6. Solncev S.S., Denisova V.S., Rozenenkova V.A. Zharostojkie jemali dlja zashhity nikelevyh splavov i stalej [Heat resisting enamels for protection of nickel alloys and steels] // Vse materialy. Jenciklopedicheskij spravochnik. 2016. №1. S. 22–28.
7. Denisova V.S., Solncev S.St., Soloveva G.A. Stekloemalevye pokrytiya dlya zashhity korrozionnostojkih stalej ot vysokotemperaturnoj gazovoj korrozii: svojstva i oblasti primeneniya (obzor) [Glass enamel coatings for stainless steels protection against attacks of hot gas corrosion: properties and application fields (review)] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №5. St. 05. Available at: http://www.viam-works.ru (accessed: February 5, 2018). DOI: 10.18577/23071-6046-2015-0-5-5-5.
8. Denisova V.S., Solncev S.S., Soloveva G.A., Malinina G.A. Sovremennoe sostoyanie issledovanij v oblasti zharostojkih resursnyh pokrytij dlya nikelevyh i titanovyh splavov (obzor) [Current state of investigations in the field of heat-resistant coatings for nickel and titanium alloys (review)] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №4. St. 02. Available at: http://www.viam-works.ru (accessed: February 5, 2018). DOI: 10.18577/23071-6046-2015-0-4-2-2.
9. Solntsev S.S. Nekotorye osobennosti pokrytij dlya plitok mnogorazovoj teplozashhity orbitalnyh kosmicheskih korablej [Some features of coatings for tiles reusable heat-protection orbiting spacecraft] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2014. №2. St. 01. Available at: http://www.viam-works.ru (accessed: February 5, 2018). DOI: 10.18577/2307-6046-2014-0-2-1-1.
10. Solntsev S.S., Rozenenkova V.A., Mironova N.A., Soloveva G.A. Vysokotemperaturnye pokrytiya na osnove zol-gel tehnologii [High-temperature coatings on basis of sol-gel technology] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2014. №1. St. 03. Available at: http://www.viam-works.ru (accessed: February 5, 2018). DOI: 10.18577/2307-6046-2014-0-1-3-3.
11. Solncev S.S., Shvagireva V.V., Isaeva N.V., Soloveva G.A. Armirovannye zharostojkie steklojemali dlja kamer sgoranija gazoturbinnyh dvigatelej [Reinforced heat-resistant glass-enamels for combustion chambers of gas-turbine engines] // Aviacionnye materialy i tehnologii. 2010. №1. S. 26–29.
12. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
13. Lomberg B.S., Ovsepyan S.V., Bakradze M.M., Mazalov I.S. Vysokotemperaturnye zharoprochnye nikelevye splavy dlya detalej gazoturbinnyh dvigatelej [High-temperature heat resisting nickel alloys for details of gas turbine engines] // Aviacionnye materialy i tehnologii. 2012. №S.
S. 52–57.
14. Ovsepyan S.V., Lukina E.A., Filonova E.V., Mazalov I.S. Formirovanie uprochnyayushhej fazy v processe vysokotemperaturnogo azotirovaniya svarivaemogo zharoprochnogo deformiruemogo splava na osnove sistemy Ni–Co–Cr [Formation of the Strengthening Phase during the High-Temperature Nitriding of Ni–Co–Cr Weldable Wrought Superalloy] // Aviacionnye materialy i tehnologii. 2013. №1. S. 3–8.
15. Solntsev St.S., Rozenenkova V.A., Mironova N.A. Vysokotemperaturnye steklokeramicheskie pokrytiya i kompozicionnye materialy [The high-temperature glass ceramic coatings and composite materials] // Aviacionnye materialy i tehnologii. 2012. №S. S. 359–368.
16. Solntsev S.S., Shvagireva V.V., Isaeva N.V., Soloveva G.A. Zharostojkoe pokrytie dlya zashhity vysokoprochnyh slozhnolegirovannyh nikelevyh splavov ot vysokotemperaturnoj gazovoj korrozii [High temperature coating for protection of high-strength complex alloyed of nickel alloys of high-temperature gas corrosion] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2014. №6. St. 04. Available at: http://www.viam-works.ru (accessed: February 5, 2018). DOI: 10.18577/2307-6046-2014-0-6-4-4.
6.
category: Functional and smart materials
УДК 620.197
Venediktova M.A.1, Krasnov L.L.1, Kirina Z.V.1
SOME ASPECTS OF APPLICATION OF FIREPROOF COVERINGS (review)
The current state of problem and perspective of production of fireproof coverings is considered. Major factors coverings of foaming type influencing fireproof efficiency are analyzed. Main types of fireproof coverings of domestic and foreign production, and world tendencies are given to developments of this direction. Aspects of creation of compounding of fireproof compositions are mentioned. Characteristics of perspective fireproof coverings intended for protection against overheat of constructive elements of aviation engineering developed by VIAM Federal State Unitary Enterprise are provided.
Keywords: fireproof pastes, fire retardant, intumescent fire protection coatings, fire protective material, thermal protection, foaming.
Reference List
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2. Gabdulin R.Sh. Jeffektivnye sposoby ognezashhity stroitelnyh konstrukcij [Effective ways fire protection of construction designs] // Bezopasnost. 2011. №1. S. 48–49.
3. Krasheninnikova M.V. Ognezashhitnye vspuchivajushhiesja materialy na osnove organorastvorimyh plenkoobrazovatelej [Fire protection swelling-up materials on the basis of solvent borne film former] // Lakokrasochnye materialy. 2006. №12. S. 14–16.
4. Kucherenko V.A. Posobie po opredeleniju predelov ognestojkosti konstrukcii [Grant by definition of limits of fire resistance of design]. M.: CNIIISK, 1985. 65 s.
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10. Eliseev O.A., Naumov I.S., Smirnov D.N., Bryk Ja.A. Reziny, germetiki i ogne-teplozashhitnye materialy [Rubbers, sealants, fireproof and heat-shielding materials] // Aviacionnye materialy i tehnologii. 2017. №S. S. 437–451. DOI: 10.18577/2071-9140-2017-0-S-437-451.
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19. High-temperature-resistant heat insulation coating: pat. 103881426 CN; publ. 25.06.14.
20. Reinforcement system for mastic intumescent fire protection coatings: pat. 5580648 US; publ. 03.12.96.
21. Fire-resistant coating material ADINA: pat. 2012115595 WO; publ. 30.08.12.
22. Fire retardant intumescent coating: pat. 7217753 US; publ. 12.05.07.
23. Low density, light weight intumescent coating: pat. 6096812 US; publ. 01.08.00.
24. Intumescent fireproof coating comprising a phosphorous/nitrogen-fire retardant and phosphinic acid salt: pat. 1627896 DK; publ. 30.06.08.
25. Fire protection composition, methods, and articles: pat. 2011023748 US; publ. 03.02.11.
26. Endothermic fire protective material: pat. 0281226 EP; publ. 07.09.88.
27. Fire, heat and backdraft protection shield for firefighters: pat. 6048805 US; publ. 11.04.20.
28. Ognezashhitnoe pokrytie: pat. 2265631 Ros. Federacija; zajavl [Fire protection cover: pat. 2265631 Rus. Federation]. 10.06.20; opubl. 10.12.05, Bjul. №4. 4 s.
29. Sloistoe vspuchivajushheesja ognezashhitnoe pokrytie: pat. 2103295 Ros. Federacija [Layered swelling-up fire protection covering: pat. 103295 Rus. Federation]; opubl. 27.01.98, Bjul. №4. 6 s.
30. Sposob poluchenija ognezashhitnoj vspuchivajushhejsja kompozicii: pat. 2492200 Ros. Federacija [Way of receiving fire protection swelling-up composition: pat. 2492200 Rus. Federation]; zajavl. 08.04.11; opubl. 10.09.13, Bjul. №5. 7 s.
31. Sostav kraski ognezashhitnoj atmosferostojkoj: pat. 2313548 Ros. Federacija [Composition of paint of the fire protection weatherproof: pat. 2313548 Rus. Federation]; zajavl. 12.09.06; opubl. 27.12.07, Bjul. №4. 4 s.
32. Ognezashhitnyj vpuchivajushhijsja sostav: pat. 2317274 Ros. Federacija [Fire protection swelling-up structure: pat. 2317274 Rus. Federation]; zajavl. 31.10.05; opubl. 20.02.08, Bjul. №3. 8 s.
33. Ognezashhitnaja vspuchivajushhajasja kraska: pat. 2224775 Ros. Federacija [Fire protection swelling-up paint: pat. 2224775 Rus. Federation]; zajavl. 17.04.03; opubl. 20.02.04, Bjul. №4. 5 s.
34. Ognezashhitnaja vspuchivajushhajasja jemal: pat. 2177973 Ros. Federacija [Fire protection swelling-up enamel: pat. 2177973 Rus. Federation]; zajavl. 13.07.99; opubl. 10.01.02, Bjul. №4. 5 s.
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2. Gabdulin R.Sh. Jeffektivnye sposoby ognezashhity stroitelnyh konstrukcij [Effective ways fire protection of construction designs] // Bezopasnost. 2011. №1. S. 48–49.
3. Krasheninnikova M.V. Ognezashhitnye vspuchivajushhiesja materialy na osnove organorastvorimyh plenkoobrazovatelej [Fire protection swelling-up materials on the basis of solvent borne film former] // Lakokrasochnye materialy. 2006. №12. S. 14–16.
4. Kucherenko V.A. Posobie po opredeleniju predelov ognestojkosti konstrukcii [Grant by definition of limits of fire resistance of design]. M.: CNIIISK, 1985. 65 s.
5. Kablov E.N. Aviakosmicheskoe materialovedenie [Aerospace materials science] // Vse materialy. Entsiklopedicheskiy spravochnik. 2008. №3. S. 2–14.
6. Kablov E.N. Khimiya v aviatsionnom materialovedenii [Chemistry in aviation materials science] // Rossiyskiy khimicheskiy zhurnal. 2010. T. LIV. №1. S. 3–4.
7. Kablov E.N., Shchetanov B.V., Ivahnenko Yu.A., Balinova Yu.A. Perspektivnye armiruyushhie vysokotemperaturnye volokna dlya metallicheskih i keramicheskih kompozicionnyh materialov [Perspective reinforcing high-temperature fibers for metal and ceramic composite materials] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №2. St. 05. Available at: http://www.viam-works.ru (accessed: December 11, 2017).
8. Pavlovich A.V., Vladenkov V.V., Izjumskij V.N., Kilchickaja S.L. Ognezashhitnye vspuchivajushhiesja pokrytija [Fire protection swelling-up coverings] // Lakokrasochnaja promyshlennost. 2012. №5. S. 22–27.
9. Polimernye materialy ponizhennoj gorjuchesti: materialy IV Mezhdunar. konf. [Polymeric materials of the lowered combustibility: materials IV of the International conference] / VOLG GTU. Volgograd, 2000. 196 s.
10. Eliseev O.A., Naumov I.S., Smirnov D.N., Bryk Ja.A. Reziny, germetiki i ogne-teplozashhitnye materialy [Rubbers, sealants, fireproof and heat-shielding materials] // Aviacionnye materialy i tehnologii. 2017. №S. S. 437–451. DOI: 10.18577/2071-9140-2017-0-S-437-451.
11. Nefedov N.I., Semenova L.V., Kuznecova V.A., Vereninova N.P. Lakokrasochnye pokrytiya dlya zashhity metallicheskih i polimernyh kompozicionnyh materialov ot stareniya, korrozii i biopovrezhdeniya [Paint coatings for protection of metallic and polymer composite materials against aging, corrosion and biodeterioration] // Aviacionnye materialy i tehnologii. 2017. №S. S. 393–404. DOI: 10.18577/2071-9140-2017-0-S-393-404.
12. Semenova L.V., Malova N.E., Kuznetsova V.A., Pozhoga A.A. Lakokrasochnye materialy i pokrytiya [Paint and varnish materials and coatings] // Aviacionnye materialy i tehnologii. 2012. №S. S. 315–327.
13. Parahin I.V., Tumanov A.S. Vlijanie kislorodsoderzhashhih soedinenij bora na svojstva teplozashhitnyh pokrytij [An influence of oxygen-bearing boron compounds on properties of thermal barrier coatings] // Aviacionnye materialy i tehnologii. 2014. №2. S. 40–43. DOI: DOI: 10.18577/2071-9140-2014-0-2-40-43.
14. Krasnov L.L., Kirina Z.V. Materialy, obespechivajushhie nadezhnost raboty konstruktivnyh jelementov v uslovijah pozhara [The materials providing reliability of work of constructive elements in the conditions of fire] // Vse materialy. Jenciklopedicheskij spravochnik. 2012. №10. S. 48–52.
15. Kablov E.N. Materialy novogo pokolenija [Materials of new generation] // Zashhita i bezopasnost. 2014. №4. S. 28–29.
16. Aseeva R.M., Zaikov G.E. Gorenie polimernyh materialov [Burning of polymeric materials]. M.: Nauka, 193 s.
17. Jakovlev A.D., Jakovlev S.A. Lakokrasochnye pokrytija funkcionalnogo naznachenija [Paint coatings of functional purpose]. SPb.: Himizdat, 2016. 272.
18. Rojtman V.M., Gabdulin R.Sh., Shherbina S.V. Mehanizm formirovanija ognezashhitnogo jeffekta vspuchivajushhihsja pokrytij zhelezobetonnyh konstrukcij pri ih nagreve [The mechanism of forming fire protection effect of swelling-up coverings of steel concrete designs at their heating] // Nauka i bezopasnost. 2012. №4. S. 40–50.
19. High-temperature-resistant heat insulation coating: pat. 103881426 CN; publ. 25.06.14.
20. Reinforcement system for mastic intumescent fire protection coatings: pat. 5580648 US; publ. 03.12.96.
21. Fire-resistant coating material ADINA: pat. 2012115595 WO; publ. 30.08.12.
22. Fire retardant intumescent coating: pat. 7217753 US; publ. 12.05.07.
23. Low density, light weight intumescent coating: pat. 6096812 US; publ. 01.08.00.
24. Intumescent fireproof coating comprising a phosphorous/nitrogen-fire retardant and phosphinic acid salt: pat. 1627896 DK; publ. 30.06.08.
25. Fire protection composition, methods, and articles: pat. 2011023748 US; publ. 03.02.11.
26. Endothermic fire protective material: pat. 0281226 EP; publ. 07.09.88.
27. Fire, heat and backdraft protection shield for firefighters: pat. 6048805 US; publ. 11.04.20.
28. Ognezashhitnoe pokrytie: pat. 2265631 Ros. Federacija; zajavl [Fire protection cover: pat. 2265631 Rus. Federation]. 10.06.20; opubl. 10.12.05, Bjul. №4. 4 s.
29. Sloistoe vspuchivajushheesja ognezashhitnoe pokrytie: pat. 2103295 Ros. Federacija [Layered swelling-up fire protection covering: pat. 103295 Rus. Federation]; opubl. 27.01.98, Bjul. №4. 6 s.
30. Sposob poluchenija ognezashhitnoj vspuchivajushhejsja kompozicii: pat. 2492200 Ros. Federacija [Way of receiving fire protection swelling-up composition: pat. 2492200 Rus. Federation]; zajavl. 08.04.11; opubl. 10.09.13, Bjul. №5. 7 s.
31. Sostav kraski ognezashhitnoj atmosferostojkoj: pat. 2313548 Ros. Federacija [Composition of paint of the fire protection weatherproof: pat. 2313548 Rus. Federation]; zajavl. 12.09.06; opubl. 27.12.07, Bjul. №4. 4 s.
32. Ognezashhitnyj vpuchivajushhijsja sostav: pat. 2317274 Ros. Federacija [Fire protection swelling-up structure: pat. 2317274 Rus. Federation]; zajavl. 31.10.05; opubl. 20.02.08, Bjul. №3. 8 s.
33. Ognezashhitnaja vspuchivajushhajasja kraska: pat. 2224775 Ros. Federacija [Fire protection swelling-up paint: pat. 2224775 Rus. Federation]; zajavl. 17.04.03; opubl. 20.02.04, Bjul. №4. 5 s.
34. Ognezashhitnaja vspuchivajushhajasja jemal: pat. 2177973 Ros. Federacija [Fire protection swelling-up enamel: pat. 2177973 Rus. Federation]; zajavl. 13.07.99; opubl. 10.01.02, Bjul. №4. 5 s.
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7.
category: Composite materials
УДК 667.621
Petrova A.P.1, Lukina N.Ph.1, Kotova E.V.1, Melnikov D.A.1
ADHESIVE BINDERS FOR POLYMER AND LAYERED ALUMINIUMPOLYMER COMPOSITE MATERIALS
Here are physical and mechanical properties, rheological properties of adhesive binders of melting type. Here are next properties: tensile strength, bending strength, relative extension, fracture viscosity, glass transition temperature, modulus of elasticity under tension and bending. Shown the influence of selected technology for processing of binder to demands for rheological properties.
Keywords: binders, adhesive binders, strength of adhesive bonds, rheological properties, physic and mechanical properties, technology for processing of binder in Polymer Composite Materials.
Reference List
1. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] //Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
2. Kablov E.N. Kontrol kachestva materialov – garantija bezopasnosti jekspluatacii aviacionnoj tehniki [Quality control of materials – security accreditation of operation of aviation engineering] // Aviacionnye materialy i tehnologii. 2001. №1. S. 3–8.
3. Anihovskaja L.I., Minakov V.T. Klei i kleevye prepregi dlja perspektivnyh izdelij aviakosmicheskoj tehniki [Glues and glue prepregs for perspective products of aerospace equipment] // Aviacionnye materialy. Izbrannye trudy «VIAM» 1932–2002. M.: MISIS–VIAM, 2002. S. 315–326.
4. Kirienko T.A., Lukina N.F., Kucevich K.E., Petrova A.P. Issledovanie reologicheskih svojstv kleevyh svjazujushhih [Research of rheological properties of the glue binding] // Klei. Germetiki. Tehnologii. 2016. №2. S. 6–8.
5. Kablov E.N., Chursova L.V., Lukina N.F., Petrova A.P. Issledovanie jepoksidno-polisulfonovyh polimernyh sistem kak osnovy vysokoprochnyh kleev aviacionnogo naznachenija [Research of epoxy and polysulfonic polymeric systems as bases of high-strength adhesives of aviation assignment] // Klei. Germetiki. Tehnologii. 2017. №3. S. 7–12.
6. Dementeva L.A., Kucevich K.E., Lukina N.F., Petrova A.P. Ispolzovanie kleevyh svjazujushhih dlja poluchenija polimernyh kompozicionnyh materialov [Use of glue polymeric composite materials binding for receiving] // Novosti materialovedenija. Nauka i tehnika: jelektron. nauch.-tehnich. zhurn. 2016. №2 (20). S. 24–35 Available at: http://www.materialsnews.ru (accessed: February 8, 2018).
7. Melnikov D.A., Gromova A.A., Raskutin A.E., Kurnosov A.O. Teoreticheskij raschet i eksperimentalnoe opredelenie modulya uprugosti i prochnosti stekloplastika VPS-53/120 [Theoretical calculation and experimental determination of modulus of elasticity and strength of GRP VPS-53/120] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2017. №1 (49). St. 08. Available at: http://www.viam-works.ru (accessed: February 8, 2018). DOI: 10.18577/2307-6046-2017-0-1-8-8.
8. Haskov M.A., Melnikov D.A., Dementeva L.A. Optimizacija rezhimov otverzhdenija jepoksidnyh kompozicij s uchetom masshtabnogo faktora [Optimization of modes of curing of epoxy compositions taking into account large-scale factor] // Sb. dokl. II Mezhdunar. nauch.-tehnich. konf. «Novye materialy i tehnologii glubokoj pererabotki syrja – osnova innovacionnogo razvitija jekonomiki Rossii». M.: VIAM, 2017. S. 30.
9. Lukina N.F., Dementeva L.A., Petrova A.P., Kirienko T.A., Chursova L.V. Kleevye svjazujushhie dlja detalej iz PKM sotovoj konstrukcii [Glue binding for details from PCM of cellular design] // Klei. Germetiki. Tehnologii. 2016. №5. S. 12–16.
10. Babin A.N., Petrova A.P. Metody ispytanij i issledovanij osnovnyh svojstv polimernyh svjazujushhih dlja konstrukcionnyh PKM [Test methods and researches of the main properties polymeric binding for constructional PCM] // Vse materialy. Jenciklopedicheskij spravochnik, 2016. №3. S. 52–59.
11. Kirienko T.A., Lukina N.F., Kutsevich K.E., Petrova A.P. A study of the rheological properties of adhesive binders // Polymer Science. D. 2016. T9. №3. P. 295–297.
12. Deev I.S., Kablov E.N., Kobets L.P., Chursova L.V. Issledovanie metodom skaniruyushhej elektronnoj mikroskopii deformacii mikrofazovoj struktury polimernyh matric pri mehanicheskom nagruzhenii [Research of the scanning electron microscopy method defor-mation of microphase structure of polymeric matrix at mechanical loading] // Trudy VIAM: elektron. nauch-tehnich. zhurn. 2014. №7. St. 06. Available at: http://www.viam-works.ru (accessed: February 8, 2018). DOI: 10.18577/2307-6046-2014-0-7-6-6.
13. Sharova I.A., Petrova A.P. Obzor po materialam mezhdunarodnoj konferencii po kleyam i germetikam (WAC-2012, Franciya) [Review of world adhesive and sealant conference (WAC-2012, France] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №8. St. 06. Available at: http://www.viam-works.ru (accessed: February 8, 2018).
14. Grashhenkov D.V., Chursova L.V. Strategiya razvitiya kompozicionnyh i funkcionalnyh materialov [Strategy of development of composite and functional materials] // Aviacionnye materialy i tehnologii. 2012. №S. S. 231–242.
15. Lukina N.F., Dementeva L.A., Petrova A.P., Serezhenkov A.A. Konstrukcionnye i termostojkie klei [Constructional and heat-resistant glues] // Aviacionnye materialy i tehnologii. 2012. №S. S. 328–335.
16. Petrovа A.P., Dementyevа L.A., Lukina N.F., Chursova L.V. Kleevye svjazujushhie dlja polimernyh kompozicionnyh materialov na ugle- i steklonapolniteljah [Adhesive binders for polymer composite materials based on carbon- and glass fillers] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №9. St. 11. Available at: http://www.viam-works.ru (accessed: February 8, 2018). DOI: 10.18577/2307-6046-2015-0-9-11-11.
17. Lukina N.F., Dementeva L.A., Serezhenkov A.A., Kotova E.V., Senatorova O.G., Sidel'nikov V.V., Kucevich K.E. Kleevye prepregi i kompozicionnye materialy na ih osnove [Glue prepregs and composite materials on their basis] // Rossijskij himicheskij zhurnal. 2010. T. LIV. №1. S. 53–56.
18. Lukina N.F., Kotova E.V., Chursova L.V., Kirienko T.A. Kleevye svjazujushhie dlja aljumo-polimernyh kompozicionnyh materialov [Glue binding for alyumo-polymeric composite materials] // Klei. Germetiki. Tehnologii. 2016. №4. S. 15–19.
2. Kablov E.N. Kontrol kachestva materialov – garantija bezopasnosti jekspluatacii aviacionnoj tehniki [Quality control of materials – security accreditation of operation of aviation engineering] // Aviacionnye materialy i tehnologii. 2001. №1. S. 3–8.
3. Anihovskaja L.I., Minakov V.T. Klei i kleevye prepregi dlja perspektivnyh izdelij aviakosmicheskoj tehniki [Glues and glue prepregs for perspective products of aerospace equipment] // Aviacionnye materialy. Izbrannye trudy «VIAM» 1932–2002. M.: MISIS–VIAM, 2002. S. 315–326.
4. Kirienko T.A., Lukina N.F., Kucevich K.E., Petrova A.P. Issledovanie reologicheskih svojstv kleevyh svjazujushhih [Research of rheological properties of the glue binding] // Klei. Germetiki. Tehnologii. 2016. №2. S. 6–8.
5. Kablov E.N., Chursova L.V., Lukina N.F., Petrova A.P. Issledovanie jepoksidno-polisulfonovyh polimernyh sistem kak osnovy vysokoprochnyh kleev aviacionnogo naznachenija [Research of epoxy and polysulfonic polymeric systems as bases of high-strength adhesives of aviation assignment] // Klei. Germetiki. Tehnologii. 2017. №3. S. 7–12.
6. Dementeva L.A., Kucevich K.E., Lukina N.F., Petrova A.P. Ispolzovanie kleevyh svjazujushhih dlja poluchenija polimernyh kompozicionnyh materialov [Use of glue polymeric composite materials binding for receiving] // Novosti materialovedenija. Nauka i tehnika: jelektron. nauch.-tehnich. zhurn. 2016. №2 (20). S. 24–35 Available at: http://www.materialsnews.ru (accessed: February 8, 2018).
7. Melnikov D.A., Gromova A.A., Raskutin A.E., Kurnosov A.O. Teoreticheskij raschet i eksperimentalnoe opredelenie modulya uprugosti i prochnosti stekloplastika VPS-53/120 [Theoretical calculation and experimental determination of modulus of elasticity and strength of GRP VPS-53/120] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2017. №1 (49). St. 08. Available at: http://www.viam-works.ru (accessed: February 8, 2018). DOI: 10.18577/2307-6046-2017-0-1-8-8.
8. Haskov M.A., Melnikov D.A., Dementeva L.A. Optimizacija rezhimov otverzhdenija jepoksidnyh kompozicij s uchetom masshtabnogo faktora [Optimization of modes of curing of epoxy compositions taking into account large-scale factor] // Sb. dokl. II Mezhdunar. nauch.-tehnich. konf. «Novye materialy i tehnologii glubokoj pererabotki syrja – osnova innovacionnogo razvitija jekonomiki Rossii». M.: VIAM, 2017. S. 30.
9. Lukina N.F., Dementeva L.A., Petrova A.P., Kirienko T.A., Chursova L.V. Kleevye svjazujushhie dlja detalej iz PKM sotovoj konstrukcii [Glue binding for details from PCM of cellular design] // Klei. Germetiki. Tehnologii. 2016. №5. S. 12–16.
10. Babin A.N., Petrova A.P. Metody ispytanij i issledovanij osnovnyh svojstv polimernyh svjazujushhih dlja konstrukcionnyh PKM [Test methods and researches of the main properties polymeric binding for constructional PCM] // Vse materialy. Jenciklopedicheskij spravochnik, 2016. №3. S. 52–59.
11. Kirienko T.A., Lukina N.F., Kutsevich K.E., Petrova A.P. A study of the rheological properties of adhesive binders // Polymer Science. D. 2016. T9. №3. P. 295–297.
12. Deev I.S., Kablov E.N., Kobets L.P., Chursova L.V. Issledovanie metodom skaniruyushhej elektronnoj mikroskopii deformacii mikrofazovoj struktury polimernyh matric pri mehanicheskom nagruzhenii [Research of the scanning electron microscopy method defor-mation of microphase structure of polymeric matrix at mechanical loading] // Trudy VIAM: elektron. nauch-tehnich. zhurn. 2014. №7. St. 06. Available at: http://www.viam-works.ru (accessed: February 8, 2018). DOI: 10.18577/2307-6046-2014-0-7-6-6.
13. Sharova I.A., Petrova A.P. Obzor po materialam mezhdunarodnoj konferencii po kleyam i germetikam (WAC-2012, Franciya) [Review of world adhesive and sealant conference (WAC-2012, France] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №8. St. 06. Available at: http://www.viam-works.ru (accessed: February 8, 2018).
14. Grashhenkov D.V., Chursova L.V. Strategiya razvitiya kompozicionnyh i funkcionalnyh materialov [Strategy of development of composite and functional materials] // Aviacionnye materialy i tehnologii. 2012. №S. S. 231–242.
15. Lukina N.F., Dementeva L.A., Petrova A.P., Serezhenkov A.A. Konstrukcionnye i termostojkie klei [Constructional and heat-resistant glues] // Aviacionnye materialy i tehnologii. 2012. №S. S. 328–335.
16. Petrovа A.P., Dementyevа L.A., Lukina N.F., Chursova L.V. Kleevye svjazujushhie dlja polimernyh kompozicionnyh materialov na ugle- i steklonapolniteljah [Adhesive binders for polymer composite materials based on carbon- and glass fillers] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №9. St. 11. Available at: http://www.viam-works.ru (accessed: February 8, 2018). DOI: 10.18577/2307-6046-2015-0-9-11-11.
17. Lukina N.F., Dementeva L.A., Serezhenkov A.A., Kotova E.V., Senatorova O.G., Sidel'nikov V.V., Kucevich K.E. Kleevye prepregi i kompozicionnye materialy na ih osnove [Glue prepregs and composite materials on their basis] // Rossijskij himicheskij zhurnal. 2010. T. LIV. №1. S. 53–56.
18. Lukina N.F., Kotova E.V., Chursova L.V., Kirienko T.A. Kleevye svjazujushhie dlja aljumo-polimernyh kompozicionnyh materialov [Glue binding for alyumo-polymeric composite materials] // Klei. Germetiki. Tehnologii. 2016. №4. S. 15–19.
8.
УДК 678.8
Sinyakov S.D.1, Zastrogina O.B.1, Pavlyuk B.F.1
COMPOSITIONS BASED ON PHENOLIC RESINS MODIFIED WITH POLYVINYL ACETALS (review)
The present article provides an overview of compositions based on phenol-formaldehyde resins and polyvinyl acetals. The mutual influence of the components on each other and on the final properties of the products obtained is considered. The features of the chemical interaction of the initial components and the changes in their physicochemical properties are studied depending on their structure. In the review, the most widely known brands of resins and adhesives, which are made on the basis of these compositions, their properties and applications, are considered.
Keywords: phenolic resin, polyvinyl acetal, modification.
Reference List
1. Grashhenkov D.V., Chursova L.V. Strategiya razvitiya kompozicionnyh i funkcionalnyh materialov [Strategy of development of composite and functional materials] // Aviacionnye materialy i tehnologii. 2012. №S. S. 231–242.
2. Kablov E.N. Materialy i khimicheskie tekhnologii dlya aviatsionnoy tekhniki [Materials and chemical technologies for aviation engineering] // Vestnik Rossiyskoy akademii nauk. 2012. T. 82. №6. S. 520–530.
3. Kablov E.N., Minakov V.T., Anikhovskaya L.I. Klei i materialy na ikh osnove dlya remonta kon-struktsiy aviatsionnoy tekhniki [Glues and materials on their basis for repair of designs of aviation engineering] // Aviatsionnye materialy i tekhnologii. 2002. №1. S. 61–65.
4. Lukina N.F., Dementeva L.A., Petrova A.P., Serezhenkov A.A. Konstrukcionnye i termostojkie klei [Constructional and heat-resistant glues] // Aviacionnye materialy i tehnologii. 2012. №S. S. 328–335.
5. Dementeva L.A., Serezhenkov A.A., Lukina N.F., Kucevich K.E. Kleevye prepregi i sloistye materialy na ih osnove [Adhesive prepregs and layered materials on their basis] // Aviacionnye materialy i tehnologii. 2013. №2. S. 19–21.
6. Kablov E.N. Khimiya v aviatsionnom materialovedenii [Chemistry in aviation materials science] // Rossiyskiy khimicheskiy zhurnal. 2010. T. LIV. №1. S. 3–4.
7. Kablov E.N. Strategicheskie napravleniya razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda [The strategic directions of development of materials and technologies of their processing for the period to 2030] // Aviacionnye materialy i tehnologii. 2012. №S. S. 7–17.
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32. Shidlz Dzh. Klejashhie materialy: spravochnik [Gluing materials: directory]. Per. s angl. M.: Mashinostroenie, 1980. 368 s.
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34. Da Silva L.F.M., Öchsner A., Adams R.D. Handbook of Adhesion Technology. Springer, 2011. 1554 p.
35. Pizzi А., Mittal K.L. Handbook of Adhesive Technology. 2nd ed., rev. and exp. Marcel Dekker, Inc, 2003. 999 p.
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37. Gerald L. Schneberger. Adhesion in Manufacturing. Marcel Dekker, Inc., 1983. 696 c.
9.
category: Composite materials
УДК 678.6
Ogmrcyan A.R.1, Guseva M.A.1
RESEARCH OF THE EFFECT OF MODIFIERS ON THE PROPERTIES OF AN EPOXYVINYLESTER COMPOSITION CURED BY THE RADICAL POLYMERIZATION MECHANISM
The possibility of replacing the imported resin in the composition of epoxyvinylether binders with domestic ones. A comparison of the properties of the domestic epoxy vinyl ester VES-BM and ester Derakane 470-300 (manufactured – by Ashland), as well as binders on their basis, is presented. The properties of binders are given, depending on the peroxides used in their composition. The results of tests carried out using differential scanning calorimetry, dynamomechanical analysis, and rheological investigation methods are shown. The results of studies on the modification of epoxyvinylether binders with isocyanate and diallyl phthalate are presented with a view to improving their properties.
Keywords: binder, epoxy vinyl ester resins, viscosity, peroxides, curing, thermomechanical studies, rheology.
Reference List
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